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1.
We derive microscopically precise identities for the geometry of small clusters in the equilibrium states of the two-dimensional Ising model with emphasis on near-critical phenomena. 相似文献
2.
Groshaus JG Dujovne I Gallais Y Hirjibehedin CF Pinczuk A Tan YW Stormer H Dennis BS Pfeiffer LN West KW 《Physical review letters》2008,100(4):046804
Neutral spin texture (ST) excitations at nu=1/3 are directly observed for the first time by resonant inelastic light scattering. They are determined to involve two simultaneous spin flips. At low magnetic fields, the ST energy is below that of the magnetoroton minimum. With increasing in-plane magnetic field these mode energies cross at a critical ratio of the Zeeman and Coulomb energies of eta(c)=0.020+/-0.001. Surprisingly, the intensity of the ST mode grows with temperature in the range in which the magnetoroton modes collapse. The temperature dependence is interpreted in terms of a competition between coexisting phases supporting different excitations. We consider the role of the ST excitations in activated transport at nu=1/3. 相似文献
3.
Intercalation of trioxatriangulenium ion in DNA: binding,electron transfer,x-ray crystallography,and electronic structure 总被引:1,自引:0,他引:1
Reynisson J Schuster GB Howerton SB Williams LD Barnett RN Cleveland CL Landman U Harrit N Chaires JB 《Journal of the American Chemical Society》2003,125(8):2072-2083
Trioxatriangulenium ion (TOTA(+)) is a flat, somewhat hydrophobic compound that has a low-energy unoccupied molecular orbital. It binds to duplex DNA by intercalation with a preference for G-C base pairs. Irradiation of intercalated TOTA(+) causes charge (radical cation) injection that results in strand cleavage (after piperidine treatment) primarily at GG steps. The X-ray crystal structure of TOTA(+) intercalated in the hexameric duplex d[CGATCG](2) described here reveals that intercalation of TOTA(+) results in an unusually large extension of the helical rise of the DNA and that the orientation of TOTA(+) is sensitive to hydrogen-bonding interactions with backbone atoms of the DNA. Electronic structure calculations reveal no meaningful charge transfer from DNA to TOTA(+) because the lowest unoccupied molecular orbital of TOTA(+), (LUMO)(T), falls in the gap between the highest occupied molecular orbital, (HOMO)(D), and the (LUMO)(D) of the DNA bases. These calculations reveal the importance of backbone, water, and counterion interactions, which shift the energy levels of the bases and the intercalated TOTA(+) orbitals significantly. The calculations also show that the inserted TOTA(+) strongly polarizes the intercalation cavity where a sheet of excess electron density surrounds the TOTA(+). 相似文献
4.
Previous investigations of the first ionization of aqueous sulfur dioxide or ‘sulfurous acid’ have led to ΔH 1 0 values ranging from ?15 to ?24.5 kJ-mol?1. To help with selection of a ‘best’ value for this enthalpy of ionization we have made calorimetric measurements of enthalpies associated with adding dilute perchloric acid to dilute aqueous sulfur dioxide and sodium bisulfite. Results have led to ΔH 1 0 =?17.40 kJ-mol?1, which we have combined with K1=0.0139 and the related ΔG 1 0 =10.60 kJ-mol?1 to obtain ΔS 1 0 =?93.9 J-K?1-mol?1 for the first ionization, all referring to 25°C. 相似文献
5.
6.
Chen D Heberling MS Nakata M Hough LE Maclennan JE Glaser MA Korblova E Walba DM Watanabe J Clark NA 《Chemphyschem》2012,13(1):155-159
The B4 liquid crystal phase of bent-core molecules, a smectic phase of helical nanofilaments, is one of the most complex hierarchical self-assemblies in soft materials. We describe the layer topology of the B4 phase of mesogens in the P-n-OPIMB homologous series near the liquid crystal/glass interface. Freeze-fracture transmission electron microscopy reveals that the twisted layer structure of the bulk is suppressed, the layers instead forming a structure with periodic layer undulations, with the topography depending on the distance from the glass. The surface layer structure is modeled as parabolic focal conic arrays generated by equidistant parabolas whose foci are defect lines along the glass surface. Nucleation and growth of toric focal conics near the glass substrate is also observed. Although the growth of twisted nanofilaments, the usual manifestation of structural chirality in the B4 phase, is suppressed near the surface, the smectic layers are intrinsically chiral, and the helical filaments that form on top of them grow with specific handedness. 相似文献
7.
8.
A Network Simulation of High-congestion Road-traffic Flows in Cities with Marine Container Terminals
James A. Pope Terry R. Rakes Loren Paul Rees Ingrid W. M. Crouch 《The Journal of the Operational Research Society》1995,46(9):1090-1101
Port cities where marine cargo terminals are located are generally near urban areas characterized by high-congestion road traffic. Changes in cargo traffic volumes into a marine terminal, or in the surrounding traffic arteries, which carry this traffic, can significantly affect the terminal's operations. Conversely, activity at the terminal can have an impact on the traffic levels and congestion for a considerable distance from the terminal. This paper demonstrates a methodology useful for studying the impact of road traffic flows on marine container terminals located in highly congested areas. This model was developed at the request of the Virginia Center for World Trade and was used to answer three planning questions in the port of Hampton Roads, Virginia, USA-what would be the impact of: opening a new section of interstate highway, a projected doubling of container traffic at one terminal, and a daily unit train in the vicinity of another terminal. The problem was made more challenging by limited data-collection funds. None the less, the model was deemed valid by a panel of traffic experts and officials from several major state and private agencies involved in marine traffic management. The model results were subsequently a factor in two major decisions related to terminal management. 相似文献
9.
Prem Paul Singh Jan Spitzer Robert M. McKay Keith G. McCurdy Loren G. Hepler 《Thermochimica Acta》1978,24(1):111-115
We have made calorimetric and density measurements leading to apparent molar heat capacities and volumes of dilute aqueous solutions of silver nitrate and silver perchlorate at 298 K. Resulting apparent molar properties at infinite dilution are the following: φoc(AgNO3) = ? 36.8 J K?1 mol?1, φov(AgNO3) = 29.1 cm3 mol?1, φoc(AgClO4) = 11.0 J K?1 mol?1, and φov(AgClO4) = 43.5 cm3 mol?1. 相似文献
10.
Dr. Kai Xue Dr. Riza Dervisoglu Dr. Heidrun Sowa Dr. Loren B. Andreas 《Chemphyschem》2020,21(15):1622-1626
The NMR pulse sequence CODEX (centerband-only detection of exchange) is a widely used method to report on the number of magnetically inequivalent spins that exchange magnetization via spin diffusion. For crystals, this rules out certain symmetries, and the rate of equilibration is sensitive to distances. Here we show that for 13C CODEX, consideration of natural abundance spins is necessary for crystals of high complexity, demonstrated here with the amino acid phenylalanine. The NMR data rule out the C2 space group that was originally reported for phenylalanine, and are only consistent with a larger unit cell containing eight magnetically inequivalent molecules. Such an expanded cell was recently described based on single crystal data. The large unit cell dictates the use of long spin diffusion times of more than 200 seconds, in order to equilibrate over the entire unit cell volume of 1622 Å3. 相似文献