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Reactivity Ratios and Sequence Distribution Characterization by Quantitative 13C NMR for RAFT Synthesis of Styrene‐Acrylonitrile Copolymers
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Md. Mahbub Alam Hui Peng Kevin S. Jack David J. T. Hill Andrew K. Whittaker 《Journal of polymer science. Part A, Polymer chemistry》2017,55(5):919-927
The kinetics and reactivity ratios of styrene‐acrylonitrile (SA) copolymerization have been studied extensively in bulk and in a variety of solution media using conventional free radical polymerizations (FRPs). Due to the significant difference in the two reactivity ratios for this monomer pair, at certain feed ratios the copolymers display composition drift with conversion due to monomer depletion. In this study, the kinetics of SA copolymerization using Reversible Addition‐Fragmentation Chain Transfer (RAFT) has been studied in bulk at 80 °C. The reactivity ratios for the terminal model were calculated from the comonomer sequence distributions for the RAFT process at low conversion for nine different compositions and found to be in the same range as those reported for conventional FRP of SA. The changes in the composition and sequence distribution with conversion were studied for three feed compositions. The copolymers show compositional drift with conversion, except at the azeotropic composition, and match the predictions from the reactivity ratios obtained at low conversion. From quantitative 13C NMR the triad distributions of these copolymers were estimated and found to match the predicted triad distributions as conversion increased. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 919–927 相似文献
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The wake of a streamwise oscillating cylinder is presently investigated. The Reynolds number investigated is 300, based on
the cylinder diameterd. The cylinder oscillates at an amplitude of 0.5d and a frequencyf
e/fs=1.8, wheref
e is the cylinder oscillating frequency andf
s is the natural vortex shedding frequency of a stationary cylinder. Under these conditions the flow is essentially two dimensional.
A two-dimensional direct numerical simulation (DNS) scheme has been developed to calculate the flow. The DNS results display
a street of binary vortices, each containing two counter-rotating vortical structures, symmetrical about the centerline, which
is in excellent agreement with measurements. The drag and lift on the cylinder have been examined. The time averaged drag
and lift are 1.4 and 0, respectively, which are the same as those on a stationary cylinder at the sameRe. However, the fluctuating drag was high, about 2.68. It has been found that, being symmetrically formed about the centerline,
the binary vortices induce an essentially zero fluctuating lift, which may have a profound implication in flow control and
engineering. 相似文献
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<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods. 相似文献
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CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献
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John W.Grove 《数学物理学报(B辑英文版)》2010,30(2):563-594
This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described. 相似文献
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In an erbium-doped fiber amplifier(EDFA), erbium ions act as a three-level system. Therefore, much higher pump energy is required to achieve the population inversion in an erbium-doped fiber(EDF). This higher pump energy requirement complicates the efficient design of an EDFA. However, efficient use of the pump power can improve the EDFA performance. The improved performance of an EDFA can be obtained by reducing the doping radius of the EDF. A smaller doping radius increases pump–dopant interactions and subsequently increases the pump–photon conversion efficiency. Decreasing the doping radius allows a larger proportion of dopant ions,which are concentrated near the core, to interact with the highest pump intensity. However, decreasing the doping radius beyond a certain limit will bring the dopant ions much closer and introduce detrimental ion–ion interaction effects. In this Letter, we show that an optimal doping radius in an EDF can provide the best gain performance. Moreover, we have simulated the well-known numerical aperture effects on EDFA gain performance to support our claim. 相似文献
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