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1.
Recent advances in the synthesis of C-5-substituted analogs of 3,4-dihydropyrimidin-2-ones: A review
3,4-Dihydropyrimidin-2-ones act as a versatile scaffold in organic synthesis, which serves as a significant template for the development of various therapeutic agents and shows a wide spectrum of activities. The attractive application of 3,4-dihydropyrimidin-2-ones in organic synthesis is undoubtedly owing to C-5 ester group, which is responsible for the change in its bioactivity. Introduction of various groups like electron-withdrawing and electron-donating groups at positions 1, 2, 3, 5, and 6 greatly increased biological activity. Significant efforts have been undertaken to exploit different synthetic routes to synthesize various derivatives of 3,4-dihydropyrimidin-2-ones. This review article gives a comprehensive account of the synthetic utility of C-5 substitution of 3,4-dihydropyrimidin-2-ones used in the design and synthesis of different types of compounds with greater emphasis on recent literature. 相似文献
2.
Shape memory polymers are novel materials that can be easily formed into complex shapes, retaining memory of their original
shape even after undergoing large deformations. The temporary shape is stable and return to the original shape is triggered
by a suitable mechanism such as heating. In this paper, we develop constitutive equations to model the mechanical behavior
of crystallizable shape memory polymers. Crystallizable shape memory polymers are called crystallizable because the temporary
shape is fixed by a crystalline phase, while return to the original shape is due to the melting of this crystalline phase.
The modeling is done using a framework that was developed recently for studying crystallization in polymers ([28], [25], [27],
[31]) and is based on the theory of multiple natural configurations. In this paper we formulate constitutive equations for
the original amorphous phase and the semi-crystalline phase that is formed after the onset of crystallization. In addition
we model the melting of the crystalline phase to capture the return of the polymer to its original shape. The model has been
used to simulate a typical uni-axial cycle of deformation, the results of this simulation compare very well with experimental
data. In addition to this we also simulate circular shear of a hollow cylinder and present results for different cases in
this geometry. 相似文献
3.
4.
M. Barot J. A. de la Peñ a 《Proceedings of the American Mathematical Society》1999,127(3):647-655
Let be a finite dimensional algebra over an algebraically closed field . Assume for a connected quiver and an admissible ideal of . We study algebras which are derived equivalent to tubular algebras. If is strongly simply connected and has more than six vertices, then is derived tubular if and only if (i) the homological quadratic form is a non-negative of corank two and (ii) no vector of is orthogonal (with respect tho the homological bilinear form) to the radical of .
5.
Santosh S. Bhujbal Chawale Bhushankumar G. Kale Mayuri A. 《Journal of Analytical Chemistry》2022,77(4):473-483
Journal of Analytical Chemistry - HPTLC is a widely used tool in standardization of herbs because of its ability to estimate the presence of active components in samples. HPTLC-bioautography is a... 相似文献
6.
Ravi Madhukar Mawale Mayuri Vilas Ausekar Lubomír Prokeš Virginie Nazabal Emeline Baudet Tomáš Halenkovič Marek Bouška Milan Alberti Petr Němec Josef Havel 《Journal of the American Society for Mass Spectrometry》2017,28(12):2569-2579
Laser desorption ionization using time-of-flight mass spectrometer afforded with quadrupole ion trap was used to study As2Ch3 (Ch = S, Se, and Te) bulk chalcogenide materials. The main goal of the study is the identification of species present in the plasma originating from the interaction of laser pulses with solid state material. The generated clusters in both positive and negative ion mode are identified as 10 unary (S p +/– and As m +/– ) and 34 binary (As m S p +/– ) species for As2S3 glass, 2 unary (Se q +/– ) and 26 binary (As m Se q +/– ) species for As2Se3 glass, 7 unary (Te r +/– ) and 23 binary (As m Te r +/– ) species for As2Te3 material. The fragmentation of chalcogenide materials was diminished using some polymers and in this way 45 new, higher mass clusters have been detected. This novel approach opens a new possibility for laser desorption ionization mass spectrometry analysis of chalcogenides as well as other materials. 相似文献
7.
