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1.
Journal of Fluorescence - This report describes a combined immunofluorescence and fluorescence viability stain applied as one staining solution for rapid detection of live Legionella... 相似文献
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P. Seelig A. Dax S. Faber M. Gerlach G. Huber T. Kühl D. Marx P. Merz W. Quint F. Schmitt H. Winter M. Würtz 《Hyperfine Interactions》1998,114(1-4):135-139
The investigation of the 1s HFS provides a good possibility for testing QED effects in a combination of a strong electric
and magnetic field. Here, we report about the laserspectroscopic measurements of the ground state hyperfine splitting in 207Pb81+. To handle this M1-transition in the infrared optical regime with its long lifetime, we developed a new detection technique
using a bunched ion beam. For the observation of fluorescence light, a new mirror system is adapted to the emission characteristics
from an ion beam at relativistic velocities.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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The synthesis of oligonucleotides containing 7-(2-deoxy-β -D -erythro-pentofuranosyl)adenine (N7Ad; 1 ) is described. Compound 1 was obtained from the precursor 4-amino-1H -imidazole-5-carbonitrile 2-deoxyribonucleoside 6 and was found to be much more labile than Ad. The N6-benzoyl protecting group (see 8 ) destabilized the N-glycosylic bond further and was difficult to remove by NH3-catalyzed hydrolysis. Therefore, a (dimethyl-amino)methylidene residue was introduced (→ 9 ). Amidine 9 was blocked at OH? C(5′) with the dimethoxytrityl residue ((MeO)2Tr), and phosphonate 4 as well as phosphoramidite 5 were prepared under standard conditions. Phosphonate 4 was employed in solid-phase oligonucleotide synthesis. Homooligonucleotides as well as self-complementary oligonucleotides were prepared. The oligomer d[(N7A)11-A] ( 11 ) formed a duplex with d(T12) ( 13 ). Antiparallel chain polarity and reverse Watson-Crick base pairing was deduced from duplex formation of the self-complementary d[(N7A)8-T8] ( 14 ). 相似文献
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Aspects of Generic Entanglement 总被引:4,自引:4,他引:0
Patrick Hayden Debbie W. Leung Andreas Winter 《Communications in Mathematical Physics》2006,265(1):95-117
We study entanglement and other correlation properties of random states in high-dimensional bipartite systems. These correlations
are quantified by parameters that are subject to the ``concentration of measure' phenomenon, meaning that on a large-probability
set these parameters are close to their expectation. For the entropy of entanglement, this has the counterintuitive consequence
that there exist large subspaces in which all pure states are close to maximally entangled. This, in turn, implies the existence
of mixed states with entanglement of formation near that of a maximally entangled state, but with negligible quantum mutual
information and, therefore, negligible distillable entanglement, secret key, and common randomness. It also implies a very
strong locking effect for the entanglement of formation: its value can jump from maximal to near zero by tracing over a number
of qubits negligible compared to the size of the total system. Furthermore, such properties are generic. Similar phenomena
are observed for random multiparty states, leading us to speculate on the possibility that the theory of entanglement is much
simplified when restricted to asymptotically generic states. Further consequences of our results include a complete derandomization
of the protocol for universal superdense coding of quantum states. 相似文献
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Jeremy R. Lizotte Sara G. Anderson Timothy E. Long 《Journal of polymer science. Part A, Polymer chemistry》2004,42(7):1547-1556
A novel dinitroxide mediating agent that was suitable for stable free‐radical polymerization was synthesized and used in the block copolymerization of styrene and t‐butyl styrene. Quantitative yields of a novel dinitroxide based on 1,6‐hexamethylene diisocyanate and 4‐hydroxy‐2,2,6,6‐tetramethyl‐1‐piperidinyloxy were obtained. Various experimental parameters, including the nitroxide‐to‐initiator molar ratio, were examined, and it was determined that the polymerization was most controlled under conditions similar to those of conventional 2,2,6,6‐tetramethyl‐1‐piperidinyloxy‐mediated stable free‐radical polymerization. Moreover, the dinitroxide mediator proved to be a viable route for the facile two‐step synthesis of triblock copolymers of styrene and t‐butyl styrene. However, the dinitroxide mediation process resulted in a higher than expected level of nitroxide decomposition, which resulted in polymers possessing a terminal alkoxyamine and an adjacent hydroxylamine rather than a preferred internal bisalkoxyamine. This decomposition resulted in the formation of diblock copolymer species during the triblock copolymer synthesis. Gel permeation chromatography was used to monitor the chain‐end decomposition kinetics, and the determined observed rate constant (5.89 × 10?5 s?1) for decomposition agreed well with previous studies for other dinitroxide mediating agents. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1547–1556, 2004 相似文献
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