Structure of zinc-borate low-melting glasses derived from IR spectroscopy data

The IR spectra of glasses of the ZnO—SrO—B₂O₃ system with constant additions of PbO, Al₂O₃, and Li₂O (20 mol. % in sum) were studied. It is established that on replacement of B₂O₃ by ZnO, the structure of the glasses is characterized by the presence of groupings with the bridge bonds B^III— O—B^III, B^III—O—B^IV, B^IV—O—B^IV and end groups B^III— O⁻; ZnO practically exerts no influence on the coordination transition [BO₃] → [BO₄]. At a high content of ZnO, zinc ions are present in both a six-and a four-coordinated state. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 778–781, November–December, 2005.     

Two new eudesmane derivatives from Verbesina virginica

<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods.     

Experimental validation of distinct element simulation for dynamic wheel–soil interaction

The deformation behaviour of the soil during dynamic wheel–soil interaction was studied by using the discontinuum modelling technique, distinct or discrete element method (DEM). The simulation model was developed using DEM for two types of soil, soil-A (coarse sand) and soil-B (medium sand). A transparent sided soil bin was used to observe the soil deformation. Three CCD video camera photographic images of the validation experiments were analyzed and compared with the simulation program results.This paper presents the simulation and validation results for two types of soil at three different vertical loadings of 4.9, 9.8 and 14.7 N. Wheel sinkage, vertical and horizontal draft force acting on the rigid wheel and the soil deformation images from the validation experiments were some of the data used to compare the simulation program results with the validation experiments. The simulation program was helpful to understand the complex deformation behaviour of the soils. The simulated results for the deformation behaviour of soil-B showed better correlation with the validation experiments than soil-A. The results obtained have also been compared with the previous work on DEM to explain phenomena such as the high simulated sinkage of the rigid wheel.     

Optimization with frequency constraints—limitations

After outlining an efficient algorithm for designing minimum weight structures for a specified frequency of vibration, the limitations of designing such structures are stressed. It is shown that the amount of material that would be necessary for an optimum bar or a beam of a fixed configuration (length and boundary conditions) to attain an abitrarily prescribed frequency can be disproportionately high, yielding a design that is completely impractical. In some cases there is an upper bound on the maximum frequency that can be attained irrespective of the amount of material used. The effectiveness of configuration changes in conjunction with optimization is emphasized to circumvent this difficulty.     

Effect of Pr-Ca substitution on the transport and magnetic behavior of LaMnO3 perovskite

The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO₃ perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good example of these properties is (La_1−2x Pr _x Ca _x )MnO₃ (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T _c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for understanding the structural, transport and magnetic properties are discussed in detail.     

PRESSURE-VELOCITY EQUILIBRIUM HYDRODYNAMIC MODELS

This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described.     

Tris-hydroxymethylaminomethane (THAM): An efficient organocatalyst in diversity-oriented and environmentally benign synthesis of spirochromenes

Tris-hydroxymethylaminomethane has been demonstrated to be an efficient organocatalyst in diversity-oriented synthesis of medicinally prevalent spirochromenes by one-pot, three-component reactions between isatins, malononitrile, and enolizable CH acids like dimedone, 4-hydroxycoumarin, 4-hydroxy-N-methylquinolin-2-one, or in situ generated 2-methylpyrazolon-2-one. Biodegradability and extremely low cost of the catalyst are the noteworthy features of this chromatography-free protocol.