全文获取类型
收费全文 | 561篇 |
免费 | 11篇 |
国内免费 | 1篇 |
专业分类
化学 | 481篇 |
晶体学 | 3篇 |
力学 | 2篇 |
数学 | 26篇 |
物理学 | 61篇 |
出版年
2022年 | 2篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 4篇 |
2013年 | 40篇 |
2012年 | 31篇 |
2011年 | 28篇 |
2010年 | 24篇 |
2009年 | 18篇 |
2008年 | 35篇 |
2007年 | 38篇 |
2006年 | 32篇 |
2005年 | 40篇 |
2004年 | 32篇 |
2003年 | 30篇 |
2002年 | 41篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1987年 | 2篇 |
1985年 | 5篇 |
1984年 | 14篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 7篇 |
1972年 | 8篇 |
1971年 | 5篇 |
1970年 | 5篇 |
1969年 | 2篇 |
1968年 | 3篇 |
1967年 | 3篇 |
1966年 | 7篇 |
排序方式: 共有573条查询结果,搜索用时 0 毫秒
1.
2.
Hiroki Tomioka Kazuhiko Takai Koichiro Oshima Hitosi Nozaki Koshiro Toriumi 《Tetrahedron letters》1980,21(50):4843-4846
The title complex oxidizes primary and secondary alcohols to the corresponding carbonyl compounds. Stereoselective epoxidation of allylic alcohols is also described. 相似文献
3.
Treatment of the title lactone and the related δ or ε-lactones with Et2AlSR (R = Et or Ph) gave 1,3-cyclohexanediones or 1,3-cycloheptanediones in excellent yields. 相似文献
4.
[reaction: see text] A conjugated pi-electron compound, 2-aryl-3-silyl-1,3-butadiene, was easily prepared from 1-benzyloxy-3-silyl-2-propyne, bis(iodozincio)methane, and an aryl halide in the presence of nickel catalyst. A subsequent cross-coupling reaction of the product with another aryl halide gave an unsymmetrical 2,3-diaryl-1,3-butadiene efficiently. 相似文献
5.
Treatment of aliphatic aldehyde with lithium pentamethylcyclopentadienide in the presence of chlorodimethylaluminum provided the corresponding carbinol in excellent yield. The carbinol returns to the parent aldehyde and pentamethylcyclopentadiene by the action of a catalytic amount of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). 相似文献
6.
Treatment of aromatic aldehyde with lithium pentamethylcyclopentadienide provided the corresponding carbinol in excellent yield. The carbinol returns to the parent aldehyde and pentamethylcyclopentadiene upon exposure to an acid or due to heating. The combination of the two reactions can represent a protection of aromatic aldehyde. 相似文献
7.
[reaction: see text] Triethylborane-induced hydrometalation of alkynes proceeds in an anti manner to afford the corresponding (Z)-alkenylmetal compounds stereoselectively, where dichloroindium hydride would play a key role. A variety of functional groups including hydroxy, carbonyl, and carboxy groups were tolerant under the reaction conditions. Following iodolysis and cross-coupling reaction of the (Z)-alkenylmetal species show the usefulness of this strategy. 相似文献
8.
The crystal structure of SrAl2O4 at 1073 K was determined from conventional X-ray powder diffraction data using direct methods, and it was further refined by the Rietveld method. The structure was hexagonal (space group P63, Z=6) with a=0.89260(3) nm, c=0.84985(2) nm and V=0.58639(3) nm3. Final reliability indices were Rwp=7.87%, Rp=5.87% and RB=4.19%. The [AlO4] tetrahedra are linked to form trigonally distorted rings and they are joined in layers. These layers are stacked with a two-layer repeat and connected by the tetrahedral apices. All of the Sr atoms occupy the centers of the rings when viewed along the c-axis. The structure is described as a stuffed derivative of tridymite. 相似文献
9.
[reaction: see text] An aqueous biphasic reaction system enables the direct use of allyl alcohol in the Tsuji-Trost reaction without the help of any activating reagents for allyl alcohol. The reaction conditions are neutral to basic, allowing the use of amines as the nucleophile. Theoretical calculations have elucidated the importance of hydration of the hydroxy group for the smooth generation of pi-allylpalladium species. 相似文献
10.
Koichiro Nakanishi Susumu Okazaki Kenji Ikari Hidekazu Touhara 《Chemical physics letters》1981,84(3):428-432
Monte Carlo calculations have been carried out for pure water and an infinitely dilute aqueous solution of methanol at 298.15 K at ordinary density by the Metropolis method in NTV ensemble. The hydration structure around methanol revealed by a graphic display technique indicates a structure-forming effect near the hydrophobic group. 相似文献