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1.
D3h‐Symmetric Porphyrin‐Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One‐Nanometer‐Sized Cavity
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Yohei Ohkoda Akane Asaishi Tomoya Namiki Tomoaki Hashimoto Midori Yamada Koichiro Shirai Yuta Katagami Dr. Tomoaki Sugaya Prof. Makoto Tadokoro Prof. Akiharu Satake 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11745-11756
The one‐step synthesis of D3h‐symmetric cyclic porphyrin trimers 1 composed of three 2,2′‐[4,4′‐bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel‐mediated reductive coupling of meso‐5,15‐bis(6‐chloro‐4‐methoxycarbonylpyrid‐2‐yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X‐ray crystallography. Treatment of an η3‐allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η3‐allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. 相似文献
2.
In this study, the nonlinear dynamic responses of a string are simulated using the Cellular Automata method based on the reflection rule. In the case of nonlinear systems, the velocity of wave propagation is not constant and depends on the amplitude. A new treatment of the dynamic time step is proposed for the Cellular Automata method considering the effect of the propagation velocity. As numerical examples, first, the dynamic responses of a string with linear characteristic are simulated using the Cellular Automata method. A typical resonance curve can be obtained. Second, the dynamic responses of a string with nonlinear characteristic are simulated using the proposed method. Some characteristic types of vibration can be obtained. It is concluded that the linear and nonlinear dynamic responses of a string may be obtained by simulation using the Cellular Automata method. 相似文献
3.
R. Bairava Ganesh Hitoshi Matsuo Takahiro Kawamura Yoshihiro Kangawa Koji Arafune Yoshio Ohshita Masafumi Yamaguchi Koichi Kakimoto 《Journal of Crystal Growth》2008,310(11):2697-2701
Multicrystalline silicon was grown by unidirectional solidification method using the accelerated crucible rotation technique. The application of the accelerated crucible rotation technique in unidirectional solidification method induced growth striations across the axial direction of the grown crystal. This striation pattern was observed from carbon concentration distribution, obtained by using Fourier transform infrared spectroscopy. The generated striation pattern was found to be weak and discontinuous. Some striations were absent, probably due to back melting, caused during each crucible rotation. From the growth striations and applied time period in crucible rotation, the growth rate was estimated by using Fourier transformation analysis. 相似文献
4.
D. Kawamura A. Takita Y. Hayasaki N. Nishida 《Applied Physics A: Materials Science & Processing》2006,85(1):39-43
The morphology of a glass surface having a transparent coating processed with focused femtosecond laser pulses is investigated. The transparent coating is formed of poly-methyl methacrylate (PMMA). When the glass was coated with a PMMA film with a thickness of 2.8 μm, bumps were formed over a wide range of axial focus positions. The same laser pulse energy produced cavities when processing bare glass with no coating. The bumps were formed as a result of suppressing material emission from the glass surface by a shielding effect of plasma generated by ablation of the PMMA film and by physical blocking of the PMMA film. A thinner film with a thickness of 0.7 μm produced a reduced shielding effect, forming an exploded bump with a small pit at its center and debris around the periphery. PACS 44.10.+i; 61.80.Ba; 79.20.Ds 相似文献
5.
Midori Kobayashi Hitoshi Awoki Yoshimi Nakazaki Gisaku Nakamura 《Graphs and Combinatorics》1989,5(1):243-244
In this paper, a perfect one-factorization ofK
36 is given, which is factor-1-rotational. 相似文献
6.
Embeddings of the CAR (canonical anticommutation relations) algebra of fermions into the Cuntz algebra ?2 (or ?2
d
more generally) are presented by using recursive constructions. As a typical example, an embedding of CAR onto the U(1)-invariant subalgebra of ?2 is constructed explicitly. Generalizing this construction to the case of ?2
p
, an embedding of CAR onto the U(1)-invariant subalgebra of ?2
p
is obtained. Restricting a permutation representation of the Cuntz algebra, we obtain the Fock representation of CAR. We
apply the results to embed the algebra of parafermions of order p into ?2
p
according to Green's ansatz.
Received: 3 September 2001 / Accepted: 19 January 2002 相似文献
7.
8.
Chang-Kyu Kim A. Takaku M. Yamamoto H. Kawamura K. Shiraishi Y. Igarashi S. Igarashi H. Takayama N. Ikeda 《Journal of Radioanalytical and Nuclear Chemistry》1989,131(1):131-137
Ammonium uranates (AU) obtained by the addition of aqueous NH4 OH to a solution of UO2 (NO3)2 or the equilibrium reaction of UO3 · 2H2 O with the vapour over concentrated NH4 OH have been studied by X-ray diffraction (XRD) analysis, diffuse reflectance Fourier transform infrared spectrometry (DR-FTIR) and chemical analysis. Ammonia can be present as either NH3 or NH
4
+
. For precipitates obtained at a pH of 3.7, ammonia in the form of NH3 is predominant. For ammonium uranate obtained by reaction over concentrated NH4OH, most of the ammonia is bonded as NH
4
+
. The reaction mechanism and structures of the products are also discussed. 相似文献
9.
Synthesis and hypotensive activity of benzopyran derivatives 总被引:1,自引:0,他引:1
M Shiratsuchi K Kawamura T Akashi M Fujii H Ishihama Y Uchida 《Chemical & pharmaceutical bulletin》1987,35(2):632-641
10.