全文获取类型
收费全文 | 1645篇 |
免费 | 74篇 |
国内免费 | 5篇 |
专业分类
化学 | 1245篇 |
晶体学 | 14篇 |
力学 | 32篇 |
数学 | 57篇 |
物理学 | 376篇 |
出版年
2023年 | 10篇 |
2022年 | 16篇 |
2021年 | 18篇 |
2020年 | 37篇 |
2019年 | 29篇 |
2018年 | 23篇 |
2017年 | 16篇 |
2016年 | 37篇 |
2015年 | 40篇 |
2014年 | 38篇 |
2013年 | 72篇 |
2012年 | 88篇 |
2011年 | 121篇 |
2010年 | 54篇 |
2009年 | 59篇 |
2008年 | 84篇 |
2007年 | 86篇 |
2006年 | 85篇 |
2005年 | 82篇 |
2004年 | 86篇 |
2003年 | 67篇 |
2002年 | 47篇 |
2001年 | 48篇 |
2000年 | 29篇 |
1999年 | 24篇 |
1998年 | 16篇 |
1997年 | 22篇 |
1996年 | 23篇 |
1995年 | 21篇 |
1994年 | 25篇 |
1993年 | 18篇 |
1992年 | 17篇 |
1990年 | 14篇 |
1989年 | 12篇 |
1988年 | 15篇 |
1987年 | 14篇 |
1986年 | 11篇 |
1985年 | 19篇 |
1984年 | 22篇 |
1983年 | 11篇 |
1980年 | 18篇 |
1979年 | 14篇 |
1978年 | 14篇 |
1977年 | 11篇 |
1976年 | 14篇 |
1975年 | 11篇 |
1974年 | 9篇 |
1973年 | 11篇 |
1969年 | 9篇 |
1967年 | 9篇 |
排序方式: 共有1724条查询结果,搜索用时 343 毫秒
1.
Optical Review - This paper demonstrates a method to estimate the depth of a fluorescence object in turbid media using dual-wavelength excited photodynamic diagnosis, to aid in the invasion depth... 相似文献
2.
Dr. Christopher R. Opie Dr. Hidetoshi Noda Prof. Dr. Masakatsu Shibasaki Dr. Naoya Kumagai 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(18):4648-4653
The B3NO2 six-membered heterocycle (1,3-dioxa-5-aza-2,4,6-triborinane=DATB), comprising three different non-carbon period 2 elements, has been recently demonstrated to be a powerful catalyst for dehydrative condensation of carboxylic acids and amines. The tedious synthesis of DATB, however, has significantly diminished its utility as a catalyst, and thus the inherent chemical properties of the ring system have remained virtually unexplored. Here, a general and facile synthetic strategy that harnesses a pyrimidine-containing scaffold for the reliable installation of boron atoms is disclosed, giving rise to a series of Pym-DATBs from inexpensive materials in a modular fashion. The identification of a soluble Pym-DATB derivative allowed for the investigation of the dynamic nature of the B3NO2 ring system, revealing differential ring-closing and -opening behaviors depending on the medium. Readily accessible Pym-DATBs proved their utility as efficient catalysts for dehydrative amidation with broad substrate scope and functional-group tolerance, offering a general and practical catalytic alternative to reagent-driven amidation. 相似文献
3.
Hirokazu Nishimura 《International Journal of Theoretical Physics》1995,34(2):211-228
The notion of a manual, introduced and investigated in detail by Foulis, Randall, and their followers, has turned out to be further reaching than its originators had envisaged. Its omnipresence is comparable with the notion of a sheaf, whose significance is well recognized by every pure and applied mathematician. The principal concern of this paper is to give an appropriate vehicle, as general as possible, by which the theory of manuals can be developed. The vehicle is called an orthogonal category, which is akin to the notion of a category with coproducts. Orthogonal categories provide also a new perspective on the notion of a sheaf over a complete Boolean algebra, deepening our comprehension of Boolean mathematics and paving the way to quantum mathematics. 相似文献
4.
The electrode reaction of decamethylferrocene (DMFc) dissolved in a thin layer of a room-temperature molten salt (RTMS), 1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (C8mimC1C1N) or 1-octyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide (C8mimC2C2N), on a self-assembled monolayer-modified gold electrode is coupled with the ion transfer across the interface between the RTMS and the outer aqueous solution (W) to give a voltammogram whose shape resembles a voltammogram of a simple one-electron transfer process. The electroneutrality of the RTMS layer during the oxidation of DMFc to decamethylferricenium ion is maintained by the concomitant dissolution of C8mim+ ion from the RTMS phase to the W phase, and the reduction of decamethylferricenium ion to DMFc is accompanied by the transfer of either C1C1N- or C2C2N- from RTMS to W. The midpoint potential of the voltammogram varies with the concentration of the salt in the aqueous phase, C8mimCl or LiCnCnN (n = 1 or 2), in a Nernstian manner, showing that the phase-boundary potential between the RTMS and the W is controlled by the partition of these ions. Although the phase-boundary potential across the RTMS / W interface is Nernstian with respect to the ions common to both phases at the equilibrium, the polarization at the RTMS / W interface under current flow distorts the shape of the voltammograms, resulting in a wider peak separation in the voltammogram. 相似文献
5.
6.
S. Homma-Takeda Y. Nishimura Y. Watanabe H. Imaseki M. Yukawa 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(3):521-525
Stage-specific and age-dependent profiles of zinc, copper, manganese, and selenium in testis were examined in Wistar rats
by both inductively coupled argon plasma-mass spectrometry (ICP-MS) with a microdissection technique and in situ elemental
imaging of micro-PIXE analysis. The young adult animals (10 weeks old) contained higher levels of zinc and manganese in the
seminiferous tubules at stages VII-VIII than stages XI through VI and IX-X and the levels were higher than those of the immature
and old animals. Copper and selenium levels at stages VII-VIII of the young adult animals were also higher than those of the
immature and old animals. In stages VII and VIII, zinc was higher in the central area of the seminiferous epithelium, where
spermatozoa were localized, demonstrating a cell-specific property.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
7.
8.
9.
This paper proposes a two step algorithm for solving a large scale semi-definite logit model, which is appreciated as a powerful
model in failure discriminant analysis. This problem has been successfully solved by a cutting plane (outer approximation)
algorithm. However, it requires much more computation time than the corresponding linear logit model. A two step algorithm
to be proposed in this paper is intended to reduce the amount of computation time by eliminating a certain portion of the
data based on the information obtained by solving an associated linear logit model. It will be shown that this algorithm can
generate a solution with almost the same quality as the solution obtained by solving the original large scale semi-definite
model within a fraction of computation time. 相似文献
10.
Katsunori Nishimura Rie Hidaka Fumitoshi Hirayama Hidetoshi Arima Kaneto Uekama 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(1-2):85-88
Geometries, electronic properties and NMR-shielding of cucurbit[5]uril, decamethylcucurbit[5]uril, cucurbit[6]uril, cucurbit[7]uril,
and cucurbit[8]uril are investigated with DFT calculations. All molecules are highly symmetrical with a distinct geometric
flexibility. In addition with a characteristic partial charge distribution these findings account for their chemical complex
building ability. 相似文献