Bending of the magnetic fluid surface in the electric field of a plane capacitor

The behavior of magnet particles in an insulating fluid exposed to an electric field is studied. The surface of the fluid in the electrode gap changes because of the space charge forming in the near-electrode layer.     

Utilization of α-olefins obtained by pyrolysis of waste high density polyethylene to synthesize α-olefin-succinic-anhydride based cold flow improvers

A new route of utilization of α-olefin rich hydrocarbon fractions obtained by waste polymer pyrolysis was investigated. α-olefin-succinic-anhydride intermediate-based pour point depressant additives for diesel fuel were synthesized, in which reactions needed α-olefins were obtained by pyrolysis of waste high-density polyethylene (HDPE). Fraction of α-olefins was produced by the de-polymerization of plastic waste in a tube reactor at 500℃ in the absence of catalysts and air. C_17~22 range of mixtures of olefins and paraffins were separated for synthesis and then, these hydrocarbons were reacted with maleic-anhydride (MA) for formation of α-olefin-succinic-anhydride intermediates. The olefin-rich hydrocarbon fraction contained approximately 60% of olefins, including 90%~95% α-olefins. Other intermediates were produced in the same way by using commercial C₂₀ α-olefin instead of C_17~22 olefin mixture. The two different experimental intermediates with number average molecular weights of 1850g/mol and 1760g/mol were reacted with different alcohols: 1-butanol, 1-hexanol, 1-octanol, i-butanol, and c-hexanol to produce their ester derivatives. The synthesized ten experimental pour point depressants were added in different concentrations to conventional diesel fuel, which had no other additive content before. The structure and efficiency of experimental additives were followed by different standardized and non-standardized methods. Results showed that the experimental additives on the basis of the product of waste pyrolysis were able to decrease not only the pour but also the cloud point and cold filter plugging point (CFPP) of diesel fuel, whose effects could be observed even if the concentration of additives was low. Furthermore, all additives had anti-wear and anti-friction effects in diesel fuel.     

An alternating direction scheme on a nonuniform mesh for reaction-diffusion parabolic problems

In this paper we develop a numerical method for two-dimensionaltime-dependent reaction-diffusion problems. This method, whichcan immediately be generalized to higher dimensions, is shownto be uniformly convergent with respect to the diffusion problems.This method, which can immediately be generalized to higherdimensions, is shown to be uniformly convergent with respectto the diffusion parameter.     

Kinetics of Electric Birefringence in Colloidal Solutions of Magnetic Particles

Birefringence kinetics in magnetite–kerosene and magnetite–transformer oil colloidal systems in electric field was studied. Coefficients of rotational Brownian diffusion of colloidal particles were calculated from experimental data, and conclusion was made of the presence of magnetite particle aggregates in these systems.     

Void Closure in Complex Plasmas under Microgravity Conditions

We describe the first observation of a void closure in complex plasma experiments under microgravity conditions performed with the Plasma-Kristall (PKE-Nefedov) facility on board the International Space Station. The void--a grain-free region in the central part of the discharge where the complex plasma is generated--has been formed under most of the plasma conditions and thought to be an inevitable effect. However, we demonstrate in this Letter that an appropriate tune of the discharge parameters allows the void to close. This experimental achievement along with its theoretical interpretation opens new perspectives in engineering new experiments with large quasi-isotropic void-free complex plasma clouds in microgravity conditions.     

Lanthanide complexes with 2,4-dimethoxybenzoic acid

Russian Journal of General Chemistry -