Intergrowth between V2O5 and TiO2 (anatase): High resolution electron microscopy evidence

V₂O₅/TiO₂ (anatase) with 5 and 20 wt.% loadings of V₂O₅ have been studied using high resolution electron microscopy. This has provided the first direct evidence for the formation of a coherent interfacial boundary between two crystalline TiO₂ and V₂O₅ phases. The type of the interfacial stacking was found to be similar for all the samples, whereas the length of the boundary formed depended on the V₂O₅ loading. A model for the atomic arrangement of this boundary based on a comparison of structural positions of oxygen and metal atoms in the crystal lattices of both phases is proposed.     

Synthesis of energetic compounds bearing a (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy group

Russian Chemical Bulletin - Energetic compounds containing a new explosophoric fragment, (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy group, and furazan rings linked by azo and azoxy bridges were...     

An empirical study of common traffic congestion features based on traffic data measured in the USA,the UK,and Germany

Based on real traffic data measured on American, UK and German freeways, we study common features of traffic congestion. We have found that traffic features [J] and [S] defining traffic phases “wide moving jam” (J) and “synchronized flow” (S) in Kerner’s three-phase theory are indeed common spatiotemporal traffic features observed in the UK, the USA and Germany. For the testing of Kerner’s “line J”, representing the propagation of the wide moving jam’s downstream front, four different methods for a study of moving jam propagation in empirical data are studied and compared for each congested traffic situation occurring in the three countries. A statistical study of velocities of wide moving jam fronts is presented, which has been performed through the analysis of database containing more than 280.000 min of observed wide moving jams measured on about 1200 km long freeway network in Hessen (Germany) during more than two years.     

Generation of oxodiazonium ions 3. Synthesis of [1,2,5]oxadiazolo[3,4-c]cinnoline-1,5-dioxides

A reaction of 4-(N-nitramino)-3-phenylfuroxane with the Ac₂O/H₂SO₄ system leads to the formation of [1,2,5]oxadiazolo[3,4-c]cinnoline-1,5-dioxide, the first representative of furoxanocinnolines. The reaction presumably proceeds through the transformation of the nitramine fragment NHNO₂ to the oxodiazonium ion [N=N=O]⁺ with subsequent intramolecular attack by this cation on the phenyl ring. Furoxanocinnoline is also formed in the reaction of the 4-(N-nitramino)-3-phenylfuroxane O-methyl derivative with H₂SO₄. It is assumed that this reaction also proceeds with involvement of the intermediate cation [N=N=O]⁺ formed by the protonation of the N=N(O)OMe group and subsequent elimination of MeOH. 7-Nitro derivative is formed when furoxanocinnoline is nitrated with the concentrated HNO₃/H₂SO₄ mixture. The compounds obtained were characterized by ¹H, ¹³C, and ¹⁴N NMR spectroscopy.     

Critical current in planar SNS Josephson junctions

Specific features of the proximity effect and Josephson behavior of submicron planar SNS junctions fabricated by electron beam lithography and shadow evaporation have been studied experimentally and theoretically. The critical current of the junctions has been found to drastically increase with a decrease in temperature, which is associated with a change in the effective size of the weak link owing to the additional SN interface.     

Progress in the area of new energy-efficient basic elements for superconducting electronics

This review is devoted to a discussion of the prospects for solving the problem of a low degree of integration of the traditional elements for promising (due to the high performance and extremely low energy dissipation) superconducting digital electronics. We define three main directions on the path to compact multi-element Josephson electronic systems: (1) reduction of the Josephson junction to submicron size, (2) decrease of the area of standard logic cells, and (3) fabrication of a compact and rapid Josephson memory. We present the physical foundations of Josephson elements in order to show the fundamental constraints on establishing standard submicron tunnel contacts and compact logic cells/memory elements. This survey clearly demonstrates the essence of breakthrough technological solutions to create ultrasmall heterostructures with desired settings, reduce and optimize logic cells, and create memory unit cells based on Josephson junctions with magnetic layers.     

Synthesis of Tetrazino‐tetrazine 1,3,6,8‐Tetraoxide (TTTO)

This study presents the first synthesis and characterization of a new high energy compound [1,2,3,4]tetrazino[5,6‐e][1,2,3,4]tetrazine 1,3,6,8‐tetraoxide (TTTO). It was synthesized in ten steps from 2,2‐bis(tert‐butyl‐NNO‐azoxy)acetonitrile. The synthetic strategy was based on the sequential closure of two 1,2,3,4‐tetrazine 1,3‐dioxide rings by the generation of oxodiazonium ions and their intramolecular coupling with tert‐butyl‐NNO‐azoxy groups. The TTTO structure was confirmed by single‐crystal X‐ray.     

Bi-SQUID arrays and parallel SQIF structures for active electrically small antennas

The basic physics of the development of broadband active electrically small superconductive antennas for the subgigahertz and gigahertz frequency ranges, based on series arrays with cells characterized by a highly linear voltage response to the magnetic component B of an electromagnetic signal, are under consideration. As such cells, bi-SQUIDs and cells based on two parallel SQIF structures that are differentially connected are proposed. Series arrays of cells with linear voltage response, including an antenna prototype, are fabricated using standard niobium technology with a critical current density of Josephson junctions of 4.5 kA/cm² and are studied experimentally. The data obtained allow estimation of the achievable dV/dB conversion factor and the sensitivity ??B for an antenna integrated with a magnetic flux converter, placed on an available area of 3.3 × 3.3 mm of a chip 5 × 5 mm in size. These values are found to be 10 ??V/nT and 20 fT/Hz^1/2, respectively. The conversion factor increases in proportion with the area a ² occupied by the antenna with a square flux converter, and the sensitivity is improved as a ^?3/2.