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1.
Pentafluorosulfanyl (SF5)-containing compounds and corresponding analogs are a highly valuable class of fluorine-containing building blocks owing to their unique properties. The reason for that is the set of peculiar and tremendously beneficial characteristics they can impart on molecules once introduced onto them. Despite this, their application in distinct scientific fields remains modest, given the extremely harsh reaction conditions needed to access such compounds. The recent synthetic approaches via S−F, and C−SF5 bond formation as well as the use of SF5-containing building blocks embody a “stairway-to-heaven” loophole in the synthesis of otherwise-inaccessible chemical scaffolds only a few years ago. Herein, we report and evaluate the properties of the SF5 group and analogs, by summarizing synthetic methodologies available to access them as well as following applications in material science and medicinal chemistry since 2015.  相似文献   
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Summary We present an approximation method of a space-homogeneous transport equation which we prove is convergent. The method is very promising for numerical computation. Comparison of a numerical computation with an exact solution is given for the Master equation.  相似文献   
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Let A be a symmetric matrix of size n×n with entries in some (commutative) field K. We study the possibility of decomposing A into two blocks by conjugation by an orthogonal matrix T∈Matn(K). We say that A is absolutely indecomposable if it is indecomposable over every extension of the base field. If K is formally real then every symmetric matrix A diagonalizes orthogonally over the real closure of K. Assume that K is a not formally real and of level s. We prove that in Matn(K) there exist symmetric, absolutely indecomposable matrices iff n is congruent to 0, 1 or −1 modulo 2s.  相似文献   
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 Nuclear Magnetic Resonance (NMR) was used to investigate the extrusion behaviour of PTFE pastes in a ram extruder. By means of 1H-NMR imaging (MRI) it is possible to determine the local proton density and therefore, the local fluid concentration. The 19F-MRI provides the local solid concentration. Thus the local saturation and the local porosity can be calculated with the information of the local fluid and solid concentration. Furthermore displacement profiles can be derived from NMR images by means of correlation techniques without any preparation or marking of the pastes. Received: 8 May 2000   Accepted: 1 May 2001  相似文献   
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From the definition of spinors as the minimal left (right) modules of multivectors (that is, of vectors and their outer products), we can construct a unified mathematical approach for the study of matter and its interaction fields, which are either defined as fields in the geometrical spacetime or considered as generators of the physical spacetime. It is also shown how matter and interaction fields can be represented either by spinor fields or by multivector fields, both types of fields carrying the same information as the traditional corresponding spinors, vectors, or tensors. Geometry is more transparent in one representation (multivector form), and physics is more obvious in the spinor representation. Our theory provides a unified and totally self-consistent representation of quarks (barions), leptons, and all their known interactions.  相似文献   
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Rees  D. A. S.  Magyari  E.  Keller  B. 《Transport in Porous Media》2003,53(3):347-355
The effect of viscous dissipation on the development of the boundary layer flow from a cold vertical surface embedded in a Darcian porous medium is investigated. It is found that the flow evolves gradually from the classical Cheng–Minkowycz form to the recently discovered asymptotic dissipation profile which is a parallel flow.  相似文献   
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Matrix extensions and eigenvalue completions, the generic case   总被引:2,自引:0,他引:2  
In this paper we provide new necessary and sufficient conditions for the so-called eigenvalue completion problem.

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