Courants caractéristiques et analyse de SEREigen currents and RCS analysis

In this Note, we return to the theory of characteristic modes which was introduced 30 years ago for electromagnetic scattering problems. A simple mathematical framework is proposed and complete definitions are given. The potential interest of this theory in terms of Radar Cross Section (RCS) analysis is then discussed, especially in the low frequency case. Finally, a 3-D example is presented to illustrate the efficiency of this decomposition. To cite this article: Y. Morel et al., C. R. Mecanique 332 (2004).     

Toward the Rational Design of Galactosylated Glycoclusters That Target Pseudomonas aeruginosa Lectin A (LecA): Influence of Linker Arms That Lead to Low‐Nanomolar Multivalent Ligands

Anti‐infectious strategies against pathogen infections can be achieved through antiadhesive strategies by using multivalent ligands of bacterial virulence factors. LecA and LecB are lectins of Pseudomonas aeruginosa implicated in biofilm formation. A series of 27 LecA‐targeting glycoclusters have been synthesized. Nine aromatic galactose aglycons were investigated with three different linker arms that connect the central mannopyranoside core. A low‐nanomolar (K_d=19 nm , microarray) ligand with a tyrosine‐based linker arm could be identified in a structure–activity relationship study. Molecular modeling of the glycoclusters bound to the lectin tetramer was also used to rationalize the binding properties observed.     

An SIS waveguide heterodyne receiver for 600 HGz-635 GHz

A waveguide SIS heterodyne receiver using a Nb/AlO_X/Nb junction has been built for astronomical observations of molecular transitions in the frequency range 600 GHz - 635 GHz, and has been successfully used at the Caltech Submillimeter Observatory (CSO). We report double sideband (DSB) receiver noise temperatures as low as 245 K at 600 GHz -610 GHz, and near 300 K over the rest of the bandwidth. These results confirm that SIS quasiparticle mixers work well at submillimeter-wave frequencies corresponding to photon energies of at least 90% of the superconductor energy gap. In addition, we have systematically investigated the effect on the receiver performance of the overlap between first-order and second-order photon steps of opposite sign at these frequencies. The receiver noise increases by as much as 40% in the region of overlap. We infer potential limitations for operating submillimeter-wave Nb/AlO_x/Nb mixers.     

Dual-frequency single-axis laser using a lead lanthanum zirconate tantalate (PLZT) birefringent etalon for millimeter wave generation: beyond the standard limit of tunability

We demonstrate the generation of optically carried, broadly tunable, millimeter-wave signals with a dual-frequency single-axis Nd:YAG laser. A frequency difference as high as 127 GHz is reached thanks to an intracavity electro-optically tunable etalon made of lead zirconate tantalate (PLZT) ceramic. We show that the available frequency range is actually limited by the bandwidth of the amplification medium, namely, far beyond the usually accepted free spectral range value in the case of a single-axis laser. Both coarse discrete and fine continuous tunabilities are obtained with the same voltage-controlled device, opening the way to widely tunable low-phase-noise optically carried submillimeter or even terahertz sources.     

A local hermitian RBF meshless numerical method for the solution of multi‐zone problems

The local Hermitian interpolation (LHI) method is a strong‐form meshless numerical technique in which the solution domain is covered by a series of small and heavily overlapping radial basis function (RBF) interpolation systems. Aside from its meshless nature and the ability to work on very large scattered datasets, the main strength of the LHI method lies in the formation of local interpolations, which themselves satisfy both boundary and governing PDE operators, leading to an accurate and stable reconstruction of partial derivatives without the need for artificial upwinding or adaptive stencil selection. In this work, an extension is proposed to the LHI formulation which allows the accurate capture of solution profiles across discontinuities in governing equation parameters. Continuity of solution value and mass flux is enforced between otherwise disconnected interpolation systems, at the location of the discontinuity. In contrast to other local meshless methods, due to the robustness of the Hermite RBF formulation, it is possible to impose both matching conditions simultaneously at the interface nodes. The procedure is demonstrated for 1D and 3D convection–diffusion problems, both steady and unsteady, with discontinuities in various PDE properties. The analytical solution profiles for these problems, which experience discontinuities in their first derivatives, are replicated to a high degree of accuracy. The technique has been developed as a tool for solving flow and transport problems around geological layers, as experienced in groundwater flow problems. The accuracy of the captured solution profiles, in scenarios where the local convective velocities exceed those typically encountered in such Darcy flow problems, suggests that the technique is indeed suitable for modeling discontinuities in porous media properties. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 27: 1201–1230, 2011     

