Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide

This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.     

双色制导用InGaAs探测器低温特性的研究

制备了平面结InGaAs短波红外探测器,分别测量了其在室温及液氮温区的响应光谱、电流～电压曲线和光生信号及噪声,发现其光生信号与室温测量值相比下降了大约50%.在液氮温区的测试结果表明,短波探测器的峰值响应率为Rvp=2.41(107V/W),峰值探测率Dp*=1.51(1012(cmHz)1/2/W.其透射谱的测量表明该探测器的透射率能够超过80%.这些指标能够满足红外双色探测系统的需求。     

铁电移相器优值研究

基于双周期性电容加载共面波导传输线的移相器结构,系统研究了温度变化对铁电薄膜移相器移相能力、传输损耗的影响.调整温度可以在一定的范围内实现对移相器性能指标的微调.给出了加载因子对移相能力的示意曲线图,并在实验上,借助氩离子刻蚀技术,改变加载因子的大小,使得移相器的优值从原来的13degree/dB提升到23degree/dB.     

用~1H NMR作石油重质油结构分析中芳香度f_a计算公式推导及经验式

报道了~1H NMR作石油重质油结构分析中芳香度f_n的计算公式,并用文献数据和~1H NMR实验作了验证、推荐了几个分别适合柴油、蜡油、常渣和减渣馏份f_n的经验公式。     

各向异性体内含任意孔洞对反平面波散射的边界元方法

本文借助于广义格林公式导出了用位移表示的各向异性介质中SH波入射时的边界积分方程.根据本文作者在文献[8]给出的基本解,求解了各向异性介质中孔洞对SH波的散射问题.边界积分方程的离散基于常数元模式.文中给出了一个圆柱、一个椭圆柱和两个椭圆柱形式的孔洞周围的位移场和应力场的数值结果.最后,对入射波频率较高时的情形作了说明.     

量子群V_q(sl(2))的商代数

本文研究当q是单位根时,V_q(sl(2))在关系H~r=K~r=1,E~(mr)=F~(nr)=0下的商代数V_q(m,n)的构造与分解,以及它的区块结构.为此,首先将U_q(sl(2))的基本性质和重要结论推广到V_q(sl(2)),并研究V_q(sl(2))的模的基本性质.利用这些结论,我们逐步构造出V_q(m,n)的左理想,并将V_q(m,n)分解成不可分解的左理想的直和.然后,把V_q(m,n)的不可分解的左理想合并成区块,并研究区块结构,从而把V_q(m,n)的表示问题归结成一个代数表示论的问题.     

Site-specific Deposition of Colloidal Pd Nanoparticles on Self-assembled Microtubules from Biolipid

Lipid microtubules with wound ribbon features were fabricated by self-assembling method, and the deposition patterns of colloidal Pd particles on tubular template were investigated. The result indicates that colloidal Pd nanoparticles are preferentially decorated on the helical markings in the interior and on the exterior of preformed tubule and to the edge of loosely helical ribbons to obtain helical deposition features. The multi-bilayer microstructure of tubules can be marked by fine Pd nanoparticles deposited at the edge of helical ribbon. There are the site-specific interactions between lipid tubular template and colloidal Pd particles at the helical edge. A new route was illustrated that colloidal Pd particles firstly attach at the edge of thin flat membranes, and then thin membranes roll up and reassemble into tubule together with particles to form helical deposition patterns. The site-specific deposition of Pd is unbeneficial to obtain the homogeneous metal film on tubules, but it can be utilized to reveal the different chemical nature of lipid molecular assembly.     

棒状薄层色谱/氢火焰检测法在石油重质油烃组成分析上的应用

在石油重质油的烃组成分析中,液固色谱,质谱和高效液相色谱等已被广泛采用。但是,这些方法均存在着一些缺点,如分析时间长、定量困难等。棒状薄层色谱/氢火焰检测(TLC/FID)法则较好地克服了上述缺点。本文扼要叙述了TLC/FID法的分析原理、试验技术和在石油重质油烃组成分析中的应用实例,并对该技术的发展前景提出了看法。     

Efficient and stable non-doped deep-blue organic light emitting diode based on an anthracene derivative

A new anthracene derivative 9,10-bis[3,5-di(4-tert-butylphenyl)phenyl]anthracene (BPPA) was synthesized via Suzuki coupling reaction and characterized by 1H NMR spectrum,mass spectrum,and elemental analysis.BPPA exhibits deep-blue emission both in solution and in solid thin film.This compound has a non-planar structure that results in high thermal stability and the phenomenon of polymorphism.The non-doped device based on this material shows stable deep-blue emission with the 1931 Commission international de...