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1.
Marc Halpern Yoel Sasson Itamar Willner Mordecai Rabinovitz 《Tetrahedron letters》1981,22(18):1719-1722
The effects of water molecules and quat structure are shown to be significant in determining the behavior of alkylation reactions of weakly acidic carbon acids under PTC/OH? conditions. 相似文献
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Sternfeld T Thilgen C Hoffman RE Del Rosario Colorado Heras M Diederich F Wudl F Scott LT Mack J Rabinovitz M 《Journal of the American Chemical Society》2002,124(20):5734-5738
Reduction of the two "closed" [6,6] methanofullerenes, [6,6]C(61)H(2) (1) and [6,6]C(71)H(2) (5), to the corresponding hexaanions with lithium metal causes the bridgehead-bridgehead bonds to open, at least partially, and this change gives rise to diamagnetic ring currents in the resulting homoconjugated six-membered rings (6-MRs). These new ring currents shield the overlying hydrogen atoms on the methylene bridge and induce upfield shifts of 1.60 and 0.11 ppm in their (1)H NMR resonances, respectively. Analogous reduction of the already "open" [5,6]methanofullerenes, [5,6]C(61)H(2) (2) and [5,6]C(71)H(2) (3 and 4), only slightly enhances the shielding of the hydrogen atoms over the homoconjugated 6-MRs (upfield shifts of 0.13, 0.68, and 0.14 ppm, respectively) but leads to exceptionally strong diamagnetic ring currents in the homoconjugated five- membered rings (5-MRs), as evidenced by dramatic shielding of the hydrogen atoms situated over them (upfield shift of 5.01, 6.78, and 1.63 ppm, respectively). The strongest shielding is seen for the hydrogen atom sitting over the 5-MR at the pole of C(71)H(2)(6)(-) (delta = -0.255 ppm) indicating that the excess charge density is concentrated at the poles. 相似文献
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Roy E. Hoffman Noach Treitel Mordecai Rabinovitz 《Magnetic resonance in chemistry : MRC》2001,39(8):489-494
Isotope shifts are a well-established tool for structural analysis by NMR. The substitution of a protium with a deuterium is the most widely studied of these effects. However, such studies call for specific deuteration that requires complex synthetic techniques owing to the low natural abundance of deuterium. 13C occurs at a higher natural abundance and couples strongly with its attached proton. We have developed and refined a method to reliably observe these much smaller shifts without needing to resort to chemical synthesis. We show that carbon induced isotope shifts reflect structural features. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
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Doubly charged systems derived from fused benzenoid polycycles reveal an unquenched delocalization of 4 n π-electrons and hence are predicted to possess antiaromatic character. The magnitude of the paratropic 1H NMR chemical shifts, due solely to the paramagnetic secondary field sustained in these species, was found to depend linearly upon the magnitude of LUMO-HOMO energy gaps of the corresponding systems. The existence of such a correlation enables a comprehensive treatment of the various factors which determine the antiaromatic character and the subtle interrelations between those factors. This, in turn, leads to a deeper understanding of antiaromaticity. 相似文献
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This paper describes the regioselective biohydroxylation of 7-azabrendane and 6-azatwistane derivatives. 相似文献
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Mordecai Avriel 《Mathematical Programming》1972,2(1):309-323
A family of real functions, calledr-convex functions, which represents a generalization of the notion of convexity is introduced. This family properly includes the family of convex functions and is included in the family of quasiconvex functions. Some properties ofr-convex functions are derived and relations with other generalizations of convex functions are discussed.Portions of this paper were presented at the 7th Mathematical Programming Symposium 1970, The Hague, The Netherlands.Research for this paper was supported in part by the Gerard Swope Fund at the Technion. 相似文献
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Mordecai Lewin 《Journal of Combinatorial Theory, Series A》1974,16(2):131-146
Subsets of a Cartesian product X × Y, where X and Y are arbitrary sets, are considered as a generalization of incidence matrices. Minimal cover, essential set etc. are introduced in a stronger sense and their properties discussed. The existence of a minimal cover for an arbitrary generalized incidence matrix is proved. As an application a previous result is extended. 相似文献
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