Highly Proton-Conductive Zinc Metal-Organic Framework Based On Nickel(II) Porphyrinylphosphonate

The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF ( IPCE-1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10⁻³ S cm⁻¹ at 75 °C and 80 % relative humidity).     

Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes

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Purcell Effect and Nonlinear Behavior of the Emission in a Periodic Structure Composed of InAs Monolayers Embedded in a GaAs Matrix

Enhancement of spontaneous emission in a resonant Bragg quantum well (QW) structure with 60 periods of triple InAs monolayers embedded in a GaAs matrix is studied experimentally and theoretically. From measurements of the time‐resolved photoluminescence, besides the QW exciton at 1.47 eV, a specific super‐radiant (SR) emission demonstrating nonlinear properties is found. The SR mode shows a near‐quadratic dependence of intensity on excitation power, while its energy position follows the Bragg condition. It is revealed that the SR mode shows a peculiar non‐monotonic dependence of intensity on direction, with a maximum observed at approximately 40°. The enhancement in the SR emission at a specific direction is correlated well with suggested theoretical consideration of the modal Purcell factor for periodic quantum well structures.     

An invariant of tangle cobordisms

We construct a new invariant of tangle cobordisms. The invariant of a tangle is a complex of bimodules over certain rings, well-defined up to chain homotopy equivalence. The invariant of a tangle cobordism is a homomorphism between complexes of bimodules assigned to boundaries of the cobordism.

     

Solving Problems with Min-Type Functions by Disjunctive Programming

We consider applications of disjunctive programming to global optimization and problems with equilibrium constraints. We propose a modification of the algorithm of F. Beaumont for disjunctive programming problems and show its numerical efficiency.     

Multidimensional transonic shocks and free boundary problems for nonlinear equations of mixed type

We establish the existence and stability of multidimensional transonic shocks for the Euler equations for steady potential compressible fluids. The Euler equations, consisting of the conservation law of mass and the Bernoulli law for the velocity, can be written as a second-order, nonlinear equation of mixed elliptic-hyperbolic type for the velocity potential. The transonic shock problem can be formulated into the following free boundary problem: The free boundary is the location of the transonic shock which divides the two regions of smooth flow, and the equation is hyperbolic in the upstream region where the smooth perturbed flow is supersonic. We develop a nonlinear approach to deal with such a free boundary problem in order to solve the transonic shock problem. Our results indicate that there exists a unique solution of the free boundary problem such that the equation is always elliptic in the downstream region and the free boundary is smooth, provided that the hyperbolic phase is close to a uniform flow. We prove that the free boundary is stable under the steady perturbation of the hyperbolic phase. We also establish the existence and stability of multidimensional transonic shocks near spherical or circular transonic shocks.

     

Characteristics of high-power radiating imploding discharge with cold start

A qualitative model of the dynamics of a multiterawatt radiating Z-pinch with cold start and high rate of current rise is proposed. The model is used to analyze discharges with currents I ～ 2–5 MA (with dI/dt > 10¹³ A/s) through uniform or structured plasma-producing loads, including wire arrays. The most important consequence of cold start is that spatially nonuniform plasma production is prolonged to almost the entire current rise time. Under these conditions, the Ampére force begins to play a dominant role in the plasma dynamics before the plasma-producing load is completely transformed into an accelerated plasma. The results of computations of wire-array vaporization are presented. A formula is proposed for estimating the highest attainable velocity of plasma flow into a heterogeneous liner driven by the Ampére force. It is shown that local imbalance between radial motion of the produced plasma and supply of the plasma-producing substance to be ionized leads to axially nonuniform breakthrough of magnetic flux into the liner, which precedes plasma collapse. The magnetic-flux breakthrough gives rise to a chaotic azimuthal-axial plasma structure consisting of radial plasma jets of relatively small diameter, which is called a radial plasma rainstorm. The breaking-through azimuthal magnetic flux obstructs further current flow in the breakthrough region. Analyses of Z-pinch implosion based on the theory of Rayleigh-Taylor instability or the snowplow model are incorrect under the plasma-rainstorm conditions. The processes taking place in a stagnant Z-pinch include conversion of the energy carried by the current-generated magnetic field into turbulent MHD flow of the ion component of the plasma, its convective mixing with magnetic field, heating, energy transfer from ions to electrons, and emission from the plasma. Under typical experimental conditions, emission plays a key role in the energy balance in an imploding pinch. Z-pinch is modeled by an electric-circuit component that has a time-dependent nonlinear impedance and consumes the magnetic energy supplied by a generator through a magnetically insulated transmission line (MITL). The peak power reached in the circuit is comparable to the peak soft X-ray power output emitted by the pinch in terms of magnitude and timing. Optimum matching conditions are formulated for the generator-MITL-pinch circuit.     

A mathematical model of the response of the semicircular canal and otolith to vestibular system rotation under gravity

A mathematical model of the system composed of two sensors, the semicircular canal and the sacculus, is suggested. The model is described by three lines of blocks, each line of which has the following structure: a biomechanical block, a mechanoelectrical transduction mechanism, and a block describing the hair cell ionic currents and membrane potential dynamics. The response of this system to various stimuli (head rotation under gravity and falling) is investigated. Identification of the model parameters was done with the experimental data obtained for the axolotl (Ambystoma tigrinum) at the Institute of Physiology, Autonomous University of Puebla, Mexico. Comparative analysis of the semicircular canal and sacculus membrane potentials is presented. __________ Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 11, No. 7, pp. 207–220, 2005.