Shape Transition and Triaxial Interaction Effect in the Structure of 152-166Dy Isotopes

The positive parity states in even-even ^152-166Dy are studied systematically in the framework of the interacting boson model (IBM). A cubic term, L=3, has been added to the Hamiltonian in order to produce the effect of triaxiality on the energy spectrum. The potential energy surfaces as a function of β and γ deformation parameters, for all isotopes have been produced. Energy levels and reduced electric quadrupole transition probabilities are calculated in framework of IBM with Cubic term (IBMC). All results are compared with available experimental data. It is found that these isotopes can be described by a schematic Hamiltonian in transition from U(5) (vibration) to SU(3) (rotation) dynamic symmetry.     

Formation of polymeric chain assemblies of transition metal complexes with a multidentate Schiff-base

The new multidentate Schiff-base (E)-6,6′-((1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-ylidene))bis(4-methyl-2-((E)(pyridine-2-ylmethylimino)methyl)phenol) H₂L and its polymeric binuclear metal complexes with Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) are reported. The reaction of 2,6-diformyl-4-methyl-phenol with ethylenediamine in mole ratios of 2:1 gave the precursor 3,3′-(1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1ylidene))bis(methan-1-yl-1-ylidene)bis(2-hydroxy-5-methylbenzaldehyde) W. Condensation of the precursor with 2-(amino-methyl)pyridine in mole ratios of 1:2 gave the new N₆O₂ multidentate Schiff-base ligand H₂L. Upon complex formation, the ligand behaves as a dibasic octadentate species with the involvement of the nitrogen atoms of the pyridine groups in coordination for all complexes. The mode of bonding and overall geometry of the complexes were determined through physico-chemical and spectroscopic methods. These studies revealed octahedral geometries for Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Cd(II) and Hg(II) complexes of general formulae [Cr₂^III(L)Cl₂]Cl₂, [Ni₂^II(L)(H₂O)₂]Cl₂ and [M₂(L)Cl₂] and five co-ordinate Zn(II) complex of general formula [Zn₂^II(L)]Cl₂.     

Cubic Interaction and Triaxiality in $$\boldsymbol{{}^{236{-}246}}$$ Pu Nuclei

Physics of Atomic Nuclei - In the present study, we investigate even–even $${}^{236{-}246}$$ Pu isotopes with triaxial interacting boson model. Calculations for the energy levels and $$E$$ 2...