One‐pot synthesis of 1‐ and 5‐substituted 1H‐tetrazoles using 1,4‐dihydroxyanthraquinone–copper(II) supported on superparamagnetic Fe3O4@SiO2 magnetic porous nanospheres as a recyclable catalyst

An effective one‐pot, convenient process for the synthesis of 1‐ and 5‐substituted 1H‐tetrazoles from nitriles and amines is described using1,4‐dihydroxyanthraquinone–copper(II) supported on Fe₃O₄@SiO₂ magnetic porous nanospheres as a novel recyclable catalyst. The application of this catalyst allows the synthesis of a variety of tetrazoles in good to excellent yields. The preparation of the magnetic nanocatalyst with core–shell structure is presented by using nano‐Fe₃O₄ as the core, tetraethoxysilane as the silica source and poly(vinyl alcohol) as the surfactant, and then Fe₃O₄@SiO₂ was coated with 1,4‐dihydroxyanthraquinone–copper(II) nanoparticles. The new catalyst was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, dynamic light scattering, thermogravimetric analysis, vibration sample magnetometry, X‐ray photoelectron spectroscopy, nitrogen adsorption–desorption isotherm analysis and inductively coupled plasma analysis. This new procedure offers several advantages such as short reaction times, excellent yields, operational simplicity, practicability and applicability to various substrates and absence of any tedious workup or purification. In addition, the excellent catalytic performance, thermal stability and separation of the catalyst make it a good heterogeneous system and a useful alternative to other heterogeneous catalysts. Also, the catalyst could be magnetically separated and reused six times without significant loss of catalytic activity. Copyright © 2016 John Wiley & Sons, Ltd.     

Microleakage and antibacterial properties of ZnO and ZnO:Ag nanopowders prepared via a sol–gel method for endodontic sealer application

A novel method, recently proved useful for the synthesis of nanoparticles, has been now used for the preparation of very stable silver iodide–trihexyl(tetradecyl)phosphonium chloride ionanofluids. Only the ionic liquid and the AgI bulk powder were needed. Synthesized nanofluids are much more stable than those obtained by simple dispersion of the nanoparticles in the base fluid. The ionanofluids were synthesized at different concentrations (up to 50 % w/w) and characterized in terms of physical, electrical, and thermal properties (density, viscosity, refractive index, electric conductivity, and specific heat capacity). A very high increase in the electric conductivity of the base ionic liquid was expected due to the high concentration of nanoparticles achieved. Nonetheless, it was not found, probably due to the reduction of ions mobility caused by the increase of the viscosity in ionanofluids with concentrations over 20 % w/w. An appropriate characterization of nanoparticles composing the nanofluids was carried out (UV–Vis absorbance, shape and size distribution). The diameter of the particles was measured and calculated by different techniques and approximations, obtaining a value of 2–4 nm. They were spherical, well-defined, and not agglomerated, with a narrow size distribution. The X-ray powder diffraction confirmed that no structural change took place in the transformation of the bulk solid to nanoparticles.     

Object recognition by use of polarimetric phase-shifting digital holography

Pattern recognition by use of polarimetric phase-shifting digital holography is presented. Using holography, the amplitude distribution and phase difference distribution between two orthogonal polarizations of three-dimensional (3D) or two-dimensional phase objects are obtained. This information contains both complex amplitude and polarimetric characteristics of the object, and it can be used for improving the discrimination capability of object recognition. Experimental results are presented to demonstrate the idea. To the best of our knowledge, this is the first report on 3D polarimetric recognition of objects using digital holography.     

Synthesis and Characterization of H3PW12O40 and H3PMo12O40 Nanoparticles by a Simple Method

In this study H₃PW₁₂O₄₀·9H₂O and H₃PMo₁₂O₄₀·6H₂O (HPA) particles were changed into nano forms by heat-treatment in an autoclave as a simple, repaid, inexpensive and one step method. The particle size of these nanoparticles was around 25 nm. The as-synthesized nanostructures were characterized by dynamic light scattering, X-ray powder diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy and inductively coupled plasma analyzer. Thermal stability of nanoparticles was surveyed by thermal gravimeter analyse. Acidity of prepared nanoparticles was investigated by pyridine adsorption method. Results showed rising acidity by declining particle size of HPA.     

Three-dimensional image fusion by use of multiwavelength digital holography

We present three-dimensional (3D) image fusion by use of digital holography. We demonstrate experimentally that, through the image fusion technique with multiresolution wavelet decomposition, it is possible to increase the details and contrast of 3D reconstructed images obtained by multiwavelength digital holography. Although there is substantial activity in the fields of image fusion and holography, to the best of our knowledge, this is the first report of 3D image fusion by use of digital holography.     

Effects of device resolution on three-dimensional integral imaging

We present the effects of a finite number of pixels in elemental images on the resolution and the depth of focus in three-dimensional integral imaging (II). We show that the number of pixels in elemental images determines not only the lateral resolution but also the depth resolution. The minimum number of pixels required in each elemental image is calculated to avoid depth-of-focus degradation. We evaluate how II system performance degrades as the number of pixels in each elemental image changes. The product of the depth of focus and the lateral resolution squared is used as the performance metric.     

Three-dimensional polarimetric integral imaging

A three-dimensional (3D) polarimetric image sensing and display technique based on integral imaging is proposed. Three-dimensional polarization distribution of reflected light from a 3D object can be measured as elemental image arrays by a rotating linear polarizer. After the measurement of the polarization of the 3D object, the 3D polarimetric object can be reconstructed optically by displaying the polarization-selected elemental images in spatial light modulators with two quarter-wave plates. Experimental demonstration of 3D polarimetric imaging of a 3D object attached to two orthogonal linear polarizers is presented. To the best of our knowledge, this is the first report on 3D polarimetric sensing imaging and 3D optical reconstruction by integral imaging.     

Three-dimensional integral imaging with large depth of focus by use of real and virtual image fields

We present an integral imaging method to enhance the depth of a three-dimensional image by displaying it throughout real and virtual image fields. When the product of depth and resolution square of the displayed three-dimensional image is used as a figure of merit in integral imaging systems, our method can maximize this merit especially when three-dimensional images with large depth of focus are displayed. The feasibility of our method is experimentally demonstrated by generation of elemental images by a computer.     

Exact solitary wave solution of Boussinesq equation by VIM

In this paper, the well known He’s variational iteration method (VIM) is used to construct solitary wave solutions for Boussinesq equation (BE). The chosen initial solution (trial function) can be in soliton form with some unknown parameters which can be determined in the solution procedure.     

Axially distributed sensing for three-dimensional imaging with unknown sensor positions

Recently, an axially distributed sensing system was proposed for three-dimensional (3D) imaging where the sensors are distributed along the optical axis. In this previously reported system, a priori knowledge of exact sensor positions was required for 3D image reconstruction. In this Letter, we present an axially distributed sensing with unknown sensor positions along the optical axis. In this system, only the relative positions of two sensors are needed, whereas all other sensor positions are assumed unknown. Experiments are presented to illustrate the feasibility of the proposed system and illustrate the visual quality of reconstructed 3D images by using the proposed calibrated sensor positions. To the best of our knowledge, this is the first report on axially distributed sensing with unknown sensor positions.