排序方式: 共有15条查询结果,搜索用时 15 毫秒
1.
Bekzat ABDIKADYR Alp KILI Onur ALEV Serkan BÜYÜKK
SE Zafer Ziya
ZTÜRK 《Turkish Journal of Chemistry》2021,45(2):295
Pristine and WO3 decorated TiO2 nanorods (NRs) were synthesised to investigate n-n-type heterojunction gas sensing properties. TiO2 NRs were fabricated via hydrothermal method on fluorine-doped tin oxide coated glass (FTO) substrates. Then, tungsten was sputtered on the TiO2 NRs and thermally oxidised to obtain WO3 nanoparticles. The heterostructure was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Fabricated sensor devices were exposed to VOCs such as toluene, xylene, acetone and ethanol, and humidity at different operation temperatures. Experimental results demonstrated that the heterostructure has better sensor response toward ethanol at 200 °C. Enhanced sensing properties are attributed to the heterojunction formation by decorating TiO2 NRs with WO3. 相似文献
2.
S. E. Mangioni H. S. Wio 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(1):67-73
We analyze the effect of a colored non Gaussian noise on a model of
a random walker moving along a ratchet potential. Such a model was
motivated by the transport properties of motor proteins, like
kinesin and myosin. Previous studies have been realized assuming
white noises. However, for real situations, in general we could
expect that those noises be correlated and non Gaussian. Among other
aspects, in addition to a maximum in the current as the noise
intensity is varied, we have also found another optimal value of the
current when departing from Gaussian behavior. We show the relevant
effects that arise when departing from Gaussian behavior,
particularly related to current's enhancement, and discuss its
relevance for both biological and technological situations. 相似文献
3.
Mangioni SE Deza RR Toral R Wio HS 《Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics》2000,61(1):223-232
A recently introduced lattice model, describing an extended system which exhibits a reentrant (symmetry-breaking, second-order) noise-induced nonequilibrium phase transition, is studied under the assumption that the multiplicative noise leading to the transition is colored. Within an effective Markovian approximation and a mean-field scheme it is found that when the self-correlation time tau of the noise is different from zero, the transition is also reentrant with respect to the spatial coupling D. In other words, at variance with what one expects for equilibrium phase transitions, a large enough value of D favors disorder. Moreover, except for a small region in the parameter subspace determined by the noise intensity sigma and D, an increase in tau usually prevents the formation of an ordered state. These effects are supported by numerical simulations. 相似文献
4.
In this study, methanol extracts (MEs) and essential oil (EO) of Angelica purpurascens (Avé-Lall.) Gill obtained from different parts (root, stem, leaf, and seed) were evaluated in terms of antioxidant activity, total phenolics, compositions of phenolic compound, and essential oil with the methods of 2,2-azino-bis(3ethylbenzo-thiazoline-6-sulfonic acid (ABTS•+), 2,2-diphenyl-1-picrylhydrazil (DPPH•) radical scavenging activities, and ferric reducing/antioxidant power (FRAP), the Folin–Ciocalteu, liquid chromatography−tandem mass spectrometry (LC−MS/MS), and gas chromatography-mass spectrometry (GC−MS), respectively. The root extract of A. purpurascens exhibited the highest ABTS•+, DPPH•, and FRAP activities (IC50: 0.05 ± 0.0001 mg/mL, IC50: 0.06 ± 0.002 mg/mL, 821.04 ± 15.96 µM TEAC (Trolox equivalent antioxidant capacity), respectively). Moreover, EO of A. purpurascens root displayed DPPH• scavenging activity (IC50: 2.95 ± 0.084 mg/mL). The root extract had the highest total phenolic content (438.75 ± 16.39 GAE (gallic acid equivalent), µg/mL)). Twenty compounds were identified by LC−MS/MS. The most abundant phenolics were ferulic acid (244.39 ± 15.64 μg/g extract), benzoic acid (138.18 ± 8.84 μg/g extract), oleuropein (78.04 ± 4.99 μg/g extract), and rutin (31.21 ± 2.00 μg/g extract) in seed, stem, root, and leaf extracts, respectively. According to the GC−MS analysis, the major components were determined as α-bisabolol (22.93%), cubebol (14.39%), α-pinene (11.63%), and α-limonene (9.41%) among 29 compounds. Consequently, the MEs and EO of A. purpurascens can be used as a natural antioxidant source. 相似文献
5.
