Facile Synthesis of Benzotriazole Derivatives Using Nanoparticles of Organosilane-Based Nitrite Ionic Liquid Immobilized on Silica and Two Room-Temperature Nitrite Ionic Liquids

Nanoparticles of organosilane-based nitrite ionic liquid immobilized on silica, 1-butyl-3-methylimidazolium nitrite, and 1-(3-trimethoxysilylpropyl)-3-methylimidazolium nitrite were used as effective reagents for the preparation of benzotriazole derivatives from 1,2-diaminobenzenes at room temperature under mild solvent-free conditions. These ionic liquids play as nitrosonium sources in this procedure.1,2-Diaminobenzene derivatives have been treated with ionic liquids to give the related diaminobenzenes in very good to excellent yields in short reaction times.

Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the full experimental and spectral details.     

Preparation of conductive,flexible and transparent films by in situ deposition of polypyrrole nanoparticles on polyethylene terephthalate

In this study polypyrrole (PPy) nanoparticles were deposited as a thin film on the modified surface of polyethyleneterephthalate (PET) by in situ chemical polymerization in the presence of sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (DBSNa) and mixture of them as the surfactant. The surface of PET was modified by KOH before deposition and was investigated for conductivity and adhesion of PPy nanoparticles to PET. Resulting conductive flexible films were characterized by UV–Vis spectroscopy, fieldemission scanning electron microscopy, contact angle measurements and four-point-probe technique for conductivity. Direct morphological observation (FESEM) and electrical measurements indicated that the morphology, conductivity and the nature of deposited PPy films depend on surfactant, surface modification of PET and monomer concentration. In optimized process condition, uniform conductive films of PPy were obtained with good adhesion to PET.     

Multi-Set designs and numbers of common triples

A two-fold multi-set triple system is a collection of triples chosen, possibly with repetitions, from av-set in such a way that each pair (whether distinct or not) occurs precisely two times. For instance the triplex, x, y (which we shall write asxxy) contains the pairxx once and the pairxy twice. Such a design has v(v + l)/3 blocks, and a necessary and sufficient condition for existence is thatv = 0 or 2 (mod 3) and y≥5. The design is called simple if it contains no repeated blocks. Let I₂(v) denote the set of non-negative integerss such that there exist two simple two-fold multi-set triple systems of orderv with preciselys blocks in common. In this paper we determine I₂(v) for all admissiblev.     

Theory of a Two-Dimensional Rotating Wigner Cluster

JETP Letters - A two-dimensional Wigner cluster (2DWC) with the number of electrons up to 200 in a parabolic potential well has been studied numerically and analytically. It has been shown that the...     

ISFET immunosensor improvement using amine-modified polystyrene nanobeads

Antigen-based sensing is recognized as a rapid and sensitive analysis among bioresearch groups. The potential of “on-site” analysis in such devices has been accompanied by some problems. Fabrication of silicon compatible and highly sensitive biosensors has been the center of excessive research within the past few years. In this paper, we report fabrication of two types of sensitive liquid oxide semiconductor (LOS) biosensors using nanostructures. These devices have been manufactured and characterized as immunosensors. These two types of sensors have been produced using different platforms for immobilization of proteins; one based on a functionalized silicon dioxide surface by 3-aminopropyltriethoxysilane (APTES) and another on the basis of using 50-nm amine-modified polystyrene nanobeads. The polystyrene platform not only benefits from its nanosize and high surface to volume ratio but also does not need any new protocol than what is already used for traditional immunosensing system. These sensors measure the change of threshold voltage of the semiconductor inversion inside the capacitor due to the bonding of antibodies to the linked peptides on the surface. Measurements showed that the sensitivity of 50-nm polystyrene-based sensor is much more than the oxide-based one. The nanobeads were then chosen to cover the gate of the ISFET for the amplified sensing. The ISFET devices were biased in a subthreshold region to demonstrate the maximum sensitivity to the accumulated charge on the gate. Repeatable results after different stress tests were obtained, which proves the suitability and reliability of the polystyrene nanobead platform for this application. Finally, a calibration curve has been derived that can be used for real sample measurements. The detection limit of 1.0152 μg/ml was calculated for the fabricated sensor.

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Scattering of Electrons between Edge and Two-Dimensional States of a Two-Dimensional Topological Insulator and the Conductivity of the Topological Insulator Strip in a Metallic State

JETP Letters - The lifetime of electrons on edge states of a two-dimensional topological insulator against the background of an allowed two-dimensional band has been determined. It has been shown...     

Friedel oscillations of a magnetic field penetrating into a normal metal and a size-quantized system

A magnetic field applied to a size-quantized system causes persistent equilibrium currents nonuniformly distributed across this system. For a quantum film and a two-dimensional strip, the distributions of the dia-and paramagnetic currents and magnetic field are determined. The possibility of observing field distribution by NMR is discussed.     

Edge excitons in a 2D topological insulator in a magnetic field

Exciton edge states and the microwave edge exciton absorption of a 2D topological insulator subject to the in-plane magnetic field are studied. The magnetic field forms a narrow gap in electron edge states that allows the existence of edge exciton. The exciton binding energy is found to be much smaller than the energy of a 1D Coulomb state. Phototransitions exist on the exciton states with even numbers, while odd exciton states are dark.     

ZrCl4/[bmim]BF4‐catalyzed condensation of salicylaldehydes and malononitrile: Single‐step synthesis of 3‐cyanocoumarin derivatives

A versatile and efficient single‐step route to 3‐cyanocoumarins via Knoevenagel condensation of salicylaldehydes and malononitrile using ZrCl₄ as the catalyst (15 mol %) in ionic liquid 1‐(n‐butyl)‐3‐methylimidazolium tetrafluoroborate as reaction medium and catalyst is described. The novel procedure features single step, short reaction time, good yields, and simple workup. J. Heterocyclic Chem., (2011).