全文获取类型
收费全文 | 160篇 |
免费 | 8篇 |
专业分类
化学 | 134篇 |
晶体学 | 6篇 |
力学 | 1篇 |
数学 | 8篇 |
物理学 | 19篇 |
出版年
2022年 | 3篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 9篇 |
2011年 | 9篇 |
2010年 | 4篇 |
2009年 | 8篇 |
2008年 | 9篇 |
2007年 | 5篇 |
2006年 | 7篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1964年 | 1篇 |
1957年 | 1篇 |
1956年 | 1篇 |
1948年 | 1篇 |
1908年 | 3篇 |
排序方式: 共有168条查询结果,搜索用时 15 毫秒
1.
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of chromium(III), manganese(III), tin(II) and lead(II) are prepared and characterized by chemical analyses, spectroscopic methods (I.R. and electronic spectra), magnetic susceptibilities, conductivity measurements and mass spectra. The complexes are of the type M(R2dtc)n, where n is the oxidation number of the metal ion. Where possible a tentative stereochemistry of the complexes is discussed on the basis of the results obtained. In all the complexes the dithiocarbamate ligands show bidentate behaviour. 相似文献
2.
Michelangelo Gruttadauria Renato Noto Serena Riela 《Journal of heterocyclic chemistry》1998,35(4):865-869
The stereoselective synthesis of a 2-substituted tetrahydropyran with adjacent alkoxy-bearing stereogenic centre is described. The key steps of this synthesis were the stereoselective epoxidation of an allylic alcohol and the regioselective epoxide ring opening by lithium aluminum hydride. The regio and stereoselective synthesis of a trihydroxyselenide and a trihydroxysulfide is also described. The latter compounds are not suitable for cyclization to tetrahydrofuran ring. 相似文献
3.
Emiliano Bedini Antonella Carabellese Marialuisa Schiattarella Michelangelo Parrilli 《Tetrahedron》2005,61(23):5439-5448
3-Acetamido-3,6-dideoxy-d-galactopyranose (d-Fucp3NAc) is an aminosugar almost exclusively found in phytopathogenic O-antigens. The glycosylation reaction involving d-Fucp3NAc donors was studied with several rhamnosyl acceptors, revealing that the best yields and highest α-stereoselectivity were obtainable by coupling a N-phenyl trifluoroacetimidate glycosyl donor in a ternary mixture (dioxane/DME/toluene 4:1:1) as solvent. For the first time a synthetic access to α-d-Fucp3NAc containing oligorhamnans, that are interesting molecules for studying the effects of O-antigen model oligosaccharides on the modulation of plant response to bacteria, was reported. An example is the pentasaccharide repeating unit of the major O-antigen component from Pseudomonas syringae pv. holci IMV 8300, which was synthesized as its methyl glycoside. 相似文献
4.
Michelangelo L. Mangano 《Zeitschrift fur Physik C Particles and Fields》1993,58(4):651-658
We analyse the implications of the measurement ofB andJ/ψ inclusivep t distributions performed in \(p\bar p\) collisions by the UA1 and CDF experiments. 相似文献
5.
Cilia of hair cells are structurally similar to unilaminar phospholipid vesicles. The close juxtaposition of adjacent cilia is similar to the intervesicle distances found in groups of vesicles. Both cilia and vesicles operate in similar ionic environments. By comparing the cross section of cilia, which are cylinders with the cross section of vesicles, which are spherical, we can see how colloid theory can be applied to both cilia and vesicles. While vesicles have been studied as colloid particles, thus far colloid theory has not been applied to hair cell cilia. This paper presents a basic explanation of colloid theory in a simple graphic form that facilitates a colloid perspective of hair cell cilia behavior. A review of relevant hair cell cilia behavior supports the hypothesis that colloid knowledge is applicable to the problem of understanding cilia functionality in the hair cell. The electromagnetic nature of colloid forces allows for their involvement in the relatively high speed operation required of hair cells which are dealing with signals of up to 2×105 Hz. A fresh look at the biophysics of the hair cell from a colloid perspective may lower the barrier to a closer understanding of active mechanical sensory transduction, amplification and adaptation, and suggest a new domain for the application of colloid theory. 相似文献
6.
A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenyl- selenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved. 相似文献
7.
Summary Five-coordinate bis(benzeneseleninato)tris(ethylenediamine) cobalt (II)complexes are obtained by reaction of Co(H2O)2 (XC6 H4 SeO2)2 complexes (X = H, p-Cl, m-CI, p-Br, ni-Br, p-Me,p-NO2) with ethylenediamine. The diaquo complexes (one mole)react with ethylenediamine (three moles)to form O-seleninato derivatives. Spectral and magnetic properties show that the complexes are low-spin (s = 1/2) and,on the basis of the electronic spectra a distorted trigonal geometry,D
3h
, is suggested. Assignments for the electronic spectra are proposed. Conductivity data indicate that these derivatives are nonelectrolytes. Both ethylenediamine and [RSeO2 ]– behave as monodentate ligands. 相似文献
8.
9.
Veronica M. T. Lattanzio Biancamaria Ciasca Miriam Haidukowski Alessandro Infantino Angelo Visconti Michelangelo Pascale 《Journal of mass spectrometry : JMS》2013,48(12):1291-1298
Fusarium langsethiae, formally described as a new species over a decade ago, has been identified as the main producer of HT‐2 (HT2) and T‐2 (T2) toxins in Europe in small cereal grains. Mycotoxin contamination caused by this Fusarium species can represent a food safety hazard that deserves further attention. In the present work, the mycotoxin profile in wheat cultures of F. langsethiae is presented with particular reference to the production of major type‐A trichothecenes and their glucosyl derivatives. F. langsethiae isolates, representative of the major Italian wheat cultivation areas, were tested for the production of T2, HT2, diacetoxyscirpenol (DAS) and neosolaniol (NEO), and relevant glucosyl derivatives. Liquid chromatography‐tandem mass spectrometry (LC‐MS/MS) was used for the identification and chemical characterization of these metabolites. F. langsethiae isolates under investigation resulted to be potent producers of T2, HT2 and NEO. Furthermore, a well‐defined set of isolates, all originating from Central Italy, produced also DAS. All isolates were found to be able to produce HT2 glucosyl derivatives, whereas only traces of T2 glucoside were detected in one sample. Furthermore, two mono‐glucosyl derivatives of NEO and one mono‐glucoside derivative of DAS were identified and characterized. The screening for the presence/absence of glucosylated trichothecenes in analyzed fungal extracts revealed a general co‐occurrence of these derivatives with the parent toxin at levels that could be roughly estimated to account up to 37% of the relevant unconjugated toxin. This is the first report of the production of glucosylated trichothecenes by F. langsethiae cultured on small grains. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献