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排序方式: 共有127条查询结果,搜索用时 15 毫秒
1.
Dmitry Yu. Murzin 《Reaction Kinetics and Catalysis Letters》2007,90(2):225-232
Reaction route analysis is applied to visualize reaction networks in several heterogeneous catalytic reactions. Combination
of the theory of complex reactions with the notion of catalytic cycles results in a topological representation of complex
mechanisms with the nodes comprising all possible surface species including free sites and branches indicating interconnections
between reactions. 相似文献
2.
Application of linear free energy relationships (correlation between kinetics and thermodynamics) to catalytic hydrogenation
of aromatic compounds in the liquidphase over supported metal catalysts is discussed. 相似文献
3.
Anatoli Tchigvintsev Dmitri Tchigvintsev Robert Flick Ana Popovic Aiping Dong Xiaohui Xu Greg Brown Wenyun Lu Hong Wu Hong Cui Ludmila Dombrowski Jeong Chan Joo Natalia Beloglazova Jinrong Min Alexei Savchenko Amy A. Caudy Joshua D. Rabinowitz Alexey G. Murzin Alexander F. Yakunin 《Chemistry & biology》2013,20(11):1386-1398
4.
A. V. Chistyakov M. A. Gubanov V. Yu. Murzin P. A. Zharova M. V. Tsodikov V. V. Kriventsov A. E. Gekhman I. I. Moiseev 《Russian Chemical Bulletin》2014,63(1):88-93
The features of ethanol conversion into hydrocarbons C4-C12 in the presence of the novel catalyst Pd-Zn/γ-alumina and pilot zeolite system Pd-Zn/MFI/γ-alumina were studied (MFI is high-siliceous zeolite with ZSM-5 type structure). The structure of active sites changes noticeably in the course of preliminary activation and catalytic reaction. High selectivity and stability of the zeolite-containing Pd-Zn catalyst in alcohol conversion into hydrocarbon components of fuels is related to the stable composition of the alloy that forms clusters PdZn. At the same time, the alumina-based catalyst loses stability due to zinc diffusion from the alloy into γ-Al2O3 to form the spinel structure. 相似文献
5.
Dmitry Yu. Murzin 《Reaction Kinetics and Catalysis Letters》2007,91(1):37-43
The general form for adsorption on nanoparticles is presented. Conditions for the validity of Langmuir adsorption isotherm
for supported nanoparticles are discussed. 相似文献
6.
V. P. Medvedev V. V. Chapurkin A. V. Murzin M. A. Vaniev V. I. Frolova G. V. Medvedev I. A. Novakov 《Polymer Science Series D》2018,11(2):174-178
The curing of oligodienediol with a combined system consisting of a polyisocyanate and a (meth)acrylate-containing compound, which allows it to be structured with the polyisocyanate both at the terminal hydroxyl groups and double bonds due to the (meth)acrylate component, has been studied. The effect of the concentration of the (meth)acrylate component and a peroxide initiator to the degree of cross linking and strength properties of elastomers has been revealed. It has been shown that the participation of oligomer double bonds to form a vulcanization structure, creating the effect of “healing” defects from functional heterogeneity, allows one to increase the degree of cross linking and strength properties of polyurethanes. 相似文献
7.
Kinetics and Catalysis - The review is focused on requirements for technical bifunctional catalysts containing, in addition to a metal phase and an acid support (zeolite), various components... 相似文献
8.
The hole dynamics and emission processes in degenerate band semiconductors in strong crossedE B fields were studied both theoretically and experimentally. The Luttinger effective mass Hamiltonian was used to study the Landau level energy spectrum in anisotropic valence bands of Ge. The dependence of the energy spectrum onE,H fields orientation is analysed. The role of quantum effects, such as interaction and mixing of light and heavy hole states in the scattering process and Landau level population is studied. The results of experimental studies of stimulated emission spectra for intersub-band and cyclotron transitions as well as their dependence onE,H field orientation are presented, the experimental data being in good agreement with the quantum model calculations. 相似文献
9.
Overview of catalytic methods for production of next generation biodiesel from natural oils and fats
M. Sn?re P. M?ki-Arvela I. L. Simakova J. Myllyoja D. Yu. Murzin 《Russian Journal of Physical Chemistry B, Focus on Physics》2009,3(7):1035-1043
Production of biodiesel from natural oils and fats can be achieved using various technologies briefly discussed in this review.
A particular appealing concept for production of green diesel is selective catalytic deoxygenation of renewables leading to
diesel fuel products. This reaction can be performed over Pd on active carbon supports with saturated and unsaturated fatty
acids and their derivatives. 相似文献
10.
Hadron production in lepton-nucleus interactions at high energies is considered in the framework of developing Monte Carlo event generator HARDPING (HARD Probe INteraction Generator). Such effects as formation length, energy loss and multiple rescattering for produced hadrons and their constituents are implemented in the HARDPING 2.0 generator. Available data from HERMES collaboration on hadron production in lepton-nucleus collisions are described by the present version of the HARDPING generator in a reasonable agreement. 相似文献