Determination of 5-nitroindazole using silver solid amalgam electrode

Monatshefte für Chemie - Chemical Monthly - The voltammetric behavior of 5-nitroindazole was investigated at polished (p-AgSAE) and at mercury meniscus-modified (m-AgSAE) silver solid amalgam...     

Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization

This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781     

Nonlinear frequency response analysis: a recent review and perspectives

The nonlinear frequency response analysis (NFRA) can be seen as an extension of electrochemical impedance spectroscopy. NFRA gives a full and detailed representation of the system response and can establish a connection between model parameters and the experimentally observed phenomena. In this article, different theoretical NFRA approaches and the most recent application examples are discussed. A simple electrochemical example is used to showcase the benefits and disadvantages of analyzing the system response by using different approaches. In addition, it was shown how to extract experimental harmonic values and analyze them.     

Infrared picosecond absorption spectroscopy of microcrystalline silicon: separation between carrier recombination in crystalline and amorphous fractions

We have studied ultra-fast carrier dynamics of photo-excited carriers in hydrogenated microcrystalline silicon prepared by a very high frequency glow-discharge technique. We report on direct observation of two types of dynamics using selective photo-excitation in picosecond pump and probe measurements. One type of the observed dynamics has been found to be independent of the sample preparation, while the other reflects the relative weights of crystalline and amorphous fractions. We propose a simple rate-equation model that describes the carrier dynamics in microcrystalline silicon in terms of the composition of those in Si microcrystallites and in the a-Si:H tissue which surrounds the microcrystallites. The model without any fitting parameters reproduces the experimental data very well when the dynamics are scaled with relative volume fractions as obtained from Raman spectra. Received: 23 November 2000 / Accepted: 17 March 2001 / Published online: 23 May 2001     

On the condensate values in QCD

Conclusions The sets (3) and (4) of condensates have been compared using the QCD sum rules (2) with indefinite weight functions. A bad matching between both sets of condensates and experimental data has been obtained. The standard values (3) appear to be closer to data but some increase ofQ is necessary to improve the agreement. Only higher values ofm ₀ ² could change the results of this analysis. It is interesting that negative values ofm ₀ ² considerably improve the agreement with data; note that this quantity cannot be determined with a sufficient accuracy. We conclude that the QCD sum rules (2) cannot definitely determine a privileged set of condensates.Dedicated to Academician Václav Votruba on the occasion of his eightieth birthday.     

Continuously coupled parametric generators and their quantum statistics

In this paper the quantum-statistical properties of light beams propagating in a directional nonlinear coupler are investigated. This device is composed of a pair of linearly coupled nonlinear waveguides operating by means of degenerate parametric downconversion. The possibility of generation of nonclassical states of light in single and compound modes, using the short-length approximation, is discussed. Influence of linear and nonlinear mismatches for generation of nonclassical light is taken into account. This work was supported by Project LN00A015, Research Project No. CEZ: J14/98 and the COST project OC P11.003 of the Czech Ministry of Education.     

Planar Chromatography of Some 1-Arylpiperazines Behaving as Dopaminergic Ligands

JPC – Journal of Planar Chromatography – Modern TLC - The chromatographic behavior of fourteen 1-arylpiperazine derivatives has been studied by thin-layer chromatography on both silica...     

Novel liquid crystals based on [1]benzothieno[3,2- b ][1]benzothiophene

Four series of new [1]benzothieno[3,2- b ][1]benzothiophene derivatives have been synthesized. In the non-chiral series a SmA phase occurs, while the chiral series exhibits a rather wide antiferroelectric SmC * A phase just below the SmA phase. The SmA-SmC * A phase transition has been studied using DSC and dielectric spectroscopy. In the SmC * A phase the spontaneous quantities have been measured. The tilt angle shows a typical temperature dependence and the values of spontaneous polarization are rather moderate. The length of the helical pitch increases on increasing the length of the non-chiral alkyl chain.