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1.
We study the structure of the most common type of Riemannian submersions, namely those whose fibers are given by the orbits
of an isometric group action on a Riemannian manifold. Special emphasis is given to the case where the ambient space has nonnegative
curvature.
The first author was supported by research grant MTM2004-04794-MEC. Most of this work was done during a visit of the second
author to Madrid, financed in part by funds of the aforementioned grant. 相似文献
2.
The economic valuation of works of art is a decisive subject in the general field of valuation. Unlike in other areas of valuation, the explanatory power of the directly observable and quantifiable variables is very low, therefore, aesthetic criteria must be used to obtain valuation models with a greater explanatory power. Frequently, these aesthetic criteria are not always precise, and experts usually express them as an interval of values. This paper describes different valuation models that use the goal programming optimisation method to include explanatory variables of the closing price in the form of intervals of values. We have also modelled the possibility that an expert can determine the relevance of each observation in the formation of the valuation function depending on the degree of precision with which the variables have been defined. 相似文献
3.
4.
Juan A. Allegretto Agustín Iborra Dr. Juan M. Giussi Dr. Catalina von Bilderling Dr. Marcelo Ceolín Dr. Sergio Moya Dr. Omar Azzaroni Dr. Matias Rafti 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(54):12388-12396
This work reports on a novel and versatile approach to control the structure of metal–organic framework (MOFs) films by using polymeric brushes as 3D primers, suitable for triggering heterogeneous MOF nucleation. As a proof-of-concept, this work explores the use of poly(1-vinylimidazole) brushes primer obtained via surface-initiated atom transfer radical polymerization (SI-ATRP) for the synthesis of Zn-based ZIF-8 MOF films. By modifying the grafting density of the brushes, smooth porous films were obtained featuring inherently hydrophobic microporosity arising from ZIF-8 structure, and an additional constructional interparticle mesoporosity, which can be employed for differential adsorption of targeted adsorbates. It was found that the grafting density modulates the constructional porosity of the films obtained; higher grafting densities result in more compact structures, while lower grafting density generates increasingly inhomogeneous films with a higher proportion of interparticle constructional porosity. 相似文献
5.
In this paper we prove that weak solutions to the Diffusive Wave Approximation of the Shallow Water equations are locally bounded. Here, u describes the height of the water, z is a given function that represents the land elevation and f is a source term accounting for evaporation, infiltration or rainfall. 相似文献
6.
2D difference gel electrophoresis reference map of a Fusarium graminearum nivalenol producing strain
Matias Pasquali Tommaso Serchi Jenny Renaut Lucien Hoffmann Torsten Bohn 《Electrophoresis》2013,34(4):505-509
Fusarium graminearum is widely studied as a model for toxin production among plant pathogenic fungi. A 2D DIGE reference map for the nivalenol‐producing strain 453 was established. Based on a whole protein extract, all reproducible spots were systematically picked and analyzed by MALDI‐TOF/TOF, leading to the identification of 1102 protein species. The obtained map contributes to the annotation of the genome by identifying previously nondescribed hypothetical proteins and will serve as a reference for future studies aiming at deciphering F. graminearum biology and chemotype diversity. 相似文献
7.
Lakovaara Matias Sirviö Juho Antti Ismail Mostafa Y. Liimatainen Henrikki Sliz Rafal 《Cellulose (London, England)》2021,28(9):5433-5447
Cellulose - In this work, deep eutectic solvent (DES) based on imidazole and triethylmethylammonium chloride was used as a reaction medium for the esterification of cellulose nanofiber (CNF) and... 相似文献
8.
On the reactivity of naphthalene and biphenyl dianions: tying up loose ends concerning an SN2‐ET dichotomy in alkylation reactions 下载免费PDF全文
Inmaculada Blasco Henoc Pérez Albert Guijarro 《Journal of Physical Organic Chemistry》2015,28(6):388-395
Naphthalene and biphenyl dianions are interesting compounds that can be obtained by double reduction of the corresponding arenes in solution with certain alkali metals. These dianions are highly reactive and rather elusive species with very high laying and highly delocalized electrons. They share many aspects of the reactivity of the alkali metal they originated from and consequently behave primarily as strong electron transfer (ET) reagents. We report here kinetic evidence for a different type of reactivity in their alkylation reactions with alkyl fluorides. By using cyclopropylmethyl fluoride (c‐C3H5CH2F) as a very fast radical probe, we were able to settle that this alkylation does not involve the classical electron transfer reaction followed by radical coupling between diffusing radicals, but supports the alternative SN2 concerted mechanism, discerning thus this mechanistic SN2‐ET dichotomy. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
9.
Gonalo A. O. Tiago Inês A. S. Matias Ana P. C. Ribeiro Luísa M. D. R. S. Martins 《Molecules (Basel, Switzerland)》2020,25(24)
In this review, the roles of room temperature ionic liquids (RTILs) and RTIL based solvent systems as proposed alternatives for conventional organic electrolyte solutions are described. Ionic liquids are introduced as well as the relevant properties for their use in electrochemistry (reduction of ohmic losses), such as diffusive molecular motion and ionic conductivity. We have restricted ourselves to provide a survey on the latest, most representative developments and progress made in the use of ionic liquids as electrolytes, in particular achieved by the cyclic voltammetry technique. Thus, the present review comprises literature from 2015 onward covering the different aspects of RTILs, from the knowledge of these media to the use of their properties for electrochemical processes. Out of the scope of this review are heat transfer applications, medical or biological applications, and multiphasic reactions. 相似文献
10.
Inês A. S. Matias Ana P. C. Ribeiro Luísa M. D. R. S. Martins 《Molecules (Basel, Switzerland)》2020,25(23)
The direct, one-pot oxidation of ethane to acetic acid was, for the first time, performed using a C-scorpionate complex anchored onto a magnetic core-shell support, the Fe3O4/TiO2/[FeCl2{κ3-HC(pz)3}] composite. This catalytic system, where the magnetic catalyst is easily recovered and reused, is highly selective to the acetic acid synthesis. The performed green metrics calculations highlight the “greeness” of the new ethane oxidation procedure. 相似文献