全文获取类型
收费全文 | 233篇 |
免费 | 3篇 |
专业分类
化学 | 140篇 |
晶体学 | 1篇 |
力学 | 14篇 |
数学 | 14篇 |
物理学 | 67篇 |
出版年
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 10篇 |
2012年 | 22篇 |
2011年 | 9篇 |
2010年 | 7篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 6篇 |
2006年 | 13篇 |
2005年 | 4篇 |
2004年 | 11篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1989年 | 4篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1979年 | 4篇 |
1978年 | 8篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1943年 | 1篇 |
1937年 | 2篇 |
1936年 | 2篇 |
1923年 | 1篇 |
1919年 | 1篇 |
1912年 | 1篇 |
1910年 | 2篇 |
1901年 | 2篇 |
1900年 | 1篇 |
1895年 | 2篇 |
1894年 | 1篇 |
1891年 | 1篇 |
1888年 | 1篇 |
1886年 | 1篇 |
排序方式: 共有236条查询结果,搜索用时 17 毫秒
1.
Francis Garnier Pierre Krausz Jacques-Emile Dubois 《Journal of organometallic chemistry》1979,170(2):195-201
The photoinduced metathesis [W(CO)6CCl4hν] of cis- and trans-RCH=CHMe gives 2-butene in a very high trans but low cis stereoselectivity. Propene behaves like a cis olefin. These results are consistent with the proposal of a dinuclear tungsten intermediate, which requires high steric constraints in the transalkylidenation step. 相似文献
2.
A method is presented to reduce the memory requirement of normal mode analysis applied to systems containing two or more large proteins when these systems exhibit symmetry properties. We use a rigid geometry model (i.e., only the dihedral angles of the polypeptide chain are considered as variables). This model allows a reduction by a factor of 8 on average of the number of variables with a concomitant freezing of the high-frequency modes. The symmetry properties of the system are used to reduce further the number of variables that must be considered in the computation. Application of group theory leads to a factorization of the matrices of interest (the coefficient and the Hessian matrices) into independent blocks along the diagonal. The initial, reducible representation is thus transformed into a number of irreducible representations of smaller dimensions. In the case of the C2 symmetry group, the method leads to a reduction of the size of the matrices that must be manipulated during the computation (coefficient matrix, Hessian matrix, and eigenvectors matrix) by a factor of 256 compared with the usual normal mode analysis in Cartesian coordinate space. The method is particularly well adapted to the study of the dynamics of oligomeric proteins because these proteins often display symmetry properties (e.g., virus coat proteins, immunoglobulins, hemoglobin, etc.). In favorable cases, in conjunction with X-ray diffuse scattering data, the study of systems showing allosteric properties might be considered. © 1994 by John Wiley & Sons, Inc. 相似文献
3.
C. Bréchignac Ph. Cahuzac M. de Frutos P. Garnier 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,42(4):303-307
Mixed lithium-lithium oxide aggregates are experimentally obtained from unimolecular evaporative cascades starting at metal rich Li p + (Li2O)n species and ending with the stoichiometric limit Li+(Li2O)n, for several sizes of the oxide part (Li2O)n with 0 ≤ n ≤ 8. The results show evidence of the vanishing of the properties of the quantum metallic droplet i.e. shell closing and odd-even alternation, portrayed in the dissociation energy, with increasing size of the oxide component. The competition between monomer and dimer lithium evaporation from the heated metal rich Li p + (Li2O)n species points out the influence of the perturbation induced by the oxide component on the mixed metal oxide clusters. 相似文献
4.
Water-soluble, amphiphilic diblock copolymers were synthesized by reversible addition fragmentation chain transfer polymerization. They consist of poly(butyl acrylate) as hydrophobic block with a low glass transition temperature and three different nonionic water-soluble blocks, namely, the classical hydrophilic block poly(dimethylacrylamide), the strongly hydrophilic poly(acryloyloxyethyl methylsulfoxide), and the thermally sensitive poly(N-acryloylpyrrolidine). Aqueous micellar solutions of the block copolymers were prepared and characterized by static and dynamic light scattering analysis (DLS and SLS). No critical micelle concentration could be detected. The micellization was thermodynamically favored, although kinetically slow, exhibiting a marked dependence on the preparation conditions. The polymers formed micelles with a hydrodynamic diameter from 20 to 100 nm, which were stable upon dilution. The micellar size was correlated with the composition of the block copolymers and their overall molar mass. The micelles formed with the two most hydrophilic blocks were particularly stable upon temperature cycles, whereas the thermally sensitive poly(N-acryloylpyrrolidine) block showed a temperature-induced precipitation. According to combined SLS and DLS analysis, the micelles exhibited an elongated shape such as rods or worms. It should be noted that the block copolymers with the most hydrophilic poly(sulfoxide) block formed inverse micelles in certain organic solvents. 相似文献
5.
J.M. Dudley C. Finot G. Millot J. Garnier G. Genty D. Agafontsev F. Dias 《The European physical journal. Special topics》2010,185(1):125-133
In this contribution we describe and discuss a series of challenges and questions relating to understanding extreme wave phenomena
in optics. Many aspects of these questions are being studied in the framework of the MANUREVA project: a multidisciplinary
consortium aiming to carry out mathematical, numerical and experimental studies in this field. The central motivation of this
work is the 2007 results from optical physics [D. Solli et al., Nature 450, 1054 (2007)] that showed how a fibre-optical system can generate large amplitude extreme wave events with similar statistical
properties to the infamous hydrodynamic rogue waves on the surface of the ocean. We review our recent work in this area, and
discuss how this observation may open the possibility for an optical system to be used to directly study both the dynamics
and statistics of extreme-value processes, a potential advance comparable to the introduction of optical systems to study
chaos in the 1970s. 相似文献
6.
