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1.
2.
The mechanism of the slowly opened Q-switch operation was investigated thoroughly. Maximum energy extraction from the resonator
could be optimized, and the smallest output beam divergence could be achieved. In this article, we present a detailed analysis
that has numerically verified the mode-selection mechanism in the slowly opened Q-switch operation, and the degree of the
smaller output laser beam divergence that has been achieved. The mechanism of the slowly opened Q-switch operation is the
inherent advantage of the passive saturable absorber in this operation. We can use the maximum energy extraction and the smallest
output beam divergence results of the slowly opened Q-switch operation to design and optimize various passive saturable absorbers:
plastic dye sheets, LiF:F2− color center crystals, Cr4+: YAG crystals, RG1000 color glass filters, and the single crystal semiconductor saturable absorber wafers that are in developed
in our microchip laser systems. 相似文献
3.
In this study, 2,7-bi-(N-penothiazinyl)fluorenone was employed as photocatalyst (PC), ethyl α-bromophenylacetate (EBP) as atom transfer radical polymerization (ATRP) initiator, and photo-induced metal-free ATRP of methyl methacrylate (MMA) was performed at 25°C under blue light irradiation. PMMAs with well-defined architectures and precisely controlled chain lengths were synthsized. The kinetics results confirmed that molecular weights increased linearly with monomer consumption. The molecular weight distributions (Mw/Mn) of the resultant PMMA were narrow. The polymerization was activated and deactivated by periodic light control process. 1H nuclear magnetic resonance spectrometer (NMR) and gel permeation chromatography (GPC) were used to characterize the obtained PMMAs. The living characters of the polymerization system were further confirmed by chain extension of from the PMMA-Br macroinitiator. 相似文献
4.
Chiral quaternary ammonium salts derived from cinchonidine have been applied to catalyze the stereoselective iodolactonizations of trans-5-aryl-4-pentenoic acids leading to a mixture of two regioselectively iodolactonized products with fair to excellent yield (37-98%) and moderate enantioselectivity (exo = 42.0% ee, endo = 31.0% ee) under mild conditions. This work is the first example of asymmetric iodolactonization reaction in the presence of less than a stoichiometric amount of chiral reagent. 相似文献
5.
Recently, low dimension nanostructures have gained considerable attention due to their technological potential as unique types of nanoscale building blocks for future optoelectronic devices and systems. Semiconducting composite nanomaterials, which can combine the advantages of two or more components, have been the focus in the area of nanomaterials synthesis and device application.In this paper, we report our work on the preparation of composite nanomaterials based on CNTs.CNTs were coated by organic or inorganic species via novel and facile methods (Fig. 1 and Fig.2).These functional CNTs based composites show eminent prospects and opportunities for new applications in a wide variation of areas. 相似文献
6.
傅里叶变换利用红外光谱、粉末X射线衍射、微分热重分析、气相色谱-飞行时间质谱、紫外光谱、1H核磁滴定以及电喷雾质谱等分析手段对β-环糊精(β-CD)和亚砷酸钠(SA)形成的分子-离子加合物SA-β-CD进行详细表征.结果显示,主-客体之间分子-离子相互作用是导致SA-β-CD的谱学特性(在固态或在溶液中)与热分解行为相异于主、客体自身行为的重要原因.而在气相色谱-飞行时间质谱条件下发生的氧化还原反应以及在电喷雾质谱条件下出现的Na+-β-CD(摩尔比为1∶1)超分子离子复合体进一步揭示了这种分子-离子加合作用的复杂性与独特性. 相似文献
7.
酞菁氧钛/卟啉氧钒复合体系光导性能的协同增强效应 总被引:9,自引:0,他引:9
在酞菁氧钛(TiOPc)/卟啉氧钒(VOTPP)复合光生材料中发现了光敏性的非线性增强现象,对复合体系的电子跃迁光谱和X射线衍射图的研究结果表明,在基态下两种材料之间没有明显相互作用,光致放电研究说明,该现象来自光激发状态下复合体系中的隙间态跃迁对光导的贡献,XPS测试结果表明酞菁氧钛与卟啉氧钒分子之间存在着定向的部分电荷转移,光致激发状态下的电荷转移是协同增强效应的起因,这种协同增强效应为利用弱的电子给体与弱的受体复合体系设计新型光导材料与器件提供了新方法。 相似文献
8.
Yuichiro Haramoto Yoshiharu Kusakabe Masato Nanasawa Seiji Ujiie Stephan Mang Cladius Schwarzwalder 《Liquid crystals》2013,40(10):1393-1397
Side chain type ionic liquid crystalline polymers having a 4-(1,3-dioxan-2-yl)pyridinium structure in their mesogenic side chain were synthesized. These polymers exhibited the smectic A phase. The molecular weights of these ionic liquid crystalline polymers are very high, e.g. for compound 7 - 2 M w = 486 000. 相似文献
9.
Ying Dong Bangyu Liu Peng Chen Qun Liu Mang Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(13):3510-3514
The insertion of an aryne into a C S bond can suppress the addition of an S nucleophile to the aryne in the presence of palladium. Catalyzed by Pd(OAc)2, a wide range of α‐carbamoyl ketene dithioacetals readily react with arynes to selectively afford functionalized 2‐quinolinones in high yields under neutral reaction conditions by a C S activation/aryne insertion/intramolecular coupling sequence. The attractive feature of the new strategy also lies in the versatile transformations of the alkythio‐substituted quinolinone products. 相似文献
10.
In this paper an alternative approach for measurement of στ product for 4
F
3/2→4
I
11/2 transition of Nd3+ doped YVO4 crystal is reported. In this method a microchip laser is formed by keeping a small piece of the sample in plane-plane resonator
and a diode laser (808 nm) is used for pumping. The pump power induced thermal lensing effect is used to make the cavity stable.
The cavity mode area is estimated by measuring the thermal lens focal length at the threshold and the average pump area is
measured by Gaussian fit to the intensity profiles of the pump beam. The value of στ product of Nd:YVO4 crystal obtained by this method is within 10% of the reported values. The advantage of this method is that it is a simple
method for direct measurement of στ product of laser crystals. 相似文献