Character of the thermal motion of water molecules according to the data on quasielastic incoherent scattering of slow neutrons

The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature.     

Controlling the diffusion process via time-variable diffusion coefficient

The establishment of the steady-state dopant profile in a medium with a time-variable diffusion coefficient is considered within the approach proposed previously for estimating mass-and heat-transfer time characteristics. It is shown that the time it takes for the equilibrium concentration to set in may be increased or decreased by appropriately choosing the law of variation of the diffusion coefficient.     

ΓD‐convergence for a class of quasilinear elliptic equations in thin structures

We study the asymptotic behaviour of the solution of a stationary quasilinear elliptic problem posed in a domain Ω^(ε) of asymptotically degenerating measure, i.e. meas Ω^(ε) → 0 as ε → 0, where ε is the parameter that characterizes the scale of the microstructure. We obtain the convergence of the solution and the homogenized model of the problem is constructed using the notion of convergence in domains of degenerating measure. Proofs are given using the method of local characteristics of the medium Ω^(ε) associated with our problem in a variational form. Copyright © 2005 John Wiley & Sons, Ltd.     

Quantum-Chemical Evaluation of the Protolytic Properties of Thiophenols

The enthalpies and free energies of proton affinity (PA) were calculated by the PM3 method for 27 thiophenoxide anions. For thiophenols, linear correlation has been found between the PAs and the values of pK _a measured by different authors in aqueous acetone, aqueous ethanol, and methanol media. The dependences found permit one to predict a priori the protolytic properties of thiophenols. The differential effects of aqueous ethanol media with different ethanol contents on thiophenol acidity were evaluated based on quantum-chemical data.Original Russian Text Copyright © 2004 by A. N. Pankratov and A. V. Shalabai__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 800–806, September–October, 2004.     

The asymptotic behavior of the solutions of variational problems in domain with “accumulators”

Translated from Teoriya Funktsii, Funktsional'nyi Analiz i Ikh Prilozheniya, No. 54, pp. 97–105, 1990.     

Chemical-potential dependence of the pairing gap in a nuclear-matter slab

The equation for the pairing gap Δ in a slab of nuclear matter governed by the Paris nucleon-nucleon potential is solved for various values of the chemical potential μ in the range from −8 MeV, which corresponds to stable nuclei, to −0.1 MeV, which corresponds to nuclei in the vicinity of the nucleon drip line. The slab is placed in a one-dimensional Woods-Saxon potential whose parameters are set to values typical of nuclei. Two models are considered. In the first, the potential-well depth is fixed at U ₀ = −50 MeV, the density within the slab growing as |μ| is reduced. In the second model, the density is fixed at the center of the slab, |U ₀| decreasing as |μ| is reduced. The behavior of the gap Δ as a function of μ is model-dependent. In the first model, Δ decreases with decreasing |μ|, while, in the second, it increases. At the same time, the effect of the surface enhancement of Δ becomes more pronounced with decreasing |μ| in both models. Original Russian Text ? S.S. Pankratov, E.E. Saperstein, M.V. Zverev, 2006, published in Yadernaya Fizika, 2006, Vol. 69, No. 12, pp. 2052–2063.     

Recognition of the structural-functional organization of genetic sequences

The analysis problem for genetic sequences is formulated from the viewpoint of modern mathematical and information approaches. Statistical, correlative, entropic, and spectral approaches are considered. A brief introduction into the background of the problem is given. Genesis of a new interdisciplinary subject area, bioinformatics, a science considering application of computer methods in biological studies, is analyzed. New approaches to studying macromolecular systems on the basis of combined spectral-analytic technologies are proposed. Estimates of the algorithmic complexity of implementation of the proposed approaches are presented.