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1.
Synthesis,spectral investigation and development of tetrahedral copper(II) complexes as artificial metallonucleases and antimalarial agents 下载免费PDF全文
Seven new copper(II) complexes of type [Cu(A)(L)]?H2O (A = sparfloxacin, ciprofloxacin, levofloxacin, gatifloxacin, pefloxacin, ofloxacin, norfloxacin; L = 5‐[(3‐chlorophenyl)diazenyl]‐4‐hydroxy‐1,3‐thiazole‐2(3H)‐thione) were synthesized and characterized using elemental and thermogravimetric analyses, and electronic, electron paramagnetic resonance (EPR), Fourier transform infrared and liquid chromatography–mass spectroscopies. Tetrahedral geometry around copper is assigned in all complexes using EPR and electronic spectral analyses. All complexes were investigated for their interaction with herring sperm DNA utilizing absorption titration (Kb = 1.27–3.13 × 105 M?1) and hydrodynamic volume measurement studies. The studies suggest the classical intercalative mode of DNA binding. The cleavage reaction on pUC19 DNA was monitored by agarose gel electrophoresis. The results indicate that the Cu(II) complexes can more effectively promote the cleavage of plasmid DNA. The superoxide dismutase mimic activity of the complexes was evaluated by nitroblue tetrazolium assay, and the complexes catalysed the dismutation of superoxide at pH = 7.8 with IC50 values in the range 0.597–0.900 μM. The complexes were screened for their in vitro antibacterial activity against five pathogenic bacteria. All the complexes are good cytotoxic agents and show LC50 values ranging from 5.559 to 11.912 µg ml?1. All newly synthesized Cu(II) complexes were also evaluated for their in vitro antimalarial activity against Plasmodium falciparum strain (IC50 = 0.62–2.0 µg ml?1). Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
2.
Journal of Thermal Analysis and Calorimetry - In the case of flow boiling, the prediction of vapour fraction in the horizontal microchannel is a severe issue using the numerical technique.... 相似文献
3.
4.
V Ravindran Pankaj Agrawal Rahul Basu Satyaki Bhattacharya J Blümlein V Del Duca R Harlander D Kosower Prakash Mathews Anurag Tripathi 《Pramana》2006,67(5):983-992
This is the report of the subgroup QCD of Working Group-4 at WHEPP-9. We present the activities that had taken place in the
subgroup and report some of the partial results arrived at following the discussion at the working group meetings. 相似文献
5.
6.
P. C. Mehta 《Hyperfine Interactions》1987,37(1-4):325-345
Optical data processing is an advancing field which has received much attention in recent years. Optical techniques have already
shown their applicability in target identification, advanced signal processing operations and advanced linear algebra operations.
The potential capabilities of processing of data using photons instead of electrons as the carrier of information have established,
beyond any doubt, that the optical techniques will be the next generation technology surpassing electronic techniques in some
important areas such as air traffic control, missile guidance and remote sensing. Although great strides have been made in
all the areas of optical data processing, the goal of high performance, high speed and very accurate all-optical computers
would be realised only around the year 1995. The main difficulty is that the required materials for high resolution and fast
spatial light modulators and optical interconnects are yet to be perfected. The present paper reviews the recent trends and
the future prospects of optical data processing. 相似文献
7.
The objective of this paper is to investigate the role of the set of irrational numbers as the codomain of order-preserving
functions defined on topological totally preordered sets. We will show that although the set of irrational numbers does not
satisfy the Debreu property it is still nonetheless true that any lower (respectively, upper) semicontinuous total preorder
representable by a real-valued strictly isotone function (semicontinuous or not) also admits a representation by means of
a lower (respectively, upper) semicontinuous strictly isotone function that takes values in the set of irrational numbers.
These results are obtained by means of a direct construction. Moreover, they can be related to Cantor’s characterization of the real line to obtain much more general results on the semicontinuous
Debreu properties of a wide family of subsets of the real line.
相似文献
8.
Pankaj Mathur 《分析论及其应用》2006,22(2):105-113
In this paper, we study the explicit representation and convergence of (0, 1;0)-interpolation on infisite interval, which means to determine a polynomial of degree ≤ 3n - 2 when the function values areprescribed at two set of points namely the zeros of Hn(x) and H′n (x) and the first derivatives at the zerosof H′n(x). 相似文献
9.
10.
Pankaj K. Agarwal 《Discrete and Computational Geometry》1990,5(1):533-573
In this paper we present efficient deterministic algorithms for various problems involving lines or segments in the plane, using the partitioning algorithm described in a companion paper [A3]. These applications include: (i) anO(m
2/3
n
2/3 · log2/3
n · log/3 (m/n)+(m+n) logn) algorithm to compute all incidences betweenm points andn lines, where is a constant <3.33; (ii) anO(m
2/3
n
2/3 · log5/3
n · log/3 (m/n)+(m+n) logn) algorithm to computem faces in an arrangement ofn lines; (iii) anO(n
4/3 log(+2)/3
n) algorithm to count the number of intersections in a set ofn segments; (iv) anO(n
4/3 log( + 2)/3
n) algorithm to count red-blue intersections between two sets of segments, and (v) anO(n
3/2 log/3
n) algorithm to compute spanning trees with low stabbing number for a set ofn points. We also present an algorithm that, given set ofn points in the plane, preprocesses it, in timeO(nm log+1/2
n), into a data structure of sizeO(m) forn lognmn
2, so that the number of points ofS lying inside a query triangle can be computed inO((n/m) log3/2
n) time.Work on this paper has been supported by Office of Naval Research Grant N00014-87-K-0129, by National Science Foundation Grant DCR-83-20085, and by grants from the Digital Equipment Corporation and the IBM Corporation. A preliminary version of this paper appears in theProceedings of the 5th ACM Symposium on Computational Geometry, 1989, pp. 11–22. 相似文献