Differentiation among some isomeric di- and trifunctional aromatic amines by plasma desorption mass spectrometry

Isomeric di- and trifunctional aromatic amines are easily differentiated on the basis of their plasma desorption (PD) mass spectra. Six series of aromatic amines were studied in the positive-ion mode. In each series, the differences observed in the PD mass spectra allow each isomer to be characterized. In the formation of molecular ions, these differences proceed from the competition between electron impact ionization and protonation. Several chemoselective or regioselective reactions such as hydrogenation, hydration, dimerization and some fragmentations also allow isomeric aromatic amines to be differentiated.     

A Markov Chain Application to Manpower Supply Planning

Markov chains have been suggested since the early sixties for modeling manpower supply, mostly in military, governmental and public agencies. An actual industrial application is presented. This will be of interest to managers as well as practitioners and students of operational research. The approach, use and validation of the Markov model are discussed, along with some limitations and extensions.     

Pair interaction of dislocations in two-dimensional crystals

The pair interaction between crystal dislocations is systematically explored by analyzing particle trajectories of two-dimensional colloidal crystals measured by video microscopy. The resulting pair energies are compared to Monte Carlo data and to predictions derived from the standard Hamiltonian of the elastic theory of dislocations. Good agreement is found with respect to the distance and temperature dependence of the interaction potential, but not regarding the angle dependence where discrete lattice effects become important. Our results on the whole confirm that the dislocation Hamiltonian allows a quantitative understanding of the formation and interaction energies of dislocations in two-dimensional crystals.     

Ferromagnetic hcp chromium in Cr/Ru(0001) superlattices

We report the first observation of a weak ferromagnetic state of Cr in Cr/Ru(0001) superlattices, based on magnetic hysteresis and corroborated by x-ray magnetic circular dichroism at the CrL(2,3) edges. In situ reflection high-energy electron diffraction, x-ray diffraction, and Cr K-edge polarized x-ray absorption investigations have shown that the Cr layers thinner than 8 angstroms adopt a slightly distorted hcp structure, accompanied by a large atomic volume expansion of up to 14% compared to the bcc packing volume. The expanded hcp structure clearly induces the observed ferromagnetism, in agreement with theory.     

Dynamic criteria for melting in two dimensions

The two-dimensional (2D) melting transition is analyzed on the basis of the long-time behavior of a modified Lindemann parameter in 2D gamma(L)(t) and the bond-angular correlation function g(6)(t). Using video microscopy complete positional data are obtained over five decades in time for an ensemble of superparamagnetic colloidal particles confined to an air-water interface. We find that each of the three phases (solid/hexatic/isotropic liquid) is uniquely characterized by the long-time behavior of gamma(L)(t), g(6)(t), and the non-Gaussian parameter of the relative neighbor-neighbor displacement.     

Partial clustering prevents global crystallization in a binary 2D colloidal glass former

A mixture of two types of super-paramagnetic colloidal particles with long-range dipolar interaction is confined by gravity to the flat interface of a hanging water droplet. The particles are observed by video microscopy and the dipolar interaction strength is controlled via an external magnetic field. The system is a model system to study the glass transition in 2D, and it exhibits partial clustering of the small particles (N. Hoffmann et al., Phys. Rev. Lett. 97, 078301 (2006)). This clustering is strongly dependent on the relative concentration of big and small particles. However, changing the interaction strength reveals that the clustering does not depend on the interaction strength. The partial clustering scenario is quantified using Minkowski functionals and partial structure factors. Evidence that partial clustering prevents global crystallization is discussed.     

Preparation and characterization of hollow spheres of rutile

Hollow spherical particles of rutile were obtained by coating colloidal polystyrene beads with a titanium oxide hydrate layer and subsequently calcining at elevated temperatures under an oxygen atmosphere. In order to investigate the optimum conditions for the preparation of these hollow beads the maximum temperature and heating rate were systematically varied. The dimensions of the voids and the shell thickness of the hollow beads can be tailored by the size of the polystyrene beads and the thickness of the inorganic layer, respectively.