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排序方式: 共有378条查询结果,搜索用时 437 毫秒
1.
Ph. Hägler B. Pire L. Szymanowski O.V. Teryaev 《The European Physical Journal C - Particles and Fields》2002,24(2):261-270
We study Pomeron-Odderon interference effects giving rise to charge and single-spin asymmetries in diffractive electroproduction
of a pair. We calculate these asymmetries, originating from both longitudinal and transverse polarizations of the virtual photon,
in the framework of QCD and in the Born approximation, in a kinematical domain accessible to HERA experiments. We predict
a sizable charge asymmetry with a characteristic dependence on the invariant mass of the pair, which makes this observable very important for establishing the magnitude of the Odderon exchange in hard processes.
The single-spin asymmetry turns out to be rather small. We briefly discuss future improvements of our calculations and their
possible effects on the results.
Received: 18 July 2002 / Published online: 25 October 2002 相似文献
2.
Lech Zielinski 《Journal of Functional Analysis》1997,150(2):453-470
We prove the asymptotic completeness of wave operators associated with the scattering of a quantum particle in a field of classical particles in the dispersive case when the free hamiltonian has the formH0=p(D) withpelliptic of degreem?1 and satisfying some convexity hypotheses. 相似文献
3.
Wojciech Bocian Jarosław Jaźwínski Lech Stefaniak Graham A. Webb 《Chemistry of Heterocyclic Compounds》1995,31(9):1103-1107
1H,13C,14N and15N NMR measurements are reported for four mesoionic 1-oxa-2, 3, 4-triazoles containing exocyclic nitrogenous groups. The NMR signal assignments are discussed and compared with those previously published for some corresponding oxatriazoles. The results obtained support the proposed cyclic mesoionic structures for the compounds studied. The questions of possible charge delocalization and valence tautomerism are addressed. Compound with N– H as a exocyclic group (Fig. 1) is found to be relatively unstable, this is attributed to proton migration in the corresponding non-cyclic form of this molecule.Published in Khimiya Geterotsikiicheskikh Soedinenii, No. 9, pp. 1260–1263, September, 1995. 相似文献
4.
I. Miesiąc K. Schügerl J. Szymanowski 《Journal of Radioanalytical and Nuclear Chemistry》1992,163(1):181-191
Potassium leakage was studied in liquid membrane systems containing various emulsifiers and compared with emulsion, stability in the storage test. The effects of various parameters upon emulsion stability and the leakage of standard traces are discussed. The transfer of cations can be caused by emulsion breaking, by transport with the specific carrier and/or with surfactants used as emulsifiers. The latter case becomes especially important when hydrophilic surfactants, e.g. ones containing polyoxyethylene chains, are present in liquid membranes. In systems containing hydrophobic emulsifiers the transfer of potassium is relatively low. In each case considered the effect of emulsifiers upon the transfer of the standard tracer should be checked prior to using the leakage test to characterize emulsion stability. 相似文献
5.
Bocian W Kawecki R Bednarek E Sitkowski J Pietrzyk A Williamson MP Hansen PE Kozerski L 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(22):5776-5787
The binding constants of camptothecin, topotecan and its lactone ring-opened carboxylate derivative to DNA octamers were measured by UV and NMR spectroscopy. The self-association of topotecan (TPT) was also measured. The carboxylate form of TPT binds in the same way as the lactone, but more weakly. Titration of TPT into d(GCGATCGC)2 shows a preferred location stacked onto the terminal G1 base. However, the intermolecular NOEs cannot be reconciled with a single conformation of the complex, and suggest a model of a limited number of conformations in fast exchange. MD calculations on four pairs of starting structures with TPT stacked onto the G1-C8 base pair in different orientations were therefore performed. The use of selected experimental "docking" restraints yielded ten MD trajectories covering a wide conformational space. From a combination of calculated free energies, NOEs and chemical shifts, some of the structures produced could be eliminated, and it is concluded that the data are consistent with two major families of conformations in fast exchange. One of these is the conformation found in a crystal of a TPT/DNA/topoisomerase I ternary complex [Proc. Natl. Acad. Sci. USA 2002, 99, 15 387-15 392]. 相似文献
6.
Alicja Wawrzynów Adam Liwo Ewa Kaczmarczyk Lech Chmurzyński 《Journal of solution chemistry》1998,27(5):463-472
Cationic heteroconjugation equilibria of more than ninety systems consisting of substituted pyridines, their N-oxides, and trimethylamine N-oxide, i. e., in systems with mixed hydrogen bridges of type OHN+ (NHO+) were studied in propylene carbonate. Both experimental systems without proton transfer, BH+/B1, and those with proton transfer, B1H+/B, were explored. The stability of the mixed hydrogen bridges, OHN+ (NHO+), is compared with that of the OHC+-type bridges. The influence of the difference in basicity of the conjugate base of the proton donor and the proton acceptor on the presence of the proton transfer equilibria, and, consequently, the possibility of determination of the cationic heteroconjugation constant values is discussed. 相似文献
7.
8.
M. B. Bogacki M. Wiśniewski J. Szymanowski 《Journal of Radioanalytical and Nuclear Chemistry》1998,228(1-2):57-61
Extraction of arsenic(V) from sulfuric acid solutions with various extractants in multistage counter-current extraction-stripping systems was compared. The extraction ability of the extractants studied showed the following order: ENIM 100>TBP=CYANEX 923>2-methylhexanol. The extraction depends significantly on the number of extraction stages and the phase ratios in extraction. The effects of the number of stripping stages and the phase ratio in stripping are less important. 相似文献
9.
Interfacial tension dat for model 2-hydroxy-5-alkylbenzophenone E oximes at toluene/water interfaces was used to discuss different versions of the copper extraction mechanism. It was found that the interfacial tension isotherms are not specific enough to distinguish different interfacial behaviour of more and less hydrophobic hydroxyoximes, but if only the interfacial process is considered then the interfacial tension data demonstrate the extraction limiting step is the reaction between hydroxyoxime molecule present near the interface and the intermediate 1'1 complex. Only in this case are the predicted reaction orders aginst hydroxyoxime in agreement with order determined experimentally. 相似文献
10.
Renata Wietecha Paweł Kościelniak Teresa Lech Tomasz Kielar 《Mikrochimica acta》2005,149(1-2):137-144
This study describes a simple, rapid and reliable method for simultaneous determination of selenium and arsenic in human hair by means of atomic fluorescence spectrometry combined with a hydride generation technique (HG-AFS). The procedure developed encompasses microwave digestion of a sample in the nitric acid environment only. The interferences caused by nitrous oxides are eliminated by removing a gas from above the digested solution with a stream of argon. The sample is then chemically treated in a flow-through hydride generation system and exposed to measurements in a double-channel atomic fluorescence spectrometer. The method permits determining both analytes in the linear range of 0.5–100µgL–1 with a detection limit equal to 0.2µgL–1, as well as with very good repeatability not exceeding 1% for Se and 2% for As. No mutual interferences from either of the analytes in the concentrations ranges matching the hair composition were found. The method was verified in terms of accuracy with the use of a reference material and then applied to the analysis of the natural samples of human hair. 相似文献