Crystallographic report: A new polymorph for bis[bis(N,N‐dibenzyldithiocarbamato)cadmium(II)]

The title compound is a centrosymmetric dimer with each cadmium in a distorted CdS₅ square pyramidal geometry. The Cd–S bond distances range from 2.5626(11) to 2.8459(11) Å. Copyright © 2004 John Wiley & Sons, Ltd.     

Hydrodynamical limit for a Hamiltonian system with weak noise

Starting from a general hamiltonian system with superstable pairwise potential, we construct a stochastic dynamics by adding a noise term which exchanges the momenta of nearby particles. We prolve that, in the scaling limit, the time conserved quantities, energy, momenta and density, satisfy the Euler equation of conservation laws up to a fixed timet provided that the Euler equation has a smooth solution with a given initial data up to timet. The strength of the noise term is chosen to be very small (but nonvanishing) so that it disappears in the scaling limit.Research partially supported by U.S. National Science Foundation grants DMS 89001682, DMS 920-1222 and a grant from ARO, DAAL03-92-G-0317Research partially supported by U.S. National Science Foundation grants DMS-9101196, DMS-9100383, and PHY-9019433-A01, Sloan Foundation Fellowship and David and Lucile Packard Foundation Fellowship     

Macroscopic energy diffusion for a chain of anharmonic oscillators

We study the energy diffusion in a chain of anharmonic oscillators where the Hamiltonian dynamics is perturbed by a local energy conserving noise. We prove that under diffusive rescaling of space–time, energy fluctuations diffuse and evolve following an infinite dimensional linear stochastic differential equation driven by the linearized heat equation. We also give variational expressions for the thermal diffusivity and some upper and lower bounds.     

A Note on Fick’s Law with Phase Transitions

Journal of Statistical Physics - We characterize the non equilibrium stationary states in two classes of systems where phase transitions are present. We prove that the interface in the limit is a...     

On Mobility and Einstein Relation for Tracers in Time-Mixing Random Environments

In this paper we rigorously establish the existence of the mobility coefficient for a tagged particle in a simple symmetric exclusion process with adsorption/desorption of particles, in a presence of an external force field interacting with the particle. The proof is obtained using a perturbative argument. In addition, we show that, for a constant external field, the mobility of a particle equals to the self-diffusivity coefficient, the so-called Einstein relation. The method can be applied to any system where the environment has a Markovian evolution with a fast convergence to equilibrium (spectral gap property). In this context we find a necessary relation between forward and backward velocity for the validity of the Einstein relation. This relation is always satisfied by reversible systems. We provide an example of a non-reversible system, where the Einstein relation is valid.This revised version was published online in March 2005 with corrections to the page numbers.     

Symmetric Simple Exclusion Process:¶Regularity of the Self-Diffusion Coefficient

We prove that the self-diffusion coefficient of a tagged particle in the symmetric exclusion process in Z ^d , which is in equilibrium at density α, is of class C ^∞ as a function of α in the closed interval [0,1]. The proof provides also a recursive method to compute the Taylor expansion at the boundaries. Received: 6 December 2000 / Accepted: 6 April 2001     

On the sector condition and homogenization of diffusions with a Gaussian drift

In this paper we present the functional central limit theorem for a class of Markov processes, whose L²-generator satisfies the so-called graded sector condition. We apply the result to obtain homogenization theorems for certain classes of diffusions with a random Gaussian drift. Additionally, we present a result concerning the regularity of the effective diffusivity tensor with respect to the parameters related to the statistics of the drift. The abstract central limit theorem, see Theorem 2.2, is obtained by applying the technique used in Sethuraman et al. (Comm. Pure Appl. Math. 53 (2000) 972) to the case of infinite particle systems.     

Driven Tracer Particle in One Dimensional Symmetric Simple Exclusion

Consider an infinite system of particles evolving in a one dimensional lattice according to symmetric random walks with hard core interaction. We investigate the behavior of a tagged particle under the action of an external constant driving force. We prove that the diffusively rescaled position of the test particle εX(ε^-2 t), t > 0, converges in probability, as ε→ 0, to a deterministic function v(t). The function v(⋅) depends on the initial distribution of the random environment through a non-linear parabolic equation. This law of large numbers for the position of the tracer particle is deduced from the hydrodynamical limit of an inhomogeneous one dimensional symmetric zero range process with an asymmetry at the origin. An Einstein relation is satisfied asymptotically when the external force is small. Received: 5 December 1996 / Accepted: 30 June 1997