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1.
Zinc polyoxometalate on activated carbon: an efficient catalyst for selective oxidation of alcohols with hydrogen peroxide 下载免费PDF全文
[PW11ZnO39]5? was immobilized on activated carbon and characterized using Fourier transform infrared, X‐ray diffraction, Brunauer–Emmett–Teller and elemental analysis techniques. Effective oxidation of various alcohols with hydrogen peroxide was performed in the presence of this catalyst. Easy separation of the catalyst from the reaction mixture, cheapness, high activity and selectivity, stability as well as retained activity in subsequent catalytic cycles make this supported catalyst suitable for small‐scale synthesis. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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We present an asymptotic analysis of the boundary-generated, small-amplitude, high-frequency waves in a one-dimensional, semi-infinite, viscoelastic solid characterized by a single-integral constitutive functional. The equations governing the wave motion constitute a 2×2 system of hyperbolic Volterra integrodifferential equations. The method of analysis is based on a single-wave expansion of nonlinear geometric optics. 相似文献
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Khalil MM Mohamed HA El-Medani SM Ramadan RM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1341-1347
Reaction of Cr(CO)(6) with 2-(2'-pyridyl)benzimidazole (pbiH) under reduced pressure resulted in the formation of the dinuclear complex [Cr(2)(CO)(6)(pbiH)(2)]. Infra-red (IR) spectroscopy revealed the presence of terminal and bridge Cr-CO bonds. Interaction of M(CO)(6), M=Cr, Mo and W, with pbiH in the presence of 2,2'-bipyridine (bpy) gave the tetracarbonyl complexes [M(CO)(4)(pbiH)].bpy. Spectroscopic studies of the complexes indicated the presence of hydrogen bonding between the bpy nitrogen and the NH group of pbiH. Reactions of M(CO)(6) with pbiH in the presence of PPh(3) gave the tricarbonyl monosubstituted derivatives [M(CO)(3)(PPh(3))(pbiH)]. The spectroscopic studies of the complexes suggested the proposed structures. 相似文献
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Ibrahim El-Sayed El-Kholy Morcos Michael Mishrikey Hassan Mostafa Feid-Allah 《Journal of heterocyclic chemistry》1981,18(1):105-110
The reaction of piperidine, morpholine, piperazine or dimethylamine with several coumarins, 3-bromocoumarin, 4,6-diaryl-2H-pyran-2-ones and 3-bromo-4,6-diaryl-2H-thiopyran-2-ones gave o-hydroxycinnamic acid amides, benzofurans, open-chain δ-oxoamides and thiophene derivatives, respectively. 相似文献
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Micro-Raman spectroscopy was used to investigate the selective adsorption of methanol/water mixtures on the surface of [60] fullerene nanospheres. C60 molecules were dispersed in methanol/water mixtures with different methanol molar fractions ranging between 1 and 0.5. The Raman active pentagon pinch mode shifted significantly (±4 cm−1) as the mixture composition was changed. The shift in the Raman mode was sinusoidal in nature indicating that methanol then water is adsorbed preferentially on the fullerene surface at different mixture compositions. The observed behavior is attributed to structure forming effects of alcohol/water mixtures and the shape and size effect of fullerene surface. 相似文献
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Minoo Dabiri Peyman Salehi Mostafa Baghbanzadeh Yasamin Vakilzadeh Shadi Kiani 《Monatshefte für Chemie / Chemical Monthly》2007,12(2):595-597
Bis(indolyl)methanes were synthesized by the reaction of indole derivatives and aromatic and aliphatic aldehydes in the presence
of diammonium hydrogen phosphate as a solid catalyst under solvent-free conditions. This methodology offers significant improvements
for the synthesis of bis(indolyl)methanes with regard to the yield of products, simplicity in operation, and green aspects
by avoiding toxic catalysts and solvents. 相似文献
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Density functional calculations were performed on bonding and structural features of [(ηn-BH4)TM(CO)4]− (n = 1, 2, 3; TM = Cr, Mo) complexes. Calculations show that the ground state is bidentate which is in good agreement with experimental results. It has been found that the bridge and terminal hydrogen atoms will interchange by two pathways: (i) twist of BH4 about one of the bridge B-H and (ii) twist of BH4 about one of the terminal B-H. The molecular orbital calculations and natural bond orbital methodologies for different isomers of these complexes have been evaluated. The final results indicate that case (i) is more preferable relative to another case. 相似文献
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Trimethyl phosphite selectively removes the N-1-oxygen in N-(3-methyl-2-quinoxaloyl) L-α-amino ester-1,4-dioxides, whereas it removes the N-4-oxygen in the corresponding series of dioxides lacking the C3-Me. This selectivity reversal reflects the relative strength of the intrahydrogen-bridging to the N-1-oxygen. The monoxides having the favourable N-oxygen are not reduced to the quinoxalines, implying that the reagent requires doubling of the N-oxide function for deoxygenation. However, alkaline sodium dithionite removes the N-1-oxygen in both series of the amino acid-dioxides, as well as in the parent quinoxaline-2-carboxylic acid-dioxides, a result that contradicts the report stating removal of the N-4-oxygen. The N-oxygenated quinoxalinium ion ( 145 or 159) prevails in the MS of the 4-oxides, but it is not observed (<1%) for the isomeric 1-oxides. 1H NMR, 13C NMR and UV spectral data also offer diagnostic criteria for differentiation between the isomeric 1- and 4-oxides. Aryl-heteryl “interaction” (as revealed by 1H NMR, though not by 13C NMR in the aromatic amino ester dioxides) is not manifested in the corresponding monoxides. 相似文献