Mg isotope fractionation in biogenic carbonates of deep-sea coral, benthic foraminifera, and hermatypic coral 总被引:1,自引:0,他引:1
Yoshimura T Tanimizu M Inoue M Suzuki A Iwasaki N Kawahata H 《Analytical and bioanalytical chemistry》2011,401(9):2755-2769
High-precision Mg isotope measurements by multiple collector inductively coupled plasma mass spectrometry were applied for
determinations of magnesium isotopic fractionation of biogenic calcium carbonates from seawater with a rapid Mg purification
technique. The mean δ26Mg values of scleractinian corals, giant clam, benthic foraminifera, and calcite deep-sea corals were −0.87‰, −2.57‰, −2.34‰,
and −2.43‰, suggesting preferential precipitation of light Mg isotopes to produce carbonate skeleton in biomineralization.
Mg isotope fractionation in deep-sea coral, which has high Mg calcite skeleton, showed a clear temperature (T) dependence from 2.5 °C to 19.5 °C: 1,000 × ln(α) = −2.63 (±0.076) + 0.0138 (±0.0051) × T(R
2 = 0.82, p < 0.01). The δ26Mg values of large benthic foraminifera, which are also composed of a high-Mg calcite skeleton, can be plotted on the same
regression line as that for deep-sea coral. Since the precipitation rates of deep-sea coral and benthic foraminifera are several
orders of magnitude different, the results suggest that kinetic isotope fractionation may not be a major controlling factor
for high-Mg calcite. The Mg isotope fractionation factors and the slope of temperature dependence from deep-sea corals and
benthic foraminifera are similar to that for an inorganically precipitated calcite speleothem. Taking into account element
partitioning and the calcification rate of biogenic CaCO3, the similarity among inorganic minerals, deep-sea corals, and benthic foraminiferas may indicate a strong mineralogical
control on Mg isotope fractionation for high-Mg calcite. On the other hand, δ26Mg in hermatypic corals composed of aragonite has been comparable with previous data on biogenic aragonite of coral, sclerosponges,
and scaphopad, regardless of species differences of samples. 相似文献
8.
Copper is extracted at pH 5.5 with 3 × 10–4
M cryptand 222 in dichloromethane with 3 × 10–4
M erythrosine B as the counter-ion. It can be stripped with 0.5M perchloric acid and determined by atomic absorption spectrometry at 324.7 nm. Copper has been separated from multicomponent mixtures containing zinc, mercury, iron, cobalt, nickel and manganese, which are generally encountered in environmental samples. 相似文献
9.
Shape memory polymers are novel materials that can be easily formed into complex shapes, retaining memory of their original
shape even after undergoing large deformations. The temporary shape is stable and return to the original shape is triggered
by a suitable mechanism such as heating. In this paper, we develop constitutive equations to model the mechanical behavior
of crystallizable shape memory polymers. Crystallizable shape memory polymers are called crystallizable because the temporary
shape is fixed by a crystalline phase, while return to the original shape is due to the melting of this crystalline phase.
The modeling is done using a framework that was developed recently for studying crystallization in polymers ([28], [25], [27],
[31]) and is based on the theory of multiple natural configurations. In this paper we formulate constitutive equations for
the original amorphous phase and the semi-crystalline phase that is formed after the onset of crystallization. In addition
we model the melting of the crystalline phase to capture the return of the polymer to its original shape. The model has been
used to simulate a typical uni-axial cycle of deformation, the results of this simulation compare very well with experimental
data. In addition to this we also simulate circular shear of a hollow cylinder and present results for different cases in
this geometry.
Received: January 5, 2005 相似文献
10.
We report electron impact total cross sections, Q(T), for e-N(2)O scattering over an extensive range of impact energies approximately from 0.1 eV to 2000 eV. We employ an ab initio calculation using R-matrix formalism below the ionization threshold of the target and above it we use the well established spherical complex optical potential to compute the cross sections. Total cross section is obtained as a sum of total elastic and total electronic excitation cross sections below the ionization threshold and above the ionization threshold as a sum of total elastic and total inelastic cross sections. Ample cross section data for e-N(2)O scattering are available at low impact energies and hence meaningful comparisons are made. Good agreement is observed with the available theoretical as well as experimental results over the entire energy range studied here. 相似文献