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1.
James M. Malloy Peter N. Keliher Malcolm S. Cresser 《Spectrochimica Acta Part B: Atomic Spectroscopy》1980,35(11-12)
The indirect evidence for a change in nebulization efficiency upon discrete sample nebulization has been critically appraised. Direct measurements of the effect of sample size upon nebulization efficiency have been made, by exploiting the reproducible droplet size obtained on allowing free-fall of droplets from a peristaltic pump outlet into a polypropylene capillary funnel. The observed enhancements in efficiency with decreasing sample size are discussed in relation to changes in measured aerosol droplet size distributions. The latter also explain the reduction in the incidence and extent of certain types of interferences. 相似文献
2.
We report the observation of enhanced near-infrared transmission through arrays of subwavelength coaxial metallic structures compared with that through comparable diameter hole arrays as a result of localized electromagnetic modes supported by the complex coaxial unit cell. Polarization and angle-dependent transmission measurements clearly demonstrate the coupling between this localized mode and delocalized surface plasmon modes. A generalized, multiple discrete states Fano line shape provides a good fit to the experimental results. 相似文献
3.
Background
Growth hormone (GH) plays an incompletely understood role in the development of the central nervous system (CNS). In this study, we use transgenic mice expressing a growth hormone antagonist (GHA) to explore the role of GH in regulating postnatal brain, spinal cord and body growth into adulthood. The GHA transgene encodes a protein that inhibits the binding of GH to its receptor, specifically antagonizing the trophic effects of endogenous GH. 相似文献4.
Gillies CW Gillies JZ Amadon SJ Suenram RD Lovas FJ Warner H Malloy R 《Journal of Molecular Spectroscopy》2001,207(2):201-210
Pulsed-beam Fourier transform microwave spectroscopy was used to observe and assign the rotational spectra of the argon-ketene van der Waals complex. Tunneling of the hydrogen or deuterium atoms splits the a- and b-type rotational transitions of H(2)CCO-Ar, H(2)(13)CCO-Ar, H(2)C(13)CO-Ar, and D(2)CCO-Ar into two states. This internal motion appears to be quenched for HDCCO-Ar where only one state is observed. The spectra of all isotopomers were satisfactorily fit to a Watson asymmetric top Hamiltonian which gave A=10 447.9248(10) MHz, B=1918.0138(16) MHz, C=1606.7642(15) MHz, Delta(J)=16.0856(70) kHz, Delta(JK)=274.779(64) kHz, Delta(K)=-152.24(23) kHz, delta(J)=2.5313(18) kHz, delta(K)=209.85(82) kHz, and h(K)=1.562(64) kHz for the A(1) state of H(2)CCO-Ar. Electric dipole moment measurements determined &mgr;(a)=0.417(10)x10(-30) C m [0.125(3) D] and &mgr;(b)=4.566(7)x10(-30) C m [1.369(2) D] along the a and b principal axes of the A(1) state of the normal isotopomer. A least squares fit of principal moments of inertia, I(a) and I(c), of H(2)CCO-Ar, H(2)(13)CCO-Ar, and H(2)C(13)CO-Ar for the A(1) states give the argon-ketene center of mass separation, R(cm)=3.5868(3) ?, and the angle between the line connecting argon with the center of mass of ketene and the C=C=O axis, θ(cm)=96.4 degrees (2). The spectral data are consistent with a planar geometry with the argon atom tilted toward the carbonyl carbon of ketene by 6.4 degrees from a T-shaped configuration. Copyright 2001 Academic Press. 相似文献
5.
Mark E. Erupe Allegra Liberman-Martin Philip J. Silva Quentin G.J. Malloy Naomi Yonis David R. Cocker III Kathleen L. Purvis-Roberts 《Journal of chromatography. A》2010,1217(13):2070-2073
An ion chromatography method with non-suppressed conductivity detection was developed for the simultaneous determination of methylamines (methylamine, dimethylamine, trimethylamine) and trimethylamine-N-oxide in particulate matter air samples. The analytes were well separated by means of cation-exchange chromatography using a 3 mM nitric acid/3.5% acetonitrile (v/v) eluent solution and a Metrosep C 2 250 (250 mm × 4 mm i.d.) separation column. The effects of the different chromatographic parameters on the separation were also investigated. Detection limits of methylamine, dimethylamine, trimethylamine, and trimethylamine-N-oxide were 43, 46, 76 and 72 μg/L, respectively. The relative standard deviations of the retention times were between 0.42% and 1.14% while the recoveries were between 78.8% and 88.3%. The method is suitable for determining if methylamines and trimethylamine-N-oxide are a significant component of organic nitrogen aerosol in areas with high concentration of these species. 相似文献
6.
