全文获取类型
收费全文 | 82篇 |
免费 | 0篇 |
专业分类
化学 | 26篇 |
晶体学 | 1篇 |
数学 | 4篇 |
物理学 | 51篇 |
出版年
2023年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2014年 | 2篇 |
2013年 | 3篇 |
2012年 | 2篇 |
2010年 | 2篇 |
2008年 | 4篇 |
2007年 | 3篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 4篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1989年 | 2篇 |
1984年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1930年 | 2篇 |
排序方式: 共有82条查询结果,搜索用时 31 毫秒
1.
2.
3.
An experimental study of the thermal decomposition of a β‐hydroxy alkene, 3‐methyl‐3‐buten‐1‐ol, in m‐xylene solution, has been carried out at five different temperatures in the range of 513.15–563.15 K. The temperature dependence of the rate constants for the decomposition of this compound in the corresponding Arrhenius equation is given by ln k (s?1) = (25.65 ± 1.52) ? (17,944 ± 814) (kJ·mol?1)·T?1. A computational study has been carried out at the M05–2X/6–31+G(d,p) level of theory to calculate the rate constants and the activation parameters by the classical transition state theory. There is a good agreement between the experimental and calculated rate constants and activation Gibbs energies. The bonding characteristics of reactant, transition state, and products have been investigated by the natural bond orbital analysis, which provides the natural atomic charges and the Wiberg bond indices. Based on the results obtained, the mechanism proposed is a one‐step process proceeding through a six‐membered cyclic transition state, being a concerted and slightly asynchronous process. The results have been compared with those obtained previously by us (Struct Chem 2013, 24, 1811–1816) for the thermal decomposition of 3‐buten‐1‐ol, in m‐xylene solution. We can conclude that in the compound studied in this work, 3‐methyl‐3‐buten‐1‐ol, the effect of substitution at position 3 by a weakly activating CH3 group is the stabilization of the transition state formed in the reaction and therefore a small increase in the rate of thermal decomposition. 相似文献
4.
Abstract Due to the wide use of polymers in medicine, researchers are required to solve a very important problem–to understand the interaction between materials of nonphysiological origin and the surrounding biological liquids, and tissues, particularly blood. 相似文献
5.
Hans-Joachim Nees Uwe Bergstrßer Heinrich Heydt Manfred Regitz 《Heteroatom Chemistry》1993,4(5):525-530
The (diazoalkyl)phosphanes 4a–e undergo [4 + 1]-cycloaddition reactions with the tetrahalo-orthobenzoquinones 5a,b to furnish the previously unknown (diazoalkyl)phosphoranes 6a–h . The structure of product 6h has been investigated by X-ray crystallography. 相似文献
6.
An Yb:glass regenerative amplifier directly side pumped by four 20-W diodes is demonstrated. By use of a novel pumping scheme and introduction of cylindrical optics into the cavity, a free-running average output power as great as 4 W with a TEM(00) -like mode was achieved from the bare cavity, with a 0.56 pump duty cycle. When the regenerative amplifier injected, 1-mJ 200-fs FWHM pulses were obtained following compression by use of 2-ms pump pulses and up to a 150-Hz repetition rate. 相似文献
7.
8.
9.
10.