The Ultraviolet Spectrum of the FeF Radical: A Study of the (6)Pi-X(6)Delta and (6)Phi-X(6)Delta Band Systems at 330 and 323 nm Respectively

Two band systems of FeF have been recorded at Doppler-limited linewidths by laser-induced fluorescence. The 330-nm system provided data for three subbands of the (0,0) band of the (6)Pi-X(6)Delta system and showed that levels of the (6)Pi(5/2) and (6)Pi(3/2) components are significantly perturbed. In the 323-nm system, the (0,0) band of the (6)Phi-X(6)Delta system was found to be overlapped by the (1,0) band of the (6)Pi-X(6)Delta system. Data were obtained for three subbands of the (1,0) (6)Pi-X(6)Delta system and for five subbands of the (0, 0) (6)Phi-X(6)Delta system. This work considerably extends the previous study by Pouilly et al. (B. Pouilly, J. Schamps, D. J. W. Lumley, and R. F. Barrow, J. Phys. B 11, 2281-2287 (1978)) because it is a higher resolution study with a lower temperature production of FeF by a continuous flow discharge method. The data recorded were combined with millimeter-wave data for FeF in the X(6)Delta state and fitted with an effective Hamiltonian to determine the major parameters for FeF in the X(6)Delta, (6)Pi, and (6)Phi electronic levels. Copyright 2001 Academic Press.     

The role of diffraction in dispersive optical bistability

A finite difference method is applied to the study of diffractive effects in dispersive optical bistability. Although quite elementary, the method produces extensive results in an efficient way. A detailed comparison is made with previous quasi-fast Hankel transform results, and the approach to the diffractionless limit is discussed.     

Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation of Alkynes to (Z)-Alkenes

Zero-valent palladium precatalysts containing rigid bidentate bis(arylimino)acenaphthene ligands (shown schematically) facilitate the highly stereoselective homogeneous catalytic hydrogenation of alkynes to (Z)-alkenes. Internal, terminal, aryl-substituted, and cyclic alkynes are suitable substrates, as are some enynes, which are chemoselectively hydrogenated to dienes. E=CO(2)Me; R(1), R(2)=4-OCH(3), 4-CH(3), 2,6-(CH(3))(2).     

A critical investigation of the effects of the radio frequency potential on the trapping of externally injected ions in ion trap mass spectrometry

The sensitivity of all ion trap mass spectrometry (ITMS) methods is dependent on the trapping efficiency of the instrument. For ITMS instruments utilizing external ion sources, such as laser desorption, trapping efficiency is known to depend on the phase and amplitude of the radio frequency (RF) potential applied to the ring electrode at the time of ion introduction. It is remarkable that, in a considerable body of literature, no consensus exists regarding the effects of these parameters on the efficacy of trapping externally generated ions. In this paper, a summary of the literature is presented in order to highlight significant discrepancies. New laser desorption ion trap mass spectrometry (LD-ITMS) data are also presented, from which conclusions are drawn in our effort to clarify some of the confusion. Copyright 1999 John Wiley & Sons, Ltd.     

Photoelastic determination of stresses in multiple-pin connectors

The design, fabrication, and testing of photoelastic models of double-lap, multiple-pin connectors are discussed. Interest is in the stresses in the inner laps. These stresses are determined by constructing models with photoelastic inner laps and transparent-acrylic outer laps. The connectors have two pins, in tandem, parallel to the load direction. A photoelastic-isotropic point is shown to permit the evaluation of load sharing between the two pins. A numerical scheme, utilizing the isochromatic- and isoclinic-photoelastic data and a finite-difference representation of the planestress equilibrium equations, is used to compute the stresses around the two pins. Representative stress distributions and stress-concentration factors are shown.     

A Study of the (2-0) Overtone Bands of the FO, BrO, and IO Free Radicals by Laser Magnetic Resonance

The (2-0) overtone bands of the FO, BrO, and IO free radicals in their ground electronic state X(2)Pi(3/2) have been detected by laser magnetic resonance. The data obtained from this work have been fitted together with data from previous work. A set of molecular parameters, including vibrational, rotational, centrifugal distortion, spin-orbit, lambda-doubling, hyperfine, and Zeeman terms, has been determined for each molecule. Copyright 2001 Academic Press.     

The asymptoticS-state amplitude of the deuteron wave function

Bounds on the asymptoticS-state amplitudeA _S of the deuteron wave function are calculated as a function of assumed impulse approximation values for the quadrupole moment. Alternatively, for a given value ofA _S, a bound is obtained on the minimum contribution to the experimental value ofQ _D from meson-exchange currents, relativistic effects and isobar contributions. The extraction ofA _S from low energy elastic nucleon-nucleon scattering data is discussed in detail.     

Synthesis of ylideplatinum(II) complexes via α-functionalised alkylplatinum(II) intermediates and some comparative data on palladium(II) complexes; X-ray structure of trans-[Pt(CH2PEt3)I(PEt3)2]I

The reaction of [Pt(PEt₃)₃] with CH₂I₂ affords trans-[Pt(CH₂PEt₃)I(PEt₃)₂]I and is believed to proceed via the α-functionalised alkyl cis-[Pt(CH₂I)I(PEt₃)₂], because similar ylides are obtained from cis- or trans-[PT(CH₂X)(PPh₃)₂X] (XCl, Br, or I) with PR₃ (PEt₃, PBu₃ⁿ, PMePh₂, PEtPh₂, or PPh₃); cis-[Pd(CH₂I)-I(PPh₃)₂] does not react with excess PPh₃, but with PEt₃ yields trans-[Pd(CH₂PEt₃)I(PPh₃)₂]I; the X-ray structure of trans-[Pt(CH₂PEt₃)I(PEt₃)₂]I (current R = 0.045) shows PtP(1) 2.332(7), PtP(2) 2.341(8), PtC 2.08(2), and PtI 2.666(2) Å, and angles (a) C(1)PtI, P(1), P(2): 176.9(8), 91.6(6), 93.4(6), (b) IPtP(1), P(2): 87.1(2), 88.5(2), and (c) P(1)P(2), 166.8(3), and (d) PtC(1)P(3), 118(1)°.     

Gravitational geons on the brane

In this paper, we examine the possibility of static, spherically symmetric gravitational geons on a 3 dimensional brane embedded in a 4+1 dimensional space-time. We choose a specific g _tt for the brane-world space-time metric. We then calculate g _rr analytically in the weak field limit and numerically for stronger fields. We show that the induced field equations on the brane do admit gravitational geon solutions.     

The nonlocal tensor operatorS 12 N (ρ, ρ′)

The extension of the tensor potentialS ₁₂ V _T (r) to the case of a nonlocal interaction is shown to be $$\begin{gathered} V_T (r{\text{,}}r'{\text{) = }}S_{12}^N F(r,r') \hfill \\ {\text{ = }}\tfrac{{\text{1}}}{{\text{2}}}[9(\rho \cdot \rho '{\text{)(}}\sigma _1 \cdot \rho \sigma _2 \cdot \rho '{\text{ + }}\sigma _1 \cdot \rho '\sigma _2 \cdot \rho {\text{)}} - 2(\sigma _1 \cdot \sigma _2 )]F(r,r'), \hfill \\ \end{gathered}$$ where ρ=r/r. This potential has the necessary invariance properties provided thatF(r, r′)=F(r′, r). With this potential andF(r, r′) taken to have a rank-one separable form, the behaviour of the model-deuteron radius with respect to the strength of the tensor nonlocality is investigated. It is found that the model radius decreases as the tensor nonlocality becomes more attractive. This is consistent with recent work which considers only central nonlocality.