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1.
Kai Cheng Xiao-Shuai Zhang Jie An Cheng Li Ruo-Yun Zhang Run Ye Prof. Dr. Bang-Jiao Ye Prof. Dr. Bo Liu Prof. Dr. Yuan-Di Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(31):7553-7560
Given their superior penetration depths, photosensitizers with longer absorption wavelengths present broader application prospects in photodynamic therapy (PDT). Herein, Ag2S quantum dots were discovered, for the first time, to be capable of killing tumor cells through the photodynamic route by near-infrared light irradiation, which means relatively less excitation of the probe compared with traditional photosensitizers absorbing short wavelengths. On modification with polydopamine (PDA), PDA-Ag2S was obtained, which showed outstanding capacity for inducing reactive oxygen species (increased by 1.69 times). With the addition of PDA, Ag2S had more opportunities to react with surrounding O2, which was demonstrated by typical triplet electron spin resonance (ESR) analysis. Furthermore, the PDT effects of Ag2S and PDA-Ag2S achieved at longer wavelengths were almost identical to the effects produced at 660 nm, which was proved by studies in vitro. PDA-Ag2S showed distinctly better therapeutic effects than Ag2S in experiments in vivo, which further validated the enhanced regulatory effect of PDA. Altogether, a new photosensitizer with longer absorption wavelength was developed by using the hitherto-unexplored photodynamic function of Ag2S quantum dots, which extended and enhanced the regulatory effect originating from PDA. 相似文献
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Lijuan Shen Li Li Sheng Lu Xiaohan Zhang Jie Liu Junlin An Guojun Zhang Bo Wu Fei Wang 《中国颗粒学报》2015,(3):10-15
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion. 相似文献
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Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献
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就标准厚度卡片在霍尔传感器的定标方面的应用作了有益的探讨。在纵向测量微小长度时,霍尔片处于磁场边缘位置,其对磁场的梯度更大,即灵敏度更高,且靠中心位置的线性更好。 相似文献
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煤直接液化油中混合酚的分离研究 《燃料化学学报》2019,47(11):1298-1304
利用分子筛择形特点,对煤直接液化油中的混合酚实施高效分离。本研究选取间甲酚和对甲酚作为分离煤直接液化油馏分段混合酚的模型化合物,采用化学液相沉积法对HZSM-5吸附剂的孔口结构进行改变,分析分子筛硅铝比及颗粒粒径对模型化合物间甲酚和对甲酚吸附分离性能的影响,以获得高性能固相吸附剂,并将其应用于180-190℃馏分段混合酚分离。结果表明,当分子筛硅铝比为25、粒径为3-5 μm时,分子筛的孔口结构调节效果最优;当正硅酸乙酯的最小用量为0.2 mL/g时,固相吸附剂的吸附量为0.03 g/g,对甲酚选择性高于95%。由于外表面沉积物对吸附剂的孔口结构变化,导致对甲酚选择性的提高。进一步采用HZSM-5(1)吸附剂对真实煤直接液化油混合酚的分离中发现,苯酚和对甲酚的选择性均达到100%。 相似文献
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在管式反应器中采用苯甲酸、聚乙二醇、固体古马隆树脂(S)、液体古马隆树脂(L)为添加剂来降低煤沥青中有害物质苯并芘的含量,以期使得煤沥青可绿色化应用。采用紫外-可见分光光度计分析煤沥青中苯并芘含量。考察了反应温度、反应时间、添加剂添加量、催化剂等工艺条件对添加剂脱除煤沥青中苯并芘的影响。结果表明,不同工艺条件能降低煤沥青中苯并芘的含量。在优化条件下,不同添加剂对苯并芘脱除率由高到低依次为:液体古马隆树脂、聚乙二醇、苯甲酸和固体古马隆树脂。分析其反应机理,这与催化剂的酸性相关,发生亲电取代反应。结果表明,液体古马隆树脂(L)在催化剂存在下对煤沥青中苯并芘脱除率可达73.0%,显示了良好的应用前景。 相似文献
10.
对石英音叉增强型光声光谱(QEPAS)系统中常用的石英音叉进行了有限元模态计算,获得石英音叉前6阶振型与模态频率,认知了第4阶对称摆动振型为有效振动,利用单因素法分析了石英音叉的音臂长度l1、音臂宽度w1、音臂厚度t、音臂切角θ、音臂圆孔直径d及音臂圆孔高度h对低阶有效共振频率(Fre)的影响,敏感度依次为: l1> w1>d>θ>t>h,考虑实际设计情形,筛选出了l1,w1,d与h四个石英音叉设计变量,采用Box-Behnken实验设计方案与RSM(response surface methodology)方法,以Fre为函数目标,建立l1,w1,d与h的二次回归响应面模型,得到了参数之间的交互作用,利用Design-Expert软件对响应面模型进行设计参数反求,结果表明,在15 000 Hz≤Fre≤25 000 Hz计算区域内误差较小,基本满足QEPAS系统的计算需求,所提出的研究与设计方法具有一定通用性,可为QEPAS系统中石英音叉结构参数设计提供参考。 相似文献