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Leite Irena Andrianov Victor Zelencova-Gopejenko Diana Loza Einars Kazhoka-Lapsa Iveta Domracheva Ilona Stojak Marta Chlopicki Stefan Kalvins Ivars 《Chemistry of Heterocyclic Compounds》2021,57(12):1235-1235
Chemistry of Heterocyclic Compounds - 相似文献
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Tale RH 《Organic letters》2002,4(10):1641-1642
[reaction: see text] Cyclization of the intermediate radical formed after initial oxidative coupling between thiophenols and aromatic nitriles leads to the synthesis of a wide range of 2-arylbenzothiazoles. 相似文献
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The title reaction furnished the yellow 3,4-dicyano-2,5-bis(diphenylmethyleneamino)-thiophene and a red precursor which contains one more sulfur atom; structures and mechanism are discussed. 相似文献
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Tekade Pradip V. Tale Bhagyashri U. Bajaj Sonal D. Authankar Nandini 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2018,92(12):2488-2496
Russian Journal of Physical Chemistry A - Ultrasonic studies of compounds of dihydropyridine series in polar and non-polar solvents at various concentrations and temperatures 303–318 K.... 相似文献
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Tekade Pradip V. Bajaj Sonal Tale Bhagyashri Titirmare Neha R. Bandwal Priyanka 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2018,92(12):2596-2599
Russian Journal of Physical Chemistry A - Formation of complexes Sr(II), Cr(II), and Al(III) with ligands (1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)acetic acid (L1),... 相似文献
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Davood Nori-Shargh Seiedeh Negar Mousavi Rose Tale Hooriye Yahyaei 《Structural chemistry》2016,27(6):1753-1768
The correlations between the global hardness (η), hyperconjugative anomeric effect, Pauli exchange-type repulsions, electrostatic model associated with dipole–dipole interaction and structural parameters in 2-fluorotetrahydropyran, -thiopyran, -selenopyran (1–3) and their chloro- (4–6) and bromo-analogs (7–9) were investigated by means of the conventional and range-corrected functionals and natural bond orbital (NBO) interpretation. By deletion of the HC-exo-AE and HC-endo-AE, the equatorial conformations of compounds 1–9 become more stable than their corresponding axial forms, revealing that anomeric relationships in compounds 1–9 have the hyperconjugative anomeric effect origins while the electrostatic model associated with dipole–dipole interaction does not play a determining role on the variations of the anomeric relationships in these compounds. The anomeric relationships in compounds 1–3 have no Pauli exchange-type repulsions origin, but it has a significant impact on the conformational preferences in compounds 4–6 and 7–9. A canonical molecular orbital interpretation was conducted to investigate the correlations between the linear combinations of natural bond orbitals in the HOMOs, LUMOs and the global hardness (η) values. There is a direct relationship between the hyperconjugative anomeric effect, global hardness (η) and zero-point energies in compounds 1–3, 4–6 and 7–9. The harder axial conformations with the greater hyperconjugative anomeric effect and zero-point energy values are more stable than their corresponding equatorial forms. 相似文献
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Eli Sutter Francisco Ivars‐Barcelo Peter Sutter 《Particle & Particle Systems Characterization》2014,31(8):879-885
Using transmission electron microscopy, the size‐dependent room temperature oxidation of tin nanoparticles is studied. The oxide that forms during room temperature oxidation of Sn particles is amorphous SnO, and it retains this stoichiometry and structure over extended time periods. From the investigation of arrays of Sn nanoparticles with broad size distribution, under identical conditions, the Sn oxide thickness is evaluated as a function of size and oxidation time. The oxide thickness depends strongly on the size of the Sn nanoparticles, which is in excellent agreement with predictions for a Mott–Cabrera model corrected for a non‐uniform electric field. The results demonstrate the accelerated oxidation kinetics of nanoscale particles with high curvature, due to the amplified electric field at the interface to a continuously shrinking metal core. 相似文献
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Several N‐lactosylated aryl thioureas and benzothiazolyl thioureas have been prepared by the condensation of hepta‐O‐acetyl‐β‐D ‐lactosyl isothiocyanate with aryl amines and 2‐aminobenzothiazole/substituted benzothiazoles. Hepta‐O‐acetyl‐β‐D ‐lactosyl isothiocyanate was prepared by the interaction of hepta‐O‐acetyl‐α‐D ‐lactosyl bromide and lead thiocyanate. The structures of these new N‐lactosides have been established on the basis of IR, NMR, and mass spectral studies. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:306–309, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20207 相似文献