Thermodesorption processes of langmuir layers of aliphatic acids and salts

Thermodesorption processes of mono-and multilayers of fatty acids and their salts with 14 to 24 carbon atoms were investigated by ellipsometry and IR spectroscopy. Cadmium, calcium, strontium, and barium salt layers, unlike the layers of pure acids, have a complex phase composition which includes not only separate acid and salt phases, but also intermediate acid-salt forms. The initial phase composition of multilayer systems determines their thermodesorption spectrum observed upon heating the samples. It was found that before the removal of molecules to the gaseous phase, phase transitions are possible in the films, similar to those observed in crystals and caused by the change of molecular conformations in the layer. Energy characteristics of thermodesorption processes are estimated for pure acid layers and for separate phases in salt layers. Possible qualitative models of the processes are discussed.Institute of Semiconductor Physics. Translated fromZhurnal Strukturnoi Khimii, Vol. 34, No. 6, pp. 123–130, November–December, 1993.Translated by L. Chernomorskaya     

Study of chromium ion sorption on modified silica ordered materials

The sensitivity of chemical sensors depends on the number of receptors on the surface; hence, an important role is played by the accessible support surface. Films based on silica mesoporous mesophase materials feature the highest specific surface area for silica materials, and their walls can be modified by various functional groups. In this paper, we propose to use mesoporous mesophase films as supports of sensitive elements for Cr³⁺ ions.     

On helicity conservation in the reaction π−p → A1p at 4.45 GeV/c

Helicity conservation in the reaction π^? p → pA₁ at 4.45 GeV/c has been studied using 50 cm and 55 cm liquid hydrogen bubble chambers. In the Jackson and the helicity frames the dependence of the ? matrix elements on the four-momentum transfer squared to the proton (t) for A₁ maximum decay has been calculated. The obtained data are in a good agreement with t-channel helicity conservation. The t-channel dependence of the ? matrix elements in the mentioned frames is in good agreement with that calculated using the Regge π-pole exchange model (it is suggested that the A₁ maximum nature is explained by a kinematical effect of the Deck type).     

Spectroscopy of persistent hole burning in the quantum dot-matrix system: Quantum-confined stark effect and electroabsorption

A theory of persistent spectral hole burning is developed. Within a simple, exactly solvable model (a cubic potential well with infinitely high walls in a uniform electric field), the energy spectrum and the rate of electron-hole pair generation are determined with due regard for the effect of the field induced in this case owing to the spatial separation of electrons and holes. The dependence of the energy spectrum on the field vector orientation relative to the symmetry axes of a quantum dot is studied. An expression describing the shape of the differential spectrum is derived.     

Interaction of a bispyrazole-based ligand with metal cations in ethanol

A new ligand based on two pyrazole cycles linked with each other was synthesized. Its interaction with Cu(II), Ni(II), Co(II), Mn(II), Cr(III), Zn(II), and Cd(II) cations in ethanol was studied by the spectrophotometric method.     

Dye molecules as nanosize sensors for low-temperature fuel cells

Dye molecules were suggested as a sensitive element for an optical sensor of parameters determining the efficiency of a fuel cell with a proton-exchange membrane, in which a water-methanol mixture is used as a fuel. The sensitivity of representatives of three different types of dyes to the concentrations of protons and methanol was examined.     

SuperQuat 5,5-dimethyl-4-iso-propyloxazolidin-2-one as a mimic of Evans 4-tert-butyloxazolidin-2-one

The incorporation of a gem-dimethyl group at the 5-position of a chiral oxazolidinone biases the conformation of the adjacent C(4)-stereodirecting group such that the gem-dimethyl-4-iso-propyl combination mimics a C(4)-tert-butyl group, providing higher levels of stereocontrol than a simple 4-iso-propyloxazolidinone. The generality of this principle is demonstrated with applications in stereoselective enolate alkylations, kinetic resolutions, Diels-Alder cycloadditions and Pd-catalysed asymmetric acetalisation reactions.     

Lithium amide conjugate addition for the asymmetric synthesis of 3-aminopyrrolidines

Conjugate addition of homochiral lithium amides to methyl 4-(N-benzyl-N-allylamino)but-2-enoate, chemoselective N-deprotection and concomitant cyclisation, followed by enolate functionalisation and deprotection allows access to syn- and anti-3,4-disubstituted aminopyrrolidines in > 98% d.e. and > 98% e.e.     

Optical Properties of the SiOx (x < 2) Thin Films Obtained by Hydrogen Plasma Processing of Thermal Silicon Dioxide

Optics and Spectroscopy - The optical properties and composition of thermal silicon oxide thin films processed in a hydrogen electron cyclotron resonance plasma have been studied by ellipsometry,...     

Asymmetric synthesis of 3,4-anti- and 3,4-syn-substituted aminopyrrolidines via lithium amide conjugate addition

The diastereoselective conjugate addition of homochiral lithium amides to methyl 4-(N-allyl-N-benzylamino)but-2-enoate has been used as the key step in a simple and efficient protocol for the preparation of 3,4-substituted aminopyrrolidines. This protocol provides a complementary and stereoselective route to both anti- and syn-3-amino-4-alkylpyrrolidines as well as anti- and syn-3-hydroxy-4-aminopyrrolidines, in high de and ee viabeta-amino enolate functionalisation. This methodology has been applied to the synthesis of anti-(3S,4S)- and syn-(3R,4S)-3-methoxy-4-(N-methylamino)pyrrolidine.