Spectroscopic studies of pure carbon tetrafluoride and carbon tetrafluoride in the presence of water vapor have been carried out. Studies have revealed changes in the absorption spectrum of the 1280 cm‒1 band of CF4, indicating the formation of new molecules, CF4–H2O hydrates. The bond between CF4 and H2O is not chemical in nature. The formation of these molecules can accelerate the removal of carbon tetrafluoride from the atmosphere with precipitation in the form of rain or snow.
相似文献The pressure dependence of the absorption spectrum of hydrogen molecules inside pores of an aerogel has been found. Two components with linear and quadratic pressure dependences have been revealed. It has been assumed that the first component can be attributed to the absorption of an individual molecule near the surface of pores, whereas the second component is due to intermolecular interaction. A method has been proposed to estimate in the first approximation the size of pores from the absorption spectrum.
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