D3h‐Symmetric Porphyrin‐Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One‐Nanometer‐Sized Cavity

The one‐step synthesis of D_3h‐symmetric cyclic porphyrin trimers 1 composed of three 2,2′‐[4,4′‐bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel‐mediated reductive coupling of meso‐5,15‐bis(6‐chloro‐4‐methoxycarbonylpyrid‐2‐yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X‐ray crystallography. Treatment of an η³‐allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η³‐allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands.     

A perfect one-factorization ofK 36

In this paper, a perfect one-factorization ofK ₃₆ is given, which is factor-1-rotational.     

Accelerated glycosylation under frozen conditions

O-Glycosylations using thiomethyl glycosides as donors were compared under both frozen and unfrozen conditions. In the presence of MeOTf as a promoter, enormous rate acceleration was observed when the glycosylation was conducted in p-xylene below its freezing point.     

Gaudin Model,KZ Equation and an Isomonodromic Problem on the Tours

This Letter presents a construction of isospectral problems on the torus. The construction starts from an SU(n) version of the XYZ Gaudin model recently studied by Kuroki and Takebe within the context of a twisted WZW model. In the classical limit, the quantum Hamiltonians of the generalized Gaudin model turn into classical Hamiltonians with a natural r-matrix structure. These Hamiltonians are used to build a nonautonomous multi-time Hamiltonian system, which is eventually shown to be an isomonodromic problem on the torus. This isomonodromic problem can also be reproduced from an elliptic analogue of the KZ equation for the twisted WZW model. Finally, a geometric interpretation of this isomonodromic problem is discussed in the language of a moduli space of meromorphic connections.     

Hierarchy structure in integrable systems of gauge fields and underlying Lie algebras

An improved version of Nakamura's self-dual Yang-Mills hierarchy is presentd and its symmetry contents are studied. The new hierarchy as well as the previous one represents a set of commuting dynamical flows in an infinite dimensional manifolds of loop type, but includes a large set of dependent variables. Because of new degrees of freedom the theory acquires a more symmetric form with richer structures. For example it allows a large symmetry algebra of Riemann-Hilbert type, which is actually a direct sum of two subalgebras (left and right). This phenomenon is basically the same as observed recently by Avan and Bellon on the case of principal chiral models. In addition to these rather familiar symmeties, a new type of symmetries referred to as coordinate transformation type are also introduced. Generators of the above dynamical flows are all included therein. These two types of symmetries altogether form a big Lie algebra, which lead to more satisfactory understanding of symmetry properties of integrable systems of guage fields.     

Fluorescence modification of Gb3 oligosaccharide and rapid synthesis of oligosaccharide moieties using fluorous protective group

The use of the bisfluorous chain-type propanoyl (Bfp) group as a fluorous protective group made it possible to rapidly synthesize the Gb2 and Gb3 oligosaccharide derivatives by a simple fluorous-organic extraction purification. Furthermore, the fluorescence-labeled Gb2 and Gb3 oligosaccharides were prepared as a potential Vero Toxins detecting reagent.     

Dispersionless Toda hierarchy and two-dimensional string theory

The dispersionless Toda hierarchy turns out to lie in the heart of a recently proposed Landau-Ginzburg formulation of two-dimensional string theory at self-dual compactification radius. The dynamics of massless tachyons with discrete momenta is shown to be encoded into the structure of a special solution of this integrable hierarchy. This solution is obtained by solving a Riemann-Hilbert problem. Equivalence to the tachyon dynamics is proven by deriving recursion relations of tachyon correlation functions in the machinery of the dispersionless Toda hierarchy. Fundamental ingredients of the Landau-Ginzburg formulation, such as Landau-Ginzburg potentials and tachyon Landau-Ginzburg fields, are translated into the language of the Lax formalism. Furthermore, a wedge algebra is pointed out to exist behind the Riemann-Hilbert problem, and speculations on its possible role as generators of extra states and fields are presented.     

Dynamical property of YFeMnO4

In order to interpret abrupt changes of distributions of orientations andmagnitudes of hyperfine fields in Mössbauer measurements of⁵⁷Fe in YFeMnO₄, a model is proposed. The origin is assumed to be not static but dynamic. Fluctuating fields are caused by spins in a fully frustrated spin system, namely, a Heisenberg spin system on a triangular lattice in a two-dimensional antiferromagnet. Extending the stochastic theory for the fluctuation between two states to that among many states with a Gaussian distribution, we fit the spectra with three parameters, hyperfine fieldH _hf, correlation time _c, andwidth of fluctuating field , within a limited condition of =_c=1. Obtained results represent the characteristic features of Mössbauer spectra well, in spite of a simplified model.     

Quasi-classical limit of Toda hierarchy andW-infinity symmetries

Previous results on quasi-classical limit of the KP hierarchy and itsW-infinity symmetries are extended to the Toda hierarchy. The Planck constant now emerges as the spacing unit of difference operators in the Lax formalism. Basic notions, such as dressing operators, Baker-Akhiezer functions, and tau function, are redefined.W _{1 +} symmetries of the Toda hierarchy are realized by suitable rescaling of the Date-Jimbo-Kashiara-Miwa vertex operators. These symmetries are contracted tow _{1 +} symmetries of the dispersionless hierarchy through their action on the tau function.