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排序方式: 共有646条查询结果,搜索用时 15 毫秒
1.
(PPh4)2HP7 · 3NH3 was prepared by the reaction of K3P7 with a proton‐charged ion exchange resin in the presence of (PPh4)Br in liquid ammonia, and characterized by low temperature X‐ray structure analysis. The thermally very unstable compound contains the hydrogenheptaphosphide anion HPequation/tex2gif-stack-1.gif, the nortricyclane‐like cage of which is slightly distorted by the attachment of the hydrogen atom. 相似文献
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Polyacrylamide gel electrophoresis was used to resolve as many as three protein components from incubation mixtures containing the inhibitor, 5-fluoro-2′-deoxyuridylate, the cofactor, 5,10-methylene tetrahydrofolate, and thymidylate synthetase. In a series of mixtures containing excess 5,10-methylenetetrahydrofolate and constant levels of thymidylate synthetase, the relative amounts of the protein components were shown to be dependent on the concentration of the inhibitor. Evidence is presented which suggests that the three protein components correspond to (1) native enzyme, (2) an inhibitor-cofactor-enzyme complex in a 1:1:1 molar ratio, and (3) an inhibitorcofactorenzyme complex in a 2:2:1 molar ratio, respectively. Ternary complexes of thymidylate synthetase are stable to gel filtration and are shown to undergo a relatively slow rate of breakdown on storage at 25 °C. 相似文献
6.
Lyon EJ Georgakaki IP Reibenspies JH Darensbourg MY 《Angewandte Chemie (International ed. in English)》1999,38(21):3178-3180
The Fe(I) organometallic complex [(μ-SCH(2)CH(2)CH(2)S)Fe(2)(CO)(6)] provides a structural model for the cyano-carbonyl diiron site of Fe-only hydrogenase as characterized by X-ray crystallography (the picture shows the structure (black) of the model overlaid with that of the Fe-Fe dimetallic site in the hydrogenase isolated from Desulfovibrio desulfuricans). Cyanide substitution of CO occurs readily and provides spectroscopic references for the active site. 相似文献
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This paper characterizes the conditions required to form nanoliter-sized droplets (plugs) of viscous aqueous reagents in flows of immiscible carrier fluid within microfluidic channels. For both non-viscous (viscosity of 2.0 mPa s) and viscous (viscosity of 18 mPa s) aqueous solutions, plugs formed reliably in a flow of water-immiscible carrier fluid for Capillary number less than 0.01, although plugs were able to form at higher Capillary numbers at lower ratios of the aqueous phase flow rate to the flow rate of the carrier fluid (in all the experiments performed, the Reynolds number was less than 1). The paper also shows that combining viscous and non-viscous reagents can enhance mixing in droplets moving through straight microchannels by providing a nearly ideal initial distribution of reagents within each droplet. The study should facilitate the use of this droplet-based microfluidic platform for investigation of protein crystallization, kinetics, and assays. 相似文献
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As12Se44—: a New Selenoarsenate Anion with a Polyarsenic Cage in the Compound [Co(NH3)6]2As12Se4 · 12 NH3 Orange coloured crystals of [Co(NH3)6]2As12Se4 · 12 NH3 were prepared by the reduction of As4Se4 with a solution of sodium in liquid ammonia and subsequent precipitation with CoBr2. The X‐ray structure determination shows them to contain the selenoarsenate anion As12Se44—, which consists of a central As12‐cage with four exo‐bonded, formally negatively charged Se atoms. The structure of the As12‐cage is equivalent to the main polyphosphorus building unit of a known organopolyphosphane and of tubular P12 in the compound (CuI)3P12. 相似文献
9.
A. Gierulski G. Marowsky B. Nikolaus N. Vorob'ev 《Applied physics. B, Lasers and optics》1985,36(3):133-135
Second-harmonic generation from dye adsorbates has been successfully used to measure the duration of ps pulses. In the red and in the blue-green spectral range pulse durations of 2.4 and 6.1 ps—in agreement with streak camera measurements — have been obtained from collinear, slow autocorrelation traces. 相似文献
10.
W. S. Lyon 《Journal of Radioanalytical and Nuclear Chemistry》1982,75(1-2):229-235
A scientometric study of communication and growth of a new development of physics, resonance ionization spectroscopy, has been made. Formal (journal publications) and informal (talks, lecures) communication patterns have been studied. Self citation dominates in early publications, but drops off as the field expands. Informal communication leads formal only by about a year in time, but is much larger in number. 相似文献