Multiplexed binding determination of seven glycoconjugates for Pseudomonas aeruginosa lectin I (PA-IL) using a DNA-based carbohydrate microarray

The binding of seven multivalent glycoconjugates displaying linear or antenna-like structures and different electronic environments were evaluated towards PA-IL on a DNA-based carbohydrate microarray. The affinity can be modulated by the charge and the topology of the galactosylated derivatives.     

On the approximation of a smooth surface with a triangulated mesh

We approximate the normals and the area of a smooth surface with the normals and the area of a triangulated mesh whose vertices belong to the smooth surface. Both approximations only depend on the triangulated mesh (which is supposed to be known), on an upper bound on the smooth surface's curvature, on an upper bound on its reach (which is linked to the local feature size) and on an upper bound on the Hausdorff distance between both surfaces.

We show in particular that the upper bound on the error of the normals is better when triangles are right-angled (even if there are small angles). We do not need every angle to be quite large. We just need each triangle of the triangulated mesh to contain at least one angle whose sinus is large enough.     

Simplicial elimination schemes,extremal lattices and maximal antichain lattices

Fix a partial order P=(X, <). We first show that bipartite orders are sufficient to study structural properties of the lattice of maximal antichains. We show that all orders having the same lattice of maximal antichains can be reduced to one representative order (called the poset of irreducibles by Markowsky [14]). We then define the strong simplicial elimination scheme to characterize orders which have distributive lattice of maximal antichains. The notion of simplicial elimination corresponds to the decomposition process described in [14] for extremal lattices. This notion leads to simple greedy algorithms for distributivity checking, lattice recognition and jump number computation. In the last section, we give several algorithms for lattices and orders.     

Polymer-nanoparticle complexes: from dilute solution to solid state

We report on the formation and the structural properties of "supermicellar" aggregates made from mineral nanoparticles and polyelectrolyte-neutral block copolymers in aqueous solutions. The mineral particles put under scrutiny are ultrafine and positively charged yttrium hydroxyacetate nanoparticles. Combining light, neutron, and X-ray scattering experiments, we have characterized the sizes and the aggregation numbers of the organic-inorganic complexes. We have found that the hybrid aggregates have typical sizes in the range of 100 nm and exhibit a remarkable colloidal stability with respect to ionic strength and concentration variations. Solid films with thicknesses up to several hundreds of micrometers were cast from solutions, resulting in a bulk polymer matrix in which nanoparticle clusters are dispersed and immobilized. It was found in addition that the structure of the complexes remains practically unchanged during film casting.     

Characterisation of ethoxylated fatty chains of anionic surfactants and determination of residual ethoxylated fatty alcohols

Bachus et al. [1] recently described a new derivatisation method using 2-furoyl chloride for the characterisation of mixtures of polyethoxylated alcohols and their corresponding sulfates. This paper deals with the control of the derivatisation steps; hydrolysis and extraction conditions were optimised. The method is extended to the characterisation of alkyl sulfosuccinates, alkyl sulfoacetates and alkyl phosphates and to the analysis of residual polyethoxylated alcohols in surfactants. Extraction of non-ionic compounds using solid-phase extraction cartridges was performed before derivatisation. Residual amounts of alcohol were determined in five commercial anionic surfactants. Moreover, direct derivatisation without preliminary SPE in the same anionic surfactants proved to be efficient for dry samples.