Camille Flament Joël Ribis Jérôme Garnier Thierry Vandenberghe Jean Henry Alexis Deschamps 《哲学杂志》2015,95(8):906-917
The age hardening 6061-T6 aluminium alloy has been chosen as structural material for the core vessel of the material testing Jules Horowitz nuclear reactor. The alloy contains incoherent Al(Cr, Fe, Mn)Si dispersoids whose characterization by energy-filtered transmission electron microscopy (EFTEM) analysis shows a core/shell organization tendency where the core is (Mn, Fe) rich, and the shell is Cr rich. The present work studies the stability of this organization under irradiation. TEM characterization on the same particles, before and after 1 MeV electron irradiation, reveals that the core/shell organization is enhanced after irradiation. It is proposed that the high level of point defects, created by irradiation, ensures a radiation-enhanced diffusion process favourable to the unmixing forces between (Fe, Mn) and Cr. Shell formation may result in the low-energy interface segregation of Cr atoms within the (Fe, Mn) system combined with the unmixing of Cr, Fe and Mn components. 相似文献
7.
Jean Roncali Francis Garnier Robert Garreau Didier Delabouglise Marc Lemaire 《Macromolecular Symposia》1989,24(1):77-90
The mechanism of the electropolymerization of thiophene derivatives has been investigated by varying the electrosynthesis conditions and the monomer structure. The results of these analyses led to the definition of optimized electrosynthesis conditions allowing the control of the electrical and electrochemical properties of poly(thiophenes). On the basis of these results, the properties of these polymers have been modified by means of a new one-step electrosynthesis of conducting composite materials and by the direct electropolymerization of tailor-made functionalized monomers. For this purpose, the steric conditions associated to the various possibilities of covalent derivatization have been analyzed, leading to the definition of a “functionalization space”, compatible with the preservation of high conductivity and electrochemical reversibility in the resulting polymers. This concept has been applied to the synthesis of highly conducting chiral poly(thiophenes) on which an effect of enantioselective molecular recognition has been demonstrated for the first time. 相似文献
8.
This research deals with the ultrasonic characterization of thermal damage in concrete. This damage leads to the appearance of microcracks which then evolve in terms of volume rate and size in the material. The scattering of ultrasonic waves from the inclusions is present in this type of medium. The propagation of the longitudinal wave in the heterogeneous media is studied via a homogenization model that integrates the multiple scattering of waves. The model allows us to determine the phase velocity and the attenuation according to the elements which make the medium. Simulations adapted to the concrete are developed in order to test the responses of the model. These behaviors are validated by an experimental study: the measurements of phase velocity and attenuation are performed in immersion, with a comparison method, on a frequency domain which ranges from 160 kHz to 1.3 MHz. The analysis of different theoretical and experimental results obtained on cement-based media leads to the model validation, on the phase velocity behavior, in the case of a damage simulated by expanded polystyrene spheres in granular media. The application to the case of a thermally damaged concrete shows a good qualitative agreement for the changes in velocity and attenuation. 相似文献
9.
L. Despont F. Clerc M. G. Garnier H. Berger L. Forró P. Aebi 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,52(3):421-426
Multiple scattering theory based on a
cluster model is used to simulate full hemispherical X-ray photoelectron
diffraction measurements on a 1T-TaS2(0001) surface. Key points to determine the surface termination are discussed. As the commonly applied single scattering simulations
do not give satisfying results, a multiple scattering approach has to be used to accurately simulate the full hemispherical
photoelectron diffraction patterns. Differences and similarities between calculations of Ta and S terminated surfaces are
presented along with experimental results at room temperature using both, the single and the multiple scattering approaches.
We find that the surface is S terminated and that the quantitative difference between the calculations for both terminations
permits to show the limits of the single scattering approach for solving surface termination problems. Moreover, by generalizing
the results obtained using the multiple scattering approach, we discuss the application of this method to other similar systems. 相似文献
10.
Dr. Siddhartha De Dr. Alexandrine Flambard Dr. Delphine Garnier Patrick Herson Dr. Frank H. Köhler Dr. Abhishake Mondal Dr. Karine Costuas Dr. Béatrice Gillon Prof. Rodrigue Lescouëzec Dr. Boris Le Guennic Dr. Frédéric Gendron 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12120-12136
The local magnetic structure in the [FeIII(Tp)(CN)3]− building block was investigated by combining paramagnetic Nuclear Magnetic Resonance (pNMR) spectroscopy and polarized neutron diffraction (PND) with first-principle calculations. The use of the pNMR and PND experimental techniques revealed the extension of spin-density from the metal to the ligands, as well as the different spin mechanisms that take place in the cyanido ligands: Spin-polarization on the carbon atoms and spin-delocalization on the nitrogen atoms. The results of our combined density functional theory (DFT) and multireference calculations were found in good agreement with the PND results and the experimental NMR chemical shifts. Moreover, the ab-initio calculations allowed us to connect the experimental spin-density map characterized by PND and the suggested distribution of the spin-density on the ligands observed by NMR spectroscopy. Interestingly, significant differences were observed between the pseudo-contact contributions of the chemical shifts obtained by theoretical calculations and the values derived from NMR spectroscopy using a simple point-dipole model. These discrepancies underline the limitation of the point-dipole model and the need for more elaborate approaches to break down the experimental pNMR chemical shifts into contact and pseudo-contact contributions. 相似文献