全文获取类型
收费全文 | 272篇 |
免费 | 0篇 |
专业分类
化学 | 170篇 |
晶体学 | 6篇 |
力学 | 3篇 |
数学 | 11篇 |
物理学 | 82篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 2篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 14篇 |
2017年 | 10篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 19篇 |
2012年 | 12篇 |
2011年 | 15篇 |
2010年 | 11篇 |
2009年 | 10篇 |
2008年 | 9篇 |
2007年 | 11篇 |
2006年 | 11篇 |
2005年 | 8篇 |
2004年 | 9篇 |
2003年 | 11篇 |
2002年 | 8篇 |
2001年 | 5篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1966年 | 2篇 |
1962年 | 1篇 |
排序方式: 共有272条查询结果,搜索用时 15 毫秒
1.
2.
Translated from Khimiya Geterotsiklicheskikh Soedinenii. Vol. 30. No. 3, pp. 424–425, March, 1994. 相似文献
3.
I. G. Alekseev P. E. Budkovsky V. P. Kanavets L. I. Koroleva B. V. Morozov V. M. Nesterov V. V. Ryltsov D. N. Svirida A. D. Sulimov V. V. Zhurkin Yu. A. Beloglazov A. I. Kovalev S. P. Kruglov D. V. Novinsky V. A. Shchedrov V. V. Sumachev V. Yu. Trautman N. A. Bazhanov E. I. Bunyatova 《Physics of Atomic Nuclei》2002,65(2):220-228
New experimental data on the spin-rotation parameters A and R measured for elastic π ± p scattering in the resonance region and on the asymmetry in pC scattering at primary momenta in the range 1.35–2.02 GeV/c, as well as in quasielastic proton scattering on nuclei in the same momentum range, are summarized. All these data were recently obtained by using the proton synchrotron installed at the Institute of Theoretical and Experimental Physics (ITEP, Moscow). The spectrum and features of seven isospin-3/2 baryon resonances that form a peak in the total cross section at a c.m. energy of 1.9 GeV are analyzed on the basis of new data on the parameters A and R, and the results of this analysis are presented. The experiments surveyed in this article were performed by a collaboration of researchers from ITEP and the Petersburg Nuclear Physics Institute (PNPI, Gatchina), the ITEP-PNPI collaboration. 相似文献
4.
5.
V. M. Novotortsev S. A. Varnavskii S. F. Marenkin L. I. Koroleva R. V. Demin V. M. Trukhan S. O. Klimonskii V. D. Kuznetsov 《Russian Journal of Inorganic Chemistry》2006,51(8):1153-1156
Solid solutions Cd1?x MnxGeP2 (x=0?0.19) have been synthesized and identified. In these solutions, the unit cell parameters decrease with an increase in the manganese content. The solid solution Cd0.81Mn0.19GeP2 is a ferromagnet with the Curie temperature T C ≈ 311 K. The paramagnetic moment of Mn2+ ions equal to 5.8 μB, as well as the spontaneous magnetization constituting 76% of the total magnetization of a crystal, has been determined with the use of the Langevin function. The origin of ferromagnetism in CdGeP2:Mn is exchange mediated by charge carriers (holes). These holes are caused by cationic defects in the structure of chalcopyrite. 相似文献
6.
M. G. Koroleva O. V. Dyablo A. F. Pozharskii Z. A. Starikova 《Chemistry of Heterocyclic Compounds》2003,39(9):1161-1171
The previously unknown 1-amino- and 3-aminonaphtho[1,2-d]imidazoles, 1-aminonaphtho[2,3-d]imidazole, 1-aminophenanthro[9,10-d]imidazole and the N-amino-N'-methylimidazolium picrates corresponding to them have been obtained by direct amination of a series of condensed imidazoles with O-picrylhydroxylamine. An X-ray structural investigation of 1-amino-3-methylnaphtho[1,2-d]imidazolium picrate showed that, in difference to 1-aminobenzimidazolium salts, a conformation exists in it in which the hydrogen atoms of the N-NH2 group are directed to the side of the meso carbon atom. 相似文献
7.
Bagiyan G. A. Koroleva I. K. Soroka N. V. Ufimtsev A. V. 《Russian Chemical Bulletin》2003,52(5):1135-1141
Side self-oxidation of thiols was studied. It was found that these reactions in neutral and alkaline solutions are induced by impurities of variable-valence metals. The ability of transition metals to catalyze oxidation of thiols changes in the order Cu > Mn > Fe > Ni Co. The plot of the self-oxidation rate vs. pH passes through a maximum whose position on the pH scale depends on both the nature of metal and the structure of the thiol oxidized. For thiols having different structures, the kinetic orders in reactions catalyzed by copper ions differently vary with pH, which is apparently associated with the formation of complexes possessing different catalytic activity. 相似文献
8.
The amounts of protein and the activities of the proteinase (trypsin) inhibitors of 16 varieties of pea have been studied. The amount of protein ranged from 19.3 to 25.2% and the amidase activities of the trypsin inhibitors from 18 to 40.8 IU. It was found that the electrophoretic spectrum of the inhibitor-containing fraction of the pea seed protein consisted of 12–16 components with molecular masses of 14–89 kDa. Features of the electrophoretic spectrum of some varieties of pea have been established.V. F. Kuprevich Institute of Experimental Botany, Belorussian SSR Academy of Sciences, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 243–247, March–April, 1989. 相似文献
9.
A. F. Pozharskii V. V. Kuz'menko V. N. Koroleva G. G. Yurchuk 《Chemistry of Heterocyclic Compounds》1980,16(5):541-546
The action of concentrated sulfuric acid on perimidine and 2-substituted perimidines, 1,3-dimethylperimidinium perchlorate, and the 1,3-dimethyl derivatives of perimidone and 2,3-dihydroperimidine gave the 6(7)-sulfonic acids of these compounds.See [1] for communication 49.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 691–696, May, 1980. 相似文献
10.
The corresponding 1-alkoxyaziridines were synthesized by oxidation of methoxy-, ethoxy-, and isopropoxyamines with lead tetraacetate in the presence of 2-methyl-2-butene and 2,3-dimethyl-2-butene. The PMR spectra of the oxidation products were investigated, and the high pyramidal stability of nitrogen in these compounds was confirmed. The individual invertomers 1-alkoxy-2,2,3-trimethylaziridines were isolated by preparative gas-liquid chromatography.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1514–1519, November, 1972.The authors thank A. A. Potekhin, I. N. Somin, R. R. Kostikov, M. I. Komendantov, and M. A. Kuznetsov for their useful discussions. 相似文献