Sergio E. Mangioni 《Physica A》2012,391(1-2):113-124
We introduced the gregarious instinct by means of a novel strategy that considers the average effect of the attractive forces between individuals within a given population. We watched how pattern formation can be explained by the effect of aggregation depending on conditions on food and / or mortality. We propose a model that describes the corresponding dynamic and by a linear stability analysis of homogeneous solutions and can identify and interpret the region of parameters where these patterns are stable. Then we test numerically these preliminary results and find stable patterns as solutions. Finally, we developed a simplified model allowing us to understand in greater detail the processes involved. 相似文献
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7.
Apart from long-known and applied nanostructures like carbon black for tyres or pigments for coatings nanotechnology has created highly sophisticated structures used for nano/molecular electronics,diagnostics,drug delivery, UV-absorbers etc.Often the main question to be solved analytically is the local determination of tiny amounts of chemicals resulting in an ever increasing need for highly sensitive as well as locally resolved techniques.Applications of techniques like mass spectroscopy,transmission el... 相似文献
8.
Four new fulgimides possessing a fluorescent coumarin unit were synthesized from the corresponding fulgides, and their photochromic as well as fluorescence properties were investigated. The open-ring forms of coumarin fulgimides were found to exhibit fluorescence in the visible region. Upon exposure to UV light, the fulgimides were transformed into the nonfluorescent closed-ring forms, which can be reverted to the initial fluorescent open-ring forms on exposure to visible light. The efficiency of quenching of fluorescence was as high as 95% at the photostationary state of UV irradiation. 相似文献
9.
Ragaini F Penoni A Gallo E Tollari S Li Gotti C Lapadula M Mangioni E Cenini S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(1):249-259
Co(II)-porphyrin complexes catalyze the reaction of aromatic azides (ArN(3)) with hydrocarbons that contain a benzylic group (ArR(1)R(2)CH) to give the corresponding amines (ArR(1)R(2)C-NHAr). When at least one of the R substituents is hydrogen, the catalytic reaction proceeds further to give the imine ArRC=NAr in good yields. The reaction mechanism has been investigated. The reaction proceeds through a reversible coordination of the arylazide to the Co(II)-porphyrin complex. This unstable adduct can either react with the hydrocarbon in the rate-determining step or decompose by a unimolecular mechanism to afford a putative "nitrene" complex, which reacts with more azide, but not with the hydrocarbon, to afford the byproduct diaryldiazene. The kinetics of the catalytic reaction have been investigated for a range of azides and substituted toluenes. Arylazides with electron-withdrawing substituents react at a faster rate and a good correlation is found between the log(k) and the Taft parameters. On the other hand, an excellent correlation between the logarithm of the rate for substituted toluenes relative to that of toluene and a radical parameter (sigma*JJ) alone was found, with no significant contribution by polar parameters. An explanation has been proposed for this anomalous effect and for the very high isotopic effect (k(H)/k(D)=14) found. 相似文献
10.
用具有大能隙的本征半导体(SrTiO3及SnO2)粉末作本体,分别掺杂1%(原子百分数)的Eu2O3;所得物质表现出Eu3+离子的线发射光谱特性,但相对发光强度及光谱形状有相当大的变化。X射线衍射结构分析显示Eu3+在SrTiO3晶格里是处在间隙位置,而它在SnO2晶格里则形成新物相Eu2Sn2O7。 相似文献