全文获取类型
收费全文 | 15404篇 |
免费 | 3042篇 |
国内免费 | 2432篇 |
专业分类
化学 | 11625篇 |
晶体学 | 314篇 |
力学 | 805篇 |
综合类 | 168篇 |
数学 | 1531篇 |
物理学 | 6435篇 |
出版年
2024年 | 38篇 |
2023年 | 335篇 |
2022年 | 578篇 |
2021年 | 724篇 |
2020年 | 808篇 |
2019年 | 780篇 |
2018年 | 646篇 |
2017年 | 659篇 |
2016年 | 874篇 |
2015年 | 910篇 |
2014年 | 1113篇 |
2013年 | 1389篇 |
2012年 | 1598篇 |
2011年 | 1642篇 |
2010年 | 1177篇 |
2009年 | 1080篇 |
2008年 | 1187篇 |
2007年 | 946篇 |
2006年 | 829篇 |
2005年 | 644篇 |
2004年 | 526篇 |
2003年 | 381篇 |
2002年 | 319篇 |
2001年 | 265篇 |
2000年 | 221篇 |
1999年 | 204篇 |
1998年 | 145篇 |
1997年 | 113篇 |
1996年 | 136篇 |
1995年 | 93篇 |
1994年 | 92篇 |
1993年 | 76篇 |
1992年 | 64篇 |
1991年 | 65篇 |
1990年 | 49篇 |
1989年 | 39篇 |
1988年 | 23篇 |
1987年 | 20篇 |
1986年 | 31篇 |
1985年 | 19篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1959年 | 2篇 |
1957年 | 5篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 531 毫秒
1.
Yujie Gao Zhiye Qiu Lei Liu Mengmeng Li Bingjie Xu Dan Yu Dongming Qi Jindan Wu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2191-2212
Refractory wounds have always been an important issue to healthcare systems, whose healing process is always delayed by multiple factors, including bacterial infections, chronic inflammation, and excessive exudates, etc. Employing multifunctional wound dressings is recognized as an effective strategy to deal with refractory wounds, which has yielded promising outcomes in recent years. Among these advanced wound dressings, fibrous dressings have gained growing attention due to their unique merits. Such wound dressings have demonstrated great potential in delivering theranostic agents, such as antibacterial agents, anti-inflammatory drugs, growth factors, and diagnostic probes, etc., for the purposes of accelerating wound healing. This paper reviews the development of multifunctional fibrous dressings and their applications in treating refractory wounds. The construction approaches of novel fibrous dressing with capabilities of antibacterial, anti-inflammation, exudate management and diagnosis were also introduced. Furthermore, the existing problems and challenges are also discussed briefly. 相似文献
2.
Tian Xiu-Zhi Yang Rui Ma Jia-Jia Ni Yong-Hao Deng Hai-Bo Dai Lei Tan Jiao-Jun Zhang Mei-Yun Jiang Xue 《高分子科学》2022,40(7):789-798
Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was... 相似文献
4.
Liu Jun-Wei Shen Shu-Qian Li Ming Li Lei 《International Journal of Theoretical Physics》2021,60(5):1712-1719
International Journal of Theoretical Physics - Quantum coherence, coming from quantum superposition, occupies a significant position in the field of physics. We put forward a lower bound of the... 相似文献
5.
6.
7.
Weiyi Li Geng Leng Caiqin Li Yajing Lyu 《International journal of quantum chemistry》2020,120(8):e26150
The mechanisms of CO2 coupling with the propargylic alcohol using alkali carbonates M2CO3 (M = Li, Na, K, Cs) have been investigated by means of density functional theory calculations. The calculations reveal that the target product tetronic acid (TA) is yielded through two stages: (a) the formation of the α-alkylidene cyclic carbonate (αACC) intermediate via Cs2CO3-mediated carboxylative cyclization of the propargylic alcohol with CO2, and (b) the conversion of the αACC intermediate with Cs2CO3 to produce the cesium salt of the TA. Since the overall kinetic barriers for the two stages are comparable and affordable, the excellent chemoselectivity to the TA should be primarily originated from the high thermodynamic stability of the cesium salt of the TA. Moreover, relative to the TA, the possibility to yield the by-product acyclic carbonate can be excluded due to the both kinetics and thermodynamic inferiority. This result is different from the organic base-mediated reaction. Alternatively, our calculations predict that CsHCO3 together generated with the cesium salt of the TA might also be an available mediating reagent for the incorporation of CO2 with the propargylic alcohol. Compared to other alkali carbonates M2CO3 (M = Li, Na, K), the stronger basicity of Cs2CO3 and the lower ionic potential of cesium ion can raise the effective concentration of the αACC intermediate, and thus the conversion of the αACC intermediate into the cesium salt of the TA can be achieved with high yield. 相似文献
8.
Lei Chen Hui-Qing Yang Cheng-Yu Jin Zhao-Xu Chen 《International journal of quantum chemistry》2020,120(22):e26366
We studied the ring opening of propylene oxide (PO) by salen-M coordinated OH− group [M = Al(III), Sc(III), Cr(III), Mn(III), Fe(III), Co(II), Co(III), Ni(II), Cu(II), Zn(II), Ru(III) and Rh(III)]. The results show that the ring-opening energy barriers for M(II) complexes are much lower than those with M(III) complexes in the gas phase, and the barriers correlate linearly with the negative charges on the OH− group and the Fukui function condensed on the OH− group. The nucleophilicity ordering in the gas phase can be rationalized by the ratio of formal positive charges/radius of M cations. Solvent effect greatly increases the barriers of M(II) complexes but slightly changes the results of M(III) ones, making the barriers similar. Analysis indicates that the reaction heats are linearly proportional to the reverse reaction barriers. The relationships established here can be used to estimate the ring-opening barriers and to screen epoxide ring-opening catalysts. 相似文献
9.
Annals of the Institute of Statistical Mathematics - To obtain M-estimators of a response variable when the data are missing at random, we can construct three bias-corrected nonparametric... 相似文献
10.
Jie Lu Ju-Kang Wu Yao Jiang Dr. Peng Tan Lin Zhang Yu Lei Prof. Xiao-Qin Liu Prof. Lin-Bing Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6490-6496
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. 相似文献