6-Oxy-(N-succinimidyl acetate)-9-(2'-methoxycarbonyl)fluorescein as a new fluorescent labeling reagent for aliphatic amines in environmental and food samples using high-performance liquid chromatography

6-Oxy-(N-succinimidyl acetate)-9-(2'-methoxycarbonyl)fluorescein (SAMF), a new fluorescein-based amine-reactive fluorescent probe was well designed, synthesized and used as a pre-column derivatizing reagent for the determination of aliphatic amines in HPLC. It exhibited relatively pH-independent fluorescence (pH 4-9) and excellent photostability. The derivatization was performed at room temperature in 6min. On a C18 column, the derivatives of SAMF with eight aliphatic amines were baseline separated in 28 min with a mobile phase of methanol-water (57:43, v/v) containing 10 mmol l(-1) pH 5.0, H3Cit3-NaOH buffer. With fluorescent detection at lambda(ex)/lambda(em) = 484/516 nm, the detection limit could reach 2-320 fmol (signal-to-noise = 3), which was equivalent to or better than the detection limits obtained from other analytical methods of aliphatic amines. The proposed method has been applied to the determination of the aliphatic amines in environmental and food samples such as lake water, red wine, white wine, and cheese with satisfying recoveries varying from 95 to 106%.     

N,N'-二(二乙氧基硫代磷酰基)-1,4-苯二胺的合成、晶体结构及热性能研究

通过二乙氧基硫代磷酰氯与对苯二胺反应生成了标题化合物N,N'-二(二乙氧基硫代磷酰基)-1,4-苯二胺，并应用元素分析, FTIR及¹H NMR对标题化合物进行了表征. 利用X射线单晶衍射测定了其晶体结构, 同时应用TG分析法对其热性能进行了分析. 标题化合物的相对分子质量M_r＝412.42, 为正交晶系, Pbca空间群, 晶胞参数为a＝0.86936(16) nm, b＝1.2787(2) nm, c＝1.8897(3) nm, β＝90°, V＝2.1006(7) nm³, Z＝8, D_c＝1.304 g/cm³, μ(Mo Kα)＝0.425 mm^－1, F(000)＝872, S＝1.052. 最终偏离因子R＝0.0628, wR＝0.1860, 可观测衍射点1852个[I＞2σ(I)]. 该晶体通过对苯二胺连接并以中心对称分布, 并形成层状结构, 且存在弱的分子内氢键N—H…S. TG分析表明该化合物有很好的热稳定性及成炭性, 通过其阻燃聚丙烯腈表明, 该物质是一种高效能的膨胀型阻燃剂.     

B0d→φK*0极化反常和Bd→φKs CP不对称的研究

在模型Ⅲ下,仅考虑来自于中性规范玻色子H0,H0和A0产生的树图阶味改变中性流的贡献,并利用QCD因子化方法,对B0d→φK(≠)0衰变过程的极化反常和Bd→φKs衰变过程的CP不对称进行了研究,经过计算发现,在147＜|λbsλss|＜165的参数范围内,这两个过程中存在的反常现象能够同时给予解释.     

TiO_2纳米管阵列薄膜制备及生长机理的研究

本论文采用阳极氧化的方法,在NH4HF2+NH4H2PO4的混合水溶液中于室温下以金属钛为基体原位合成氧化钛纳米管阵列薄膜。讨论了电解液成分、外加电压、溶液的pH值对氧化钛纳米管阵列薄膜微观结构及形貌的影响,并建立了阳极氧化钛纳米管阵列薄膜的生长模型。氧化钛纳米管的结构与外加电压有很大的关系,只有电压在5～35V范围内才能制备出二氧化钛纳米管阵列薄膜,其管径随着电压的升高而增加,且管径范围为30～160nm。而薄膜的厚度与电解液有关,通过控制电解液的成分及pH值,可获得厚度为6.5μm的氧化钛纳米管阵列薄膜。     

一般球对称带电蒸发黑洞的熵

从一般球对称带电蒸发黑洞的时空线元和零曲面方程出发,得到了该黑洞的视界;利用KleinGordon方程求得波数,进而采用WenzelKramersBrillouin近似方法和薄膜brickwall模型,求出了一般球对称带电蒸发黑洞的熵,所得的熵正好与该黑洞的视界面积成正比 关键词： 黑洞 KleinGordon方程 熵 薄膜brickwall模型 视界     

Study of the η'→Ve~+e~- decay with hidden local symmetry model

Within the hidden local symmetry framework, the Dalitz decay η→Ve+e-is studied with the vector meson dominance model. It is found that the partial width Γ(η→ωe+e-)≈40 e V and branching ratio B(η→ωe+e-)≈2×10-4, and Γ(η→ρe+e-)≈10Γ(η→ωe+e-) and B(η→ρe+e-)≈10B(η→ωe+e-). The maximum position of the dilepton distribution is m e+e-≈1.33 Me V. These decays are measurable with the advent of high statistic ηexperiments.     

CP violation in B→φKs decay in R-parity violating supersymmetry

In the framework of R-parity violating supersymmetry, we investigate the time dependent CP asymmetry SφKs anomaly of B→φKs decay. When the values of the weak phase φ in the R-parity violating coupling fall into certain parameter spaces (246°<φ<263°) we find that this anomaly can be easily ex-plained; at the same time, the branching ratio of B →φKs decay can also be in agreement with experimental measurements.     

Searches for the technicolor signatures via gg → W±πt± at the Large Hadron Collider

In this paper, we calculate the production of a charged top pion in association with a W boson via gg fusion at CERN's Large Hadron Collider in the context of the topcolor assisted technicolor model. We find that the total cross section of pp → gg → W^±π_t is several dozen femtobarns with reasonable values of the parameters, and the total cross section of pp → W^±π_t can reach a few hundred femtobarns when we consider the sum of the contributions of these two parton subprocesses, gg → W^±π_t and bb → W^±π_t.     

NO在Ir(111)表面吸附与解离的第一性原理研究

本文系统研究了NO在Ir(111)表面的吸附,解离,以及可能的N_2生成机理.结果表明,顶位吸附的NO,其解离能垒较高(3.17 eV),不会发生解离,而三重Hcp和Fcc空位吸附的NO发生解离,能垒分别为1.23和1.28 eV.N_2是唯一的生成物,不会有副产物N_2O的产生.其最可能的反应路径为N和NO经过N_2O中间体而生成N_2,而不是直接N提取和N-N聚合产生N_2的机理.     

脉冲电沉积法制备Pt-TiO2 纳米管电极及其电催化性能

采用阳极氧化法在高纯钛片上原位组装TiO2纳米管阵列, 然后用脉冲电沉积方法将Pt沉积到TiO2纳米管阵列上, 制备出Pt-TiO2纳米管电极. 利用XRD和SEM对所获电极的微观结构和形貌进行表征, 结果表明, Pt纳米颗粒以花簇状分散在TiO2纳米管上, 晶粒大小约为25.6 nm. 对甲醇的电催化性能的研究结果表明, 脉冲电沉积制得的Pt-TiO2纳米管电极比TiO2纳米管电极和纯Pt片电极具有更高的电催化活性, 是Pt电极的40多倍.