The bonding in the ozone molecule: From a different perspective

A new qualitative treatment of the bonding in ozone is presented. It is based upon a combination of several simple concepts: the nonparticipation of the pairs of electrons tightly held in the atomic 2s orbitals; simple overlap of the 2p orbitals to form sigma bonds; interaction of three 2p orbitals to yield bonding and nonbonding pi molecular orbitals that are populated by electron pairs; and van der Waals repulsion between the two terminal oxygen atoms forcing these atoms apart to yield the bond angle of 117° as a compromise. Both the assumptions and the resulting bonding picture are in accord with the photoelectron spectroscopic data, the results from sophisticated molecular orbital calculations, and the common physical properties of ozone.     

Semiclassical approach to collision-induced emission in the presence of intense laser radiation: An aspect in the study of cooperative chemical and optical pumping

Collion-induced emission in molecular systems in an intense laser field is studied using the semiclassical approach, with a view towards cooperative chemical and optical pumping in laser production. The formalism is developed with the electronic-field representation, which treats collision and radiative interaction on the same footing. Electronic-field surfaces can be regarded as forming spectra for spontaneous emission; and particular emission events can be accounted for by propagating classical trajectories on emission electronic-field surfaces. Pre-emission loss from the excited state is dealt with by propagating classical trajectories on a loss surface along a complex contour of emission branch points. This loss surface is derived on the basis of localized radiative couplings between electronic-field states and provides a framework to treat the general problem of discrete state-continuum interactions. The formalism is applied to a two-state, collinear exponential model to compute S-matrix elements and transition probabilities between asymptotic states.     

Permanent Wave Structures and Resonant Triads in a Layered Fluid

A closed three layer fluid with small density differences between the layers has two closely related modes of gravity wave propagation. The nonlinear interactions between the wave modes are investigated, particularly the nearly resonant or significant interactions. Permanent wave solutions are calculated, and it is shown that a permanent wave of the slower mode can generate resonantly a wave harmonic of the faster mode. The equations governing resonant triads of the two modes are derived, and solutions having a permanent structure are calculated from them. It is found that some resonant triad solutions vanish when the triad is embedded in the set of all harmonics with wavenumbers in its neighborhood     

Radiation effects in gas filled microballoons

Using a modified form of the computer code MEDUSA we study the effect of radiative diffusion in laser compression simulations of neon filled, thin glass microballoons. Our calculations show that the radiative preheat of the target reduces the final gas density by up to a factor 3 while the final shell density drops from 10⁵kg/m³ to 1.8 × 10⁴/kgm³.     

Anomalous magnetic field reversal in laser-plasma interactions

Two-dimensional numerical results are presented for laser produced carbon plasmas evolving through the formation of the critical surface. These results show a novel reversal of the spontaneously generated magnetic field.     

Coalitions and payoffs in three‐person sequential games: Initial tests of two formal models

In this paper we develop two formal models predicting coalitions and payoffs among rank striving players in a sequential three‐person game. We test the models’ predictions with data from a laboratory study of eleven male triads. Each triad plays a sequence of games; in each game a two‐person coalition forms and divides the coalition's point value between the two coalition partners. Participants know that the sequence of games will end without warning at a randomly chosen time; at the sequence's end each player's monetary payoff is a linear function of the rank of his accumulated point score, relative to those of the other members of his triad. The complexity of this situation prevents players and analysts from representing it as a single game; thus they are unable to use n‐person game theory to identify optimal strategies. Consequently, we assume that players, unable to develop strategies that are demonstrably optimal in the long run, adopt certain bargaining heuristics and surrogate short run objectives.

The two models follow the same basic outline; they differ, however, in the planning horizon they assume players to use. Proceeding from a priori assumptions concerning each player's decision calculus and the bargaining process, the two models state the probability that each coalition forms and predict the point divisions in the winning coalition. The laboratory data provide consistently strong support for the predictions of both models.     

G1 Smoothing Solid Objects by Bicubic Bezier Patches

A general and unified method is presented for generating a wide range of 3-D objects by smoothing the vertices and edges of a given polyhedron with arbitrary topology using bicubic Bezier patches. The common solution to the compatibility equations of $G^1$ geometric continuity between two Bezier patches is obtained and employed as the foundation of this new method such that this new solid and surface model is reliable and compatible with the solid modeling and surface modeling systems in the most common use. The new method has been embedded in an algorithm supported by our newly developed solid modeling system MESSAGE. The performance and implementation of this new algorithm show that it is efficient, flexible and easy to manipulate.     

Selenium Biofortification: Roles,Mechanisms, Responses and Prospects

The trace element selenium (Se) is a crucial element for many living organisms, including soil microorganisms, plants and animals, including humans. Generally, in Nature Se is taken up in the living cells of microorganisms, plants, animals and humans in several inorganic forms such as selenate, selenite, elemental Se and selenide. These forms are converted to organic forms by biological process, mostly as the two selenoamino acids selenocysteine (SeCys) and selenomethionine (SeMet). The biological systems of plants, animals and humans can fix these amino acids into Se-containing proteins by a modest replacement of methionine with SeMet. While the form SeCys is usually present in the active site of enzymes, which is essential for catalytic activity. Within human cells, organic forms of Se are significant for the accurate functioning of the immune and reproductive systems, the thyroid and the brain, and to enzyme activity within cells. Humans ingest Se through plant and animal foods rich in the element. The concentration of Se in foodstuffs depends on the presence of available forms of Se in soils and its uptake and accumulation by plants and herbivorous animals. Therefore, improving the availability of Se to plants is, therefore, a potential pathway to overcoming human Se deficiencies. Among these prospective pathways, the Se-biofortification of plants has already been established as a pioneering approach for producing Se-enriched agricultural products. To achieve this desirable aim of Se-biofortification, molecular breeding and genetic engineering in combination with novel agronomic and edaphic management approaches should be combined. This current review summarizes the roles, responses, prospects and mechanisms of Se in human nutrition. It also elaborates how biofortification is a plausible approach to resolving Se-deficiency in humans and other animals.