Moreno KX Harrison C Sherry AD Malloy CR Merritt ME 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,213(1):187-191
Nuclei with long T1s are optimal targets for dynamic nuclear polarization (DNP). Therefore, most of the agents used in metabolic imaging and spectroscopy studies are based on carboxylic acid moieties that lack protons, a strong source of dipolar relaxation. Metabolic flux information encoded into spectra of small molecule metabolites in the form of the 13C isotopomer data cannot be accessed using standard 13C hyperpolarization methods because protonated carbons relax too quickly through T1 dipolar relaxation. It is shown here that the longitudinal mixing sequence FLOPSY-8 can be used to transfer polarization from a long T1 storage nucleus to adjacent protonated carbons so that they may be detected with high sensitivity. We demonstrate that FLOPSY-8 allows a direct readout of isotopomer populations in butyrate and glutamate in vitro. 相似文献
7.
8.
The infrared and Raman data on the ring-puckering vibration in cyclobutane and cyclobutane-d8 have been reexamined including the coordinate dependence of the reduced mass in the Hamiltonian. This was done for the purpose of estimating the importance of these small terms in the determination of barrier heights for four-membered rings and also on the determination of the dihedral angle corresponding to the potential minimum.The conclusions reached are that there is an isotopic dependence of the barriers to planarity in cyclobutane and cyclobutane-d8 yielding a difference of ~14 cm?1, but the precise value of the difference in barrier heights is ill determined. The higher-order kinetic energy terms in the Hamiltonian can account for a spread of ~3 cm?1 in each of the barriers derived for cyclobutane and cyclobutane-d8, depending on the details of the model used for the vibration, but not a difference of 14 cm?1, which undoubtedly indicates the effects of coupling with other vibrational modes. It is also found that the derived values of the dihedral angles are quite sensitive to the details of the vibrational model, in fact, much more so than to the uncertainties in the bond distances and bond angles. A relationship between the potential constants derived for cyclobutane and cyclobutane-d8 assuming an effective constant reduced mass and those derived for a semirigid model is demonstrated. 相似文献
9.
A Mukherjee M Dasgupta DJ Hinde CR Morton AC Berriman RD Butt JO Newton H Timmers 《Pramana》2001,57(1):195-198
Fusion cross-sections for the 7Li + 12C reaction have been measured at energies above the Coulomb barrier by the direct detection of evaporation residues. The heavy
evaporation residues with energies below 3 MeV could not be separated out from the α-particles in the spectrum and hence their
contribution was estimated using statistical model calculations. The present work indicates that suppression of fusion cross-sections
due to the breakup of 7Li may not be significant for 7Li + 12C reaction at energies around the barrier. 相似文献
10.
M. Dybiec S. Ostapenko J.L. Casas Espinola K.J. Malloy 《Applied Surface Science》2006,252(15):5542-5545
The photoluminescence spectra of InAs quantum dots (QDs) embedded into four types of InxGa1−xAs/GaAs (x = 0.10, 0.15, 0.20 and 0.25) multi quantum well MBE structures have been investigated at 300 K in dependence on the QD position on the wafer. PL mapping was performed with 325 nm HeCd laser (35 mW) focused down to 200 μm (110 W/cm2) as the excitation source. The structures with x = 0.15 In/Ga composition in the InxGa1−xAs capping layer exhibited the maximum photoluminescence intensity. Strong inhomogeneity of the PL intensity is observed by mapping samples with the In/Ga composition of x ≥ 0.20-0.25. The reduction of the PL intensity is accompanied by a gradual “blue” shift of the luminescence maximum at 300 K as follows from the quantum dot PL mapping. The mechanism of this effect has been analyzed. PL peak shifts versus capping layer composition are discussed as well. 相似文献