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1.
V. Balek T. Mitsuhashi I.M. Bountseva H. Haneda Z. Malek J. Šubrt 《Journal of Sol-Gel Science and Technology》2003,26(1-3):185-189
The diffusion structural analysis (DSA) was used to characterize microstructure changes of hydrous titania gel films under in situ conditions of heating. TG and DTA were used in order to elucidate the processes controlling the formation of anatase film during heating of hydrous titania gel film. The annealing of porosity and near surface structure defects of the dehydrated titania films was indicated by DSA in the temperature range 255–700°C as the decrease of radon release rate. It was demonstrated that the annealing was enhanced on heating in oxygen in comparison with heating in argon. The DSA experimental results were compared with model curves describing the radon diffusion mobility and the annealing of radon diffusion paths. 相似文献
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P. Budrugeac J. M. Criado F. J. Gotor J. Malek L. A. Prez‐Maqueda E. Segal 《国际化学动力学杂志》2004,36(6):309-315
The isoconversional method suggested by Friedman and the invariant kinetic parameters method (IKP) were used in order to examine the kinetics of the nonisothermal crystallization of (GeS2)0.3(Sb2S3)0.7. The objective of the paper is to show the usefulness of the IKP method both for determining the activation parameters as well as the model of the investigated process. It was shown that the kinetic triplet [(E, A, f(α), where E is the activation energy, A is the preexponential factor, and f(α) is the differential function of conversion], which results through the application of the IKP method, depends on the set of kinetic models considered. For different sets of kinetic models, proportional values of f(α) are obtained. A criterion for the selection of this set, the use of which lead to the true kinetic triplet corresponding to the analyzed process (E = 163.2 kJ mol?1; A = 2.47 × 1012 min?1 and the Avrami‐Erofeev model, Am, for m = 2.5–2.6 was suggested. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 309–315, 2004 相似文献
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A method for improving separations of peptides and other positively charged species in capillary zone electrophoresis with untreated capillaries using acidic buffers containing tetraalkylammonium cations is described. Tetramethylammonium and tetrabutylammonium cations dynamically modify the capillary surface, leading to a reversal in the direction of the electroosmotic flow. As a result, the adsorption of positively charged peptides and proteins is minimized, and resolution and peak capacity are improved as the migration of cationic analytes is counterbalanced by the electroosmotic flow. The combining effect of reversing electroosmotic flow and cyclodextrin inclusion complexation on separations of closely related peptides and a protein mixture, as well as tryptic digest of hemoglobin is demonstrated. 相似文献
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Reactions of anions derived from chiral nonracemic allyl, crotyl, and cinnamyl bicyclic C(2)-symmetrical phosphonamides with alpha, beta-unsaturated cyclic ketones, esters, lactones, and lactams take place at the gamma-position of the reagents. The products are diastereomerically pure or enriched beta-substituted carbonyl compounds. The method also provides easy access to vicinal substitution of as many as three stereogenic centers including in some cases quaternary carbon atoms, in a one-pot sequence. 相似文献
6.
Bruno Ameduri Bernard Boutevin Fouad Malek 《Journal of polymer science. Part A, Polymer chemistry》1994,32(16):3161-3169
The synthesis of maleimides that have pyrazolic or bipyrazolic pendant groups is described. Their homopolymerization and their copolymerization with 2-chloroethyl vinyl ether (CEVE) is reported. The homopolymerizations of such maleimides were performed under various conditions and led to low molecular-weight polymers. However, alternating copolymers were obtained from CEVE as comonomers whatever the monomers feed compositions. A similar behavior was also observed for maleimides that do not exhibit any spacer, whereas for bulky vinyl ethers, random copolymers were produced. A comparison of the thermal behavior between these copolymers (glass transition temperatures, Tg, and decomposition temperatures) and other copolymers having different spacers between the nitrogenated cycles and the chain are related. Thus, an important decrease of Tg, was observed when C3H6CO2CH2 groups were used as the spacer instead of methylene groups. Moreover, the thermal weakness of these copolymers may come from the substituents of the vinyl ether and is discussed. © 1994 John Wiley & Sons, Inc. 相似文献
7.
J. P. Bocquet F. Malek H. Nifenecker M. Rey-Campagnolle M. Maurel E. Monnand P. Perrin C. Ristori G. Ericsson T. Johansson G. Tibell S. Polikanov T. Krogulski J. Mougey 《Zeitschrift für Physik A Hadrons and Nuclei》1992,342(2):183-189
Antiproton induced fission probabilities of U238, Bi209, Pb208 and Au177 are reported together with the mass distribution of the fission fragments in the U238 and Bi209 cases. The charged particles multiplicities observed in co-incidence with fission have, also, been measured for U and Bi and are presented.Dedicated to Peter Armbruster on the occasion of his 60th birthday in recognition of his important contribution to modern Nuclear Physics 相似文献
8.
Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anionic network in which 74% of the volume is available for including cations and neutral guests. Other salts of anion 2 with diverse cations crystallize consistently to form the same network, whereas a neutral analogue of anion 2, tetraphenylmethane 1, produces an uncharged network that is far less open. Cations can be exchanged in single crystals of salts of tetraphenylborate 2 with retention of crystallinity and with selectivities similar to those observed in typical zeolites. Together, these observations provide new strategies for making ordered molecular materials by design, and they reveal that constructing such materials from charged subunits offers special advantages. 相似文献
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