Cross-metathesis of vinyl aromatic heterocycles with 1-octene in the presence of a Schrock catalyst

Metathesis of 2-vinyl aromatic heterocycles such as furan, thiophene, pyrrole and pyridine in the presence of a molybdenum-based Schrock catalyst has been investigated from a synthetic point of view. The self-metathesis of 2-vinyl aromatic heterocycles was not successful. However, in cross-metathesis of thiophene, furan and styrene with 1-octene, the cross-metathesis product, heterodimer, was readily obtained selectively, together with only small amounts of the two corresponding self-metathesis products. The origin of the surprisingly high selectivity of heterodimer formation was elucidated through metallacyclobutane intermediate mechanism, observations of carbenes by in situ ¹H NMR, and reaction products.     

Combinatorial and approximative analyses in a spatially random division process

For a spatial characteristic, there exist commonly fat-tail frequency distributions of fragment-size and -mass of glass, areas enclosed by city roads, and pore size/volume in random packings. In order to give a new analytical approach for the distributions, we consider a simple model which constructs a fractal-like hierarchical network based on random divisions of rectangles. The stochastic process makes a Markov chain and corresponds to directional random walks with splitting into four particles. We derive a combinatorial analytical form and its continuous approximation for the distribution of rectangle areas, and numerically show a good fitting with the actual distribution in the averaging behavior of the divisions.     

Bayesian predictive densities based on superharmonic priors for the 2-dimensional Wishart model

Bayesian predictive densities for the 2-dimensional Wishart model are investigated. The performance of predictive densities is evaluated by using the Kullback–Leibler divergence. It is proved that a Bayesian predictive density based on a prior exactly dominates that based on the Jeffreys prior if the prior density satisfies some geometric conditions. An orthogonally invariant prior is introduced and it is shown that the Bayesian predictive density based on the prior is minimax and dominates that based on the right invariant prior with respect to the triangular group.     

Isolation and structure determination of a new thiopeptide globimycin from Streptomyces globisporus subsp. globisporus based on genome mining

Based on genome-mining, a new thiopeptide globimycin was discovered from the extract of Streptomyces globisporus subsp. globisporus, along with known one radamycin. The structure of globimycin was established by a combination of 2D NMR and ESI-MS experiments, and globimycin was identified to be a structural isomer of a known thiopeptide methylsulfomycin. The proposed biosynthetic gene cluster for globimycin and radamycin was found in the genome of S. globisporus subsp. globisporus.     

Chemical etching op fission tracks in ethylene-tetrafluoroethylene copolymer

The chemical etching of fission tracks in ethylene-tetrafluoro-ethylene copolymer was studied. Etched holes 3000–4000 Å in diameter was recognized by electron microscopy for a film bombarded by fission fragments in oxygen and etched in a 12N sodium hydroxide solution at 125°C. The radial etching rate at 125°C was 6–8 Å/hr, which is less than 17 Å/hr for polyvinylidene fluoride in the same sodium hydroxide concentration at 85°C. The smaller rate is a reflection of the larger chemical resistivity of ethylene-tetrafluoro-ethylene copolymer than polyvinylidene fluoride.     

Radial compression of an antiproton cloud for production of intense antiproton beams

We report here the radial compression of a large number of antiprotons ( approximately 5 x 10(5)) in a strong magnetic field under ultrahigh vacuum conditions by applying a rotating electric field. Compression without any resonant structures was demonstrated for a range of frequencies from the sideband frequency of 200 kHz to more than 1000 kHz. The radial compression achieved is a key technique for synthesizing and manipulating antihydrogen atoms and antiprotonic atoms.     

Elution of residual ions with etching of heavy ion-injected polyimide

The experiment was carried out to estimate the amount of residual ions after the etching of polyimide irradiated by heavy ions, where etching resulted in a channel of measurable depth in the polyimide. None of the analytical techniques presents each ion separately in etched polyimide containing heavy ions. Activation analysis was used for the irradiated polyimide to see how the injected ions were eluted into the solution by etching. When the irradiated polyimide was etched for only a little longer than the time needed to dissolve a selected range of incident ions, the bulk began subsequently to dissolve. The residual radioactivity in polyimide was found to fall below the limit of detection when the depth of the etched channel appeared 10% deeper than the expected value.     

Trends of optically fed wireless communication systems

Mobile communication systems such as cellular radio and PHS are rapidly penetrating into our real life, and have gained many subscriber numbers. User demands will be growing to higher data rates that support multimedia mobile computing demands, such as graphics and motion pictures. These demands require more band width and/or spectrum utilization efficiency enhancement, and optically fed communication systems are considered to be one of the most powerful solutions. In this paper, the roles, technologies and application examples of optically fed communication systems are described. In the final part, prospects for systems and requirements for photonic devices are mentioned.