全文获取类型
收费全文 | 958篇 |
免费 | 21篇 |
国内免费 | 7篇 |
专业分类
化学 | 581篇 |
晶体学 | 6篇 |
力学 | 41篇 |
数学 | 134篇 |
物理学 | 224篇 |
出版年
2023年 | 8篇 |
2022年 | 28篇 |
2021年 | 35篇 |
2020年 | 27篇 |
2019年 | 22篇 |
2018年 | 18篇 |
2017年 | 13篇 |
2016年 | 45篇 |
2015年 | 35篇 |
2014年 | 30篇 |
2013年 | 73篇 |
2012年 | 62篇 |
2011年 | 50篇 |
2010年 | 48篇 |
2009年 | 52篇 |
2008年 | 95篇 |
2007年 | 79篇 |
2006年 | 55篇 |
2005年 | 28篇 |
2004年 | 32篇 |
2003年 | 16篇 |
2002年 | 25篇 |
2001年 | 16篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 10篇 |
1996年 | 9篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有986条查询结果,搜索用时 0 毫秒
1.
Fátima Nunes Serralha José Madeira Lopes Francisco Lemos Duarte Prazeres Maria Aires-Barros Joo Rocha Joaquim Cabral Fernando Ramôa Ribeiro 《Reaction Kinetics and Catalysis Letters》2000,69(2):217-222
Novel [CrIII(amp)(bipy)(Cl)] (1) (H2amp = N-(hydroxyphenyl)salicyldimine; bipy = 2,2-bipyridyl) and [CrIII(app)(bipy)(Cl)]+ (2) (H2app = N-(hydroxyphenyl)pyridine-2-carboxaldimine; bipy = 2,2-bipyridyl) complexes have been synthesized and characterized by physico-chemical methods. Complexes 1 and 2 have been employed as catalysts in the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). The significance of the results with respect to oxo-functionalization of C-H bonds both in unsaturated and saturated hydrocarbons is noted. 相似文献
2.
R. F. B. Serpa E. F. O. De Jesus M. J. Anjos R. T. Lopes M. G. T. do Carmo S. Moreira M. S. Rocha A. M. B. Martinez 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(3):647-652
Summary The study of trace element levels is of great importance due to their relevance in agingand several neurodegenerative diseases.
This work compares the elemental concentrations in different postnatal ages and between the temporal cortex, entorhinal cortex
and hippocampus from Wistar rats, using X-ray total reflection fluorescence with synchrotron radiation. Ten elements were
determined in brain samples: Ti, Cr, Mn, Fe, Cu, Zn, (at trace level) and P, S, Cl and K (at major levels). The elements that
increased with aging in cortical areas were: S, K, Fe, Cu and Zn. Ca and Zn levels decreased with advancing age in the hippocampus.
In addition to this, Ti, Mn and Fe levels were more conspicuous in the entorhinal cortex. 相似文献
3.
4.
Renato P. Freitas Cristiane Calza Tania A. Lima Angela Rabello Ricardo Tadeu Lopes 《X射线光谱测定》2010,39(5):307-310
In this work, 102 fragments of Marajoara ceramics, belonging to the National Museum collection (Rio de Janeiro, Brazil), were analyzed using energy dispersive X‐ray fluorescence (EDXRF) and principal component analysis (PCA) in order to identify possible groups of samples that present similar behaviors or different characteristics. This information will give an important aid to a more accurate classification of these artifacts. The EDXRF measurements were carried out with a portable system developed in the Nuclear Instrumentation Laboratory consisting of an Oxford TF3005 X‐ray tube, with W anode, and an Si‐PIN XR‐100CR detector from Amptek, working at 25 kV and 100 µA, acquisition time of 600 s and a beam collimation of 2 mm. PCA applied to the X‐ray fluorescence results revealed a clear cluster separation to the samples. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
5.
