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1.
Synthesis of diisocyanides with phenolic groups and their polymerization to helically chiral poly(quinoxaline‐2,3‐diyl)s
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Johannes Scholz Michael Reggelin 《Journal of polymer science. Part A, Polymer chemistry》2015,53(11):1320-1329
The development of synthetic routes which lead to five new diisocyanide monomers with one or two phenolic groups is described. Their polymerization behavior is studied with Pd‐ and Ni‐based initiators, as well as under microwave irradiation. The polymerizability is mainly dominated by steric effects as is concluded from experiments using different protecting groups. Chiroptical properties of these new polymers are studied by CD‐spectroscopy. After deprotection, helically chiral poly(quinoxalin‐2,3‐diyl)s are obtained which display a Brønsted function attached to a stereolabile biaryl axis whose configuration should be influenced by the chiral polymer backbone. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1320–1329 相似文献
2.
3.
Arno Jüschke Johannes Jahn Andreas Kirsch 《Computational Optimization and Applications》1997,7(3):261-276
In this paper we consider a special optimization problem withtwo objectives which arises in antenna theory. It is shown that thisabstract bicriterial optimization problem has at least one solution.Discretized versions of this problem are also discussed, and therelationships between these finite dimensional problems and the infinitedimensional problem are investigated. Moreover, we presentnumerical results for special parameters using a multiobjectiveoptimization method. 相似文献
4.
John L. Wood Johannes Schwarzenberg Edward F. Zganjar Dubravka Rupnik 《Hyperfine Interactions》1992,75(1-4):51-58
State-of-the-art spectroscopy of nuclei far from stability has achieved an extraordinary level of sophistication and detail
in the last ten years. In principle, if a state can be populated, it can be characterized by its energy, spin, parity, and
major decay paths. Sometimes its lifetime can be measured. In practice, one is confronted with enormous complexity. To convert
raw spectroscopic data into nuclear structure data involves a complex process of disentangling gamma rays and conversion electrons
into decay schemes. Specifically, coincidence techniques, especially coincidence intensities, play a crucial role in this
process. Recent examples and methods from work done at UNISOR are presented. 相似文献
5.
Florin Radu Alexei Nefedov Johannes GrabisGregor Nowak Andre BergmannHartmut Zabel 《Journal of magnetism and magnetic materials》2006
We have used soft X-ray resonant magnetic scattering (XRMS) to search for the presence of an effective ferromagnetic moment belonging to the antiferromagnetic (AF) layer which is in close contact with a ferromagnetic (F) layer. Taking advantage of the element specificity of the XRMS technique, we have measured hysteresis loops of both Fe and CoO layers of a CoO(40 Å)/Fe (150 Å) exchange bias bilayer. From these measurements we have concluded that the proximity of the F layer induces a magnetic moment in the AF layer. The F moment of the AF layer has two components: one is frozen and does not follow the applied magnetic field and the other one follows in phase the ferromagnetic magnetization of the F layer. The temperature dependence of the F components belonging to the AF layer is shown and discussed. 相似文献
6.
7.
We study a class of shape optimization problems for semi-linear elliptic equations with Dirichlet boundary conditions in smooth
domains in ℝ2. A part of the boundary of the domain is variable as the graph of a smooth function. The problem is equivalently reformulated
on a fixed domain. Continuity of the solution to the state equation with respect to domain variations is shown. This is used
to obtain differentiability in the general case, and moreover a useful formula for the gradient of the cost functional in
the case where the principal part of the differential operator is the Laplacian.
Online publication 23 January 2004. 相似文献
8.
9.
Auguet C. Martorell F. Moll F. Torra V: 《Journal of Thermal Analysis and Calorimetry》2002,70(1):277-290
The miniaturized calorimetric devices furnish a reduced working flat surface and permits measurements with extremely low-mass
quantities. The experimental sensitivity shows relevant position dependence with x-y surface coordinates and with z-distance. The device identification is realized via a 2-D model based in Fourier general equation.
Using the Marquardt method the experimental flat surface device can be identified and the fitted parameters used to simulate
the behavior of the experimental system. From the model, the effects of several dissipation configurations can be evaluated.
Also, via the RC-analogy, a way to 3-D experimental devices is roughly described.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
10.
Editor's preface 总被引:1,自引:0,他引:1
Johannes Jahn 《Mathematical Methods of Operations Research》1991,35(3):I-I