Characteristics investigation on heat transfer growth of sonochemically synthesized ZnO-DW based nanofluids inside square heat exchanger

Journal of Thermal Analysis and Calorimetry - In recent decades, the growth of heat transfer using nanomaterials in the conventional base fluid has caught the attention of researchers...     

The effect of rapid rotation on a vertical bridgman furnace at large Rayleigh number

In quasi-steady operation, convection currents in a Bridgmandevice, used for producing a semi-conductor crystal, createinhomogeneities that may make the crystal unusable. It has oftenbeen suggested that additional forces due to rotation or magnetismmight be efficacious in reducing the segregation of the elementsof the alloy. It has been found that, over a wide range of rotationrates, there is no improvement in performance due to rotationabout the vertical axis. However, numerical results that havebeen obtained previously (Lee & Pearlstein, J. Crys. Growth240, 2002) indicate that, when effects of centrifugal buoyancyare introduced, a substantial reduction in segregation is achieved.In the work reported here, by contrast, in which we extend previouslarge-Rayleigh-number asymptotic analysis to include centrifugalbuoyancy, we find no improvement in radial segregation, butrather increasing segregation with increasing rotation rate.     

Enhancing photoinduced hydrophilicity of micro arc oxidized TiO2 nanostructured porous layers by V-doping

This study sheds light on the effect of vanadium doping on hydrophilicity properties of micro arc oxidized TiO₂ porous layers. Pure and V-doped titania layers, with a pore size of 50–400 nm, were grown by micro arc oxidation method. Morphology and topography of the layers were studied by SEM and AFM techniques where formation of a porous structure with a rough surface was confirmed. Moreover, phase structure and chemical composition of the samples were investigated employing XRD and XPS techniques. The pure TiO₂ layers consisted of anatase and rutile phase. Vanadia phase was also detected in V-doped layers. It was also revealed that V₂O₅ not only dispersed in the TiO₂ matrix, but also doped into the crystalline lattice. Optical properties and band gap energy of the synthesized layers were evaluated by a UV-Vis spectrophotometer. Our results showed that the band gap energy decreased when vanadium was introduced into the titania lattice. Finally, hydrophilicity of the pure and the doped layers was studied under ultraviolet and visible illuminations by measuring the water contact angle on their surface. The V-doped layers, especially those which were grown under intermediate voltages, revealed an enhanced hydrophilicity when compared to the pure TiO₂ layers.     

Controlled hydrothermal growth of ZnO nanostructures by sequestering the Zn metal ions with the chelating agent EDTA

In the present work, a controlled growth of ZnO nanostructures by manipulating Zn metal ion concentration by the chelating action of ethylene diaminetetra acetic acid in hydrothermal method is studied. EDTA produces metal–chelate complex by the formation of bidentate ligand with Zn²⁺ in the solution and diminishes the reactivity of Zn metal cations. Concentration of EDTA in the mother solution was varied in different ranges like 3, 5 and 10 mM while retaining the zinc metal salt and the NaOH concentration the same. Three different morphologies of wurtzite structured ZnO nanostructures such as nanorods-bunch, separate/discrete uniformly sized hexagonal nanorods and tapered flower petals like shapes are achieved by 3, 5 and 10 mM strengths of EDTA, respectively. The medium concentration 5 mM of EDTA is found to have moderate control over producing ZnO nanostructures of uniform diameter and a high aspect (length to diameter) ratio. An array of vertically aligned free standing ZnO nanorods with uniform spacing is successfully achieved by the addition of 5 mM of EDTA in the mother solution and the same is studied for its fluorescence property at an excitation of 325 nm and it has exhibited a characteristic UV emission of ZnO around 383 nm.     

Self-assembly of boehmite nanopetals to form 3D high surface area nanoarchitectures

A flower-like boehmite nanostructure was prepared through a template-free chemical route by the self-assembly process of nanosize petals 800–1000 nm long, 200–250 nm wide, 20–50 nm thick and having an average crystallite size of about 2.21 nm. X-ray diffraction analysis (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), DTA/TGA analyses and Brunauer–Emmet–Teller (BET-N₂) analyses were used in order to characterize the product obtained. XRD results exhibited that the obtained nanostructures composed of pure orthorhombic AlOOH phase. The effects of Cl⁻ ions and TEA on the growth of boehmite three-dimensional nanoarchitectures in the presence of NO₃^-\mathrm{NO}_{3}^{-} ions were investigated. BET analyses of as-prepared material demonstrate that this nanostructure material has a high specific surface area, as high as 123 m² g⁻¹.     

How photocatalytic activity of the MAO-grown TiO2 nano/micro-porous films is influenced by growth parameters?

Pure titania porous layers consisted of anatase and rutile phases, chemically and structurally suitable for catalytic applications, were grown via micro-arc oxidation (MAO). The effect of applied voltage, process time, and electrolyte concentration on surface structure, chemical composition, and especially photocatalytic activity of the layers was investigated. SEM and AFM studies revealed that pore size and surface roughness of the layers increased with the applied voltage, and the electrolyte concentration. Moreover, the photocatalytic performance of the layers synthesized at medium applied voltages was significantly higher than that of the layers produced at other voltages. About 90% of methylene blue solution was decomposed after 180 min UV-irradiation on the layers produced in an electrolyte with a concentration of 10 g l⁻¹ at the applied voltage of 450 V.     

New ideas in neutrino detection

What is new in the field of neutrino detection? In addition to new projects probing both the low and high ends of the neutrino energy scale, an inexpensive, effective technique is being developed to allow tagging of antineutrinos in water Cherenkov (WC) detectors via the addition to water of a solute with a large neutron cross-section and energetic γ daughters. Gadolinium is an excellent candidate since in recent years it has become very inexpensive, now less than $8 per kilogram in the form of commercially available gadolinium trichloride. This non-toxic, non-reactive substance is highly soluble in water. Neutron capture on gadolinium yields an 8.0 MeV gamma cascade easily seen in detectors like Super-Kamiokande. The uses of GdCl₃ as a possible upgrade for the Super-Kamiokande detector — with a view toward improving its performance as an antineutrino detector for supernova neutrinos and reactor neutrinos — are discussed, as are the ongoing R&;D efforts which aim to make this dream a reality within the next two years.     

有机硅活性中间体的研究 II. 一些含环丙基的有机硅化合物的合成及其结构

用锂有机物的方法合成了四种含有环丙基有机硅化合物,对上述每种化合物中可能存在着的立体异构进行了分离和和构型测定。