Kostya Khanin João Lopes Dias Jens Marklof 《Communications in Mathematical Physics》2007,270(1):197-231
The disadvantage of ‘traditional’ multidimensional continued fraction algorithms is that it is not known whether they provide
simultaneous rational approximations for generic vectors. Following ideas of Dani, Lagarias and Kleinbock-Margulis we describe
a simple algorithm based on the dynamics of flows on the homogeneous space
(the space of lattices of covolume one) that indeed yields best possible approximations to any irrational vector. The algorithm
is ideally suited for a number of dynamical applications that involve small divisor problems. As an example, we explicitly
construct a renormalization scheme for the linearization of vector fields on tori of arbitrary dimension. 相似文献
6.
Fractional calculus (FC) is the area of calculus that generalizes the operations of differentiation and integration. FC operators are non-local and capture the history of dynamical effects present in many natural and artificial phenomena. Entropy is a measure of uncertainty, diversity and randomness often adopted for characterizing complex dynamical systems. Stemming from the synergies between the two areas, this paper reviews the concept of entropy in the framework of FC. Several new entropy definitions have been proposed in recent decades, expanding the scope of applicability of this seminal tool. However, FC is not yet well disseminated in the community of entropy. Therefore, new definitions based on FC can generalize both concepts in the theoretical and applied points of view. The time to come will prove to what extend the new formulations will be useful. 相似文献
7.
Leitão Jorge C. Parente Lopes João M. Viana Altmann Eduardo G. 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(10):1-10
The European Physical Journal B - A way to make financial models effective is by letting them to represent the so called “fat tails”, i.e., extreme changes in stock prices that are... 相似文献
8.
Measurements of synchrotron radiation emitted by 30-MeV runaway electrons in the TEXTOR-94 tokamak show that the runaway population decays after switching on neutral beam injection (NBI). The decay starts only with a significant delay, which decreases with increasing NBI heating power. This delay provides direct evidence of the energy dependence of runaway confinement, which is expected if magnetic modes govern the loss of runaways. Application of the theory by Mynick and Strachan [Phys. Fluids 24, 695 (1981)] yields estimates for the "mode width" (delta) of magnetic perturbations: delta<0.5 cm in Ohmic discharges, increasing to delta = 4.4 cm for 0. 6 MW NBI. 相似文献
9.
Recent research has shown that a phase transformation of diamond to a different form of carbon is involved when diamonds are polished in the traditional fashion. The question as to how this phase transformation is activated and maintained to produce high wear rates is of great technological interest since it may radically change the way we view the processing of diamond. This paper describes the use of Raman spectroscopy to examine debris produced on the diamond polishing wheel, both during its preparation and during polishing. In addition, polished diamond surfaces were examined for the possible existence of non-diamond surface layers in an attempt to identify material removal mechanisms. Raman spectroscopy proves ideal for these analyses because its relatively high spatial resolution is well suited to the analysis of small wear features and debris particles, and because of the wealth of information it reveals about chemical structure. This level of structural information has been lacking in previous analyses of diamond polishing debris. In addition to the non-diamond carbon found in the wear debris, significant quantities of two iron oxides, magnetite (Fe3O4) and haematite (α-Fe2O3), were also found. An interesting observation was that a transformation from magnetite to haematite could be induced either by using high power laser excitation or by frictional heating during polishing. It is suggested that some of the Raman peaks previously attributed to lonsdaleite might better be explained by the presence of these oxides. 相似文献
10.
SNO measurements strongly constrain the central temperature of the Sun, to within a precision of much less than 1%. This result can be used to probe the parameter space of supersymmetric dark matter. In this first analysis we find a lower limit for the weakly interacting massive particle (WIMP) mass of 60 GeV. Furthermore, in the event that WIMPs create a quasi-isothermal core, they will produce a peculiar distribution of the solar neutrino fluxes measured on Earth. Typically, a WIMP with a mass of 100 GeV and annihilation cross section of 10(-34) cm(3)/sec will decrease the neutrino predictions, by up to 4% for the Cl, by 3% for the heavy water, and by 1% for the Ga detectors. 相似文献