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1.
Geerk J. Linker G. Meyer O. Politis C. Ratzel F. Smithey R. Strehlau B. Xiong G. C. 《Zeitschrift für Physik B Condensed Matter》1987,67(4):507-511
Thin superconducting films of La1.8Sr0.2CuO4 have been prepared by magnetron sputter deposition and subsequent temperature treatment. The composition of the films has been determined by Rutherford backscattering and the structure by thin film X-ray diffraction. The onset of superconductivity was about 32 K and the midpoint near 28 K. Defect production in the films by He ion bombardment revealed a drasticT
c
reduction with a sensitivity similar to that observed in the Chevrel phases. Oxygen implantation and subsequent annealing led to an enhancement of theT
c
onset. 相似文献
2.
3.
Sommermann T Kim BG Peters K Peters EM Linker T 《Chemical communications (Cambridge, England)》2004,(22):2624-2625
Only three steps are required for the convenient synthesis of 2-C-branched glyco-amino acids from glycals with good yields and stereoselectivities. 相似文献
4.
5.
6.
Cyclic beta-keto ester monoanions react with 1,4-dihalobutenes to give C-alkylated products which subsequently undergo a stereoselective SN2' O-alkylation reaction to yield functionalized enol ethers. When the starting material was ethyl cyclopentanone carboxylate, the C-alkylated product, treated with a base, directly afforded the functionalized bicyclo[4.2.1]nonanone. The enol ethers were submitted to a flash vacuum thermolysis (FVT) reaction to readily afford functionalized bicyclo[4.n.1]alkanones (n = 3, 4). This reaction sequence was applied to the synthesis of a functionalized tricyclo[7.4.1.0(1,5)]tetradecanone, which represents an analogue to the tricyclic core of ingenol. 相似文献
7.
Tobias Krüger Katja Vorndran Dr. Torsten Linker Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(44):12082-12091
Arenes with various alkyl side‐chains were synthesized in high yields and excellent regioselectivities. Starting from toluic and naphthoic acids, the carboxylate group was conveniently substituted by alkyl halides by Birch reduction and subsequent decarbonylation. The method is characterized by inexpensive starting materials and reagents, and methylation of arenes was realized. Besides simple alkyl substituents, the scope of arene functionalization was extended by benzyl, fluoro, amino, and ester groups. We were able to control the alkylation of 1‐naphthoic acid during Birch reduction by the addition of tert‐butanol. This allowed the regioselective synthesis of mono and bis‐substituted naphthalenes from the same starting material. 相似文献
8.
We have fabricated tunnel junctions on thin films of Y1Ba2Cu3O7 which were epitaxially grown by magnetron sputtering on (100) and on (110) oriented SrTiO3 substrates. These junctions of the type Y1Ba2Cu3O7/barrier/Pb or In showed with high reproducibility in the conductance a gap-like structure with the maxima near±16mV. We supplied experimental arguments that this structure reflects properties of the quasi particle excitation spectrum of Y1Ba2Cu3O7. The gap-like structure was found to disappear atT
c mainly by weakening and not by a shift of the peaks to lower voltages. 相似文献
9.
Dr. Werner Fudickar Prof. Dr. Torsten Linker 《Angewandte Chemie (International ed. in English)》2018,57(39):12971-12975
The generation of reactive singlet oxygen under mild conditions is of current interest in chemistry, biology, and medicine. We were able to release oxygen from dipyridylanthracene endoperoxides (EPOs) by using a simple chemical trigger at low temperature. Protonation and methylation of such EPOs strongly accelerated these reactions. Furthermore, the methyl pyridinium derivatives are water soluble and therefore serve as oxygen carriers in aqueous media. Methylation of the EPO of the ortho isomer affords the parent form directly without increasing the temperature under very mild conditions. This exceptional behavior is ascribed to the close contact between the nitrogen atom and the peroxo group. Singlet oxygen is released upon this reaction, and can be used to oxygenate an acceptor such as tetramethylethylene in the dark with no heating. Thus, a new chemical source of singlet oxygen has been found, which is triggered by a simple stimulus. 相似文献
10.
Two different reaction pathways in the photooxygenation of 9,10-diarylanthracenes are identified, with strong evidence for polar (forward, singlet oxygen addition) and radical (backward, thermolysis) intermediates